AROMATICS EXTRACTION THROUGH INTEGRATION OF COMPLEMENTARY CO-SOLVENTS

    公开(公告)号:US20240218267A1

    公开(公告)日:2024-07-04

    申请号:US18528858

    申请日:2023-12-05

    申请人: UOP LLC

    摘要: Solvent mixtures for extractive distillation are described. One solvent mixture consists essentially of: a first solvent having a higher octane-to-benzene relative volatility than sulfolane in a 90% benzene 10% octane feed mixture at 150° C. and 24:1 solvent-to-feed weight ratio; a second solvent having a higher octane-to-benzene relative volatility than sulfolane in a 50% benzene 50% octane feed mixture at 150° C. and 3:1 solvent-to-feed weight ratio; and optionally an additive; wherein the solvent mixture has a higher octane-to-benzene relative volatility than Sulfolane in a combined benzene and octane feed at 125° C. and 3:1 solvent-to-feed weight ratio wherein a benzene weight ratio is higher than 30%. Another solvent mixture consists essentially of: a base solvent selected from the group consisting of sulfolane, N-methyl-pyrrolidone (NMP), N-formylmorpholine (NFM), dimethylformamide (DMF), glycol derivatives, or combinations there along with first and second co-solvents. Methods of extractive distillation are also described.

    Method of Desulfurizing an Oil Composition
    76.
    发明公开

    公开(公告)号:US20230287277A1

    公开(公告)日:2023-09-14

    申请号:US18018250

    申请日:2021-07-28

    摘要: The invention provides a method of desulfurizing an oil composition, the method comprising: flowing an oil composition comprising sulfur through a conduit comprising a constricted region, wherein oil-phase bubbles form in the constricted region and collapse in a turbulent zone downstream of the constricted region; contacting the oil composition with an immiscible deep eutectic solvent in the turbulent zone, thereby extracting at least a portion of the sulfur from the oil composition into association with the deep eutectic solvent; and separating the deep eutectic solvent and the extracted sulfur from the desulfurized oil composition.

    Composition Process And Apparatus To Remove Sulfur From Refined Crude Oil Fraction

    公开(公告)号:US20220259506A1

    公开(公告)日:2022-08-18

    申请号:US17631315

    申请日:2020-07-29

    发明人: Enrico Fumagalli

    IPC分类号: C10G21/20 C10G33/04

    摘要: A ionic liquid composition to remove sulfur from refined crude oil fraction, comprising or consisting of two or more compounds having: —an imidazolium cation substituted by one or more straight or branched C1-C6 alkyl group and —an anion selected from the group consisting of R5COO, CI., Br, [BF4], [PF6]—, [SbF6]—, [R6SO4], [OTs], [OMs], wherein R5 is C1-C8 alkyl, Cs—Cs cycloalkyl, benzyl, C2-C6 alkenyl, and R6 is C1-C6 alkyl.