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    OLIGOMERISATION OF OLEFINIC COMPOUNDS WITH REDUCED POLYMER FORMATION
    71.
    发明申请
    OLIGOMERISATION OF OLEFINIC COMPOUNDS WITH REDUCED POLYMER FORMATION 有权
    具有降低聚合物形成的烯烃化合物的低级化

    公开(公告)号：US20120316303A1

    公开(公告)日：2012-12-13

    申请号：US13502664

    申请日：2010-10-13

    申请人： Martin John Hanton ,  David Matthew Smith ,  William Fullard Gabrielli ,  Mark William Kelly

    发明人： Martin John Hanton ,  David Matthew Smith ,  William Fullard Gabrielli ,  Mark William Kelly

    IPC分类号： C08F4/00 ,  C08F110/02 ,  C08F4/69 ,  C08F4/52

    CPC分类号： C07C2/36 ,  C07C2/32 ,  C07C2531/12 ,  C07C2531/14 ,  C07C2531/24 ,  C07C11/02

    摘要： The invention relaters to a process for producing an oligomeric product by oligomerisation of at least one olefinic compound, the process including a) providing an activated oligomerisation catalyst by combining, in any order, i) a source of chromium, ii) a ligating compound of the formula I (R1)mX1(Y) X2 (R2)n. . . . I wherein X1 and X2 are independently an atom selected from the group consisting of nitrogen, phosphorus, arsenic, antimony, bismuth, oxygen, sulphur and selenium or said atom oxidized by S, Se, N or O where the valence of X1 and/or X2 allows for such oxidation, Y is a linking group between X1 and X2, m and n are independently 0, 1 or a larger integer, and R1 and R2 are independently hydrogen, a hydrocarbyl group, an organoheteryl group or a heterohydrocarbyl group, and R1 being the same or different when m>1, and R2 being the same or different when n>1, iii) a catalyst activator or combination of catalyst activators, b) providing a zinc compound, and c) contacting the at least one olefinic compound with a composition containing the activated oligomerisation catalyst and the zinc compound, the zinc compound being present in a sufficient quantity such that the ratio of the molar amount of zinc in the zinc compound to the molar amount of chromium in the source of chromium is between 1 and 10000 The invention also provides for a process for activating an oligomerisation catalyst to be used to produce an oligomeric product from at least one olefinic compound, as described above

    摘要翻译： 本发明涉及通过至少一种烯烃化合物的低聚制备低聚产物的方法，该方法包括：a）通过以任何顺序，i）铬源，ii）结合化合物提供活化的低聚催化剂， 式（R1）mX1（Y）X2（R2）n。 。 。 。 其中X1和X2独立地是选自氮，磷，砷，锑，铋，氧，硫和硒的原子或由S，Se，N或O氧化的所述原子，其中X 1和/或 X2允许这种氧化，Y是X1和X2之间的连接基团，m和n独立地是0,1或更大的整数，R1和R2独立地是氢，烃基，有机酰基或杂烃基，和 当m> 1时，R 1相同或不同，并且当n> 1时，R 2相同或不同，iii）催化剂活化剂或催化剂活化剂的组合，b）提供锌化合物，和c）使至少一种烯属 与含有活化低聚催化剂和锌化合物的组合物的化合物，锌化合物以足够的量存在，使得锌化合物中的锌的摩尔量与铬源中的铬的摩尔量的比例在 1 an d 10000本发明还提供了用于活化低聚催化剂以用于从至少一种烯烃化合物制备低聚产物的方法，如上所述

    Process for the preparation of atactic 1-butene polymers
    72.
    发明授权
    Process for the preparation of atactic 1-butene polymers 有权
    制备无规1-丁烯聚合物的方法

    公开(公告)号：US08178636B2

    公开(公告)日：2012-05-15

    申请号：US11579525

    申请日：2005-04-25

    申请人： Luigi Resconi ,  Simona Guidotti

    发明人： Luigi Resconi ,  Simona Guidotti

    IPC分类号： C08F4/64 ,  C08F4/72 ,  C08F4/52 ,  C08F110/08 ,  C08F10/08

    CPC分类号： C08F10/08 ,  C08F4/65912 ,  C08F110/08 ,  C08F210/02 ,  C08F210/08 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/17 ,  C08F2500/03 ,  C08F2500/20 ,  C08F2500/15 ,  C08F210/06 ,  C08F210/16

    摘要： A process for obtaining atactic 1-butene polymer optionally containing at least one comonomer selected from ethylene, propylene or an alpha-olefin of formula CH2═CHRo, wherein Ro is a linear or branched C3-C20 alkyl group, comprising the step of polymerizing 1-butene and optionally ethylene, propylene or said alpha-olefin, in the presence of a catalyst system obtainable by contacting: a) at least one metallocene compound of formula (I) in its meso or meso-like form wherein M is an atom of a transition metal; p is an integer from 0 to 3; X, same or different, is a hydrogen atom, a halogen atom, or a hydrocarbon group; L is a divalent C1-C40 hydrocarbon radical optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; R1 and R2, are C1-C40 hydrocarbon radicals; T, equal to or different from each other, is a moiety of formula (IIa) or (IIb): wherein R3 is a C1-C40 hydrocarbon radical; R4 and R6, are hydrogen atoms or C1-C40 hydrocarbon radicals; R5 is a C1-C40 hydrocarbon radical; R7 and R8, equal to or different from each other, are hydrogen atoms or C1-C40 hydrocarbon radicals; and b) an alumoxane or a compound capable of forming an alkyl metallocene cation.

    摘要翻译： 获得任选含有至少一种选自乙烯，丙烯或式CH 2 = CHRo的α-烯烃的共聚单体的无规1-丁烯聚合物的方法，其中Ro是直链或支链C 3 -C 20烷基，其包括聚合1 丁烯和任选的乙烯，丙烯或所述α-烯烃，在催化剂体系存在下，可通过以下步骤：a）至少一种其中间或内消旋形式的式（I）金属茂化合物，其中M是 过渡金属; p是0至3的整数; X相同或不同，是氢原子，卤素原子或烃基; L是任选含有属于元素周期表第13-17族的杂原子的二价C 1 -C 40烃基; R1和R2是C1-C40烃基; T为等于或不同的式（IIa）或（IIb）的部分：其中R 3为C 1 -C 40烃基; R4和R6是氢原子或C1-C40烃基; R5是C1-C40烃基; R 7和R 8彼此相同或不同，为氢原子或C 1 -C 40烃基; 和b）铝氧烷或能够形成烷基茂金属阳离子的化合物。

    Ultra high molecular weight ethylene copolymer powder
    73.
    发明授权
    Ultra high molecular weight ethylene copolymer powder 有权
    超高分子量乙烯共聚物粉末

    公开(公告)号：US08173755B2

    公开(公告)日：2012-05-08

    申请号：US11793378

    申请日：2005-12-28

    申请人： Akio Fujiwara ,  Koichi Hasebe

    发明人： Akio Fujiwara ,  Koichi Hasebe

    IPC分类号： C08F4/50 ,  C08F4/52 ,  C08F210/02

    CPC分类号： C08F210/18 ,  C08F10/00 ,  C08F210/16 ,  C08F4/6555 ,  C08F210/08 ,  C08F2500/01 ,  C08F2500/17 ,  C08F2500/08 ,  C08F2500/18 ,  C08F2500/25

    摘要： The present invention relates to an ultrahigh-molecular-weight ethylene copolymer powder having an intrinsic viscosity (η) of 10 dl/g to 34 dl/g, obtainable by copolymerizing ethylene and at least one olefin selected from the group consisting of α-olefins having 3 to 20 carbon atoms, cyclic olefins having 3 to 20 carbon atoms, compounds represented by the formula CH2═CHR1 wherein R1 is an aryl group having 6 to 20 carbon atoms, and linear, branched or cyclic dienes having 4 to 20 carbon atoms, wherein (1) a molded article of the copolymer powder has a haze of from 30% to 80% and (2) the copolymer powder has a bulk density of from 0.35 g/cm3 to 0.6 g/cm3.

    摘要翻译： 本发明涉及一种超高分子量乙烯共聚物粉末，其具有10dl / g至34dl / g的特性粘度（＆egr），可通过共聚乙烯和至少一种选自α-烯烃的烯烃， 具有3至20个碳原子的烯烃，具有3至20个碳原子的环烯烃，由式CH 2 = CHR表示的化合物，其中R 1是具有6至20个碳原子的芳基，以及具有4至20个碳原子的直链，支链或环状二烯 原子，其中（1）共聚物粉末的模制品的雾度为30％至80％，（2）共聚物粉末的堆积密度为0.35g / cm 3至0.6g / cm 3。

    METHOD TO MAKE AN ACID CATALYST HAVING GREATER THAN 20 WT% CONJUNCT POLYMER
    75.
    发明申请
    METHOD TO MAKE AN ACID CATALYST HAVING GREATER THAN 20 WT% CONJUNCT POLYMER 审中-公开
    制备具有超过20 WT％共轭聚合物的酸催化剂的方法

    公开(公告)号：US20110319258A1

    公开(公告)日：2011-12-29

    申请号：US13228143

    申请日：2011-09-08

    申请人： Sven Ivar Hommeltoft ,  Howard S. Lacheen ,  Saleh Elomari

    发明人： Sven Ivar Hommeltoft ,  Howard S. Lacheen ,  Saleh Elomari

    IPC分类号： B01J31/06 ,  C08F4/52

    CPC分类号： B01J31/06 ,  B01J31/0284 ,  B01J31/0298 ,  B01J2231/32 ,  C07C2/58 ,  C07C2527/126 ,  C07C2531/02 ,  C07C2531/06

    摘要： A method to make an acidic ionic liquid catalyst, by mixing aluminum chloride in the presence of a hydrocarbon solvent, an organic chloride, and optionally an ionic liquid; wherein the acidic ionic liquid catalyst does not precipitate out solids; and wherein the acidic ionic liquid catalyst has greater than 20 wt % conjunct polymer and a molar ratio of Al to a heteroatom selected from the group consisting of N, P, O, S, and combinations thereof greater than 2.0. Also a method to make the acidic ionic liquid catalyst comprising: a. mixing aluminum chloride in the presence of a hydrocarbon solvent, and an organic chloride, to make an acid catalyst phase comprising a conjunct polymer; b. adding hydrogen chloride to the acid catalyst phase.

    摘要翻译： 一种通过在烃溶剂，有机氯化物和任选的离子液体的存在下混合氯化铝来制备酸性离子液体催化剂的方法; 其中所述酸性离子液体催化剂不会沉淀出固体; 并且其中所述酸性离子液体催化剂具有大于20重量％的结合聚合物，并且Al与选自N，P，O，S及其组合的杂原子的摩尔比大于2.0。 还有一种制备酸性离子液体催化剂的方法，包括：a。 在烃溶剂和有机氯化物的存在下混合氯化铝，以制备包含结合聚合物的酸催化剂相; b。 在酸催化剂相中加入氯化氢。

    Catalytic system for obtaining conjugated diene/mono-olefin copolymers and these copolymers
    77.
    发明授权
    Catalytic system for obtaining conjugated diene/mono-olefin copolymers and these copolymers 有权
    用于获得共轭二烯/单烯烃共聚物和这些共聚物的催化体系

    公开(公告)号：US08039565B2

    公开(公告)日：2011-10-18

    申请号：US12453333

    申请日：2009-05-07

    申请人： Christophe Boisson ,  Vincent Monteil ,  Roger Spitz

    发明人： Christophe Boisson ,  Vincent Monteil ,  Roger Spitz

    IPC分类号： C08F4/52 ,  C08F236/04 ,  C08F236/06 ,  B01J31/22

    CPC分类号： C08F210/00 ,  C08F210/02 ,  C08F210/06 ,  C08F210/14 ,  C08F210/16 ,  C08F236/04 ,  Y10S526/943 ,  C08F4/52 ,  C08F236/06

    摘要： A catalytic system usable for the copolymerization of at least one conjugated diene and at least one monoolefin, a process for preparing this catalytic system, a process for preparing a copolymer of a conjugated diene and at least one monoolefin using said catalytic system, and said copolymer are described. This catalytic system includes: (i) an organometallic complex represented by the following formula: {[P(Cp)(Fl)Ln(X)(LX)}p  (1) where Ln represents a lanthanide atom to which is attached a ligand molecule comprising cyclopentadienyl Cp and fluorenyl Fl groups linked to one another by a bridge P of the formula MR1R2, M is an element from column IVa of Mendeleev's periodic table and R1 and R2 each represent alkyl groups of 1 to 20 carbon atoms or cycloalkyl or phenyl groups of 6 to 20 carbon atoms, X represents a halogen atom, L represents an optional complexing molecule, such as an ether, and optionally a substantially less complexing molecule, such as toluene, p is a natural integer greater than or equal to 1 and x is greater than or equal to 0, and (ii) a co-catalyst selected from alkylmagnesiums, alkyllithiums, alkylaluminums, Grignard reagents and mixtures of these constituents.

    摘要翻译： 一种可用于共聚二烯和至少一种单烯烃的催化体系，该催化体系的制备方法，使用所述催化体系制备共轭二烯和至少一种单烯烃的共聚物的方法，所述共聚物 被描述。 该催化体系包括：（i）由下式表示的有机金属络合物：{[P（Cp）（Fl）Ln（X）（LX）} p（1）其中Ln表示连接有配体的镧系元素 包含通过式MR1R2的桥P彼此连接的环戊二烯基Cp和芴基F1基团的分子，M是门多列夫元素周期表第IVa列的元素，R 1和R 2各自表示1-20个碳原子的烷基或环烷基或苯基 6至20个碳原子的基团，X表示卤素原子，L表示任选的络合分子，例如醚，以及任选的基本上较少络合的分子，例如甲苯，p是大于或等于1的天然整数， x大于或等于0，和（ii）选自烷基镁，烷基锂，烷基铝，格氏试剂和这些组分的混合物的助催化剂。

    Process for the polymerization of 1-butene
    78.
    发明授权
    Process for the polymerization of 1-butene 有权
    1-丁烯聚合方法

    公开(公告)号：US08030421B2

    公开(公告)日：2011-10-04

    申请号：US12288687

    申请日：2008-10-22

    申请人： Luigi Resconi

    发明人： Luigi Resconi

    IPC分类号： C08F4/64 ,  C08F4/76 ,  C08F4/52

    CPC分类号： C08F110/08 ,  C08F4/65912 ,  C08F10/08 ,  C08F210/08 ,  Y10S526/941 ,  Y10S526/943 ,  C08F4/65927 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/15 ,  C08F2500/20 ,  C08F2500/03 ,  C08F210/16

    摘要： A process for polymerizing 1-butene comprising the step of contacting under polymerization conditions 1-butene and optionally from 0 to 20% by mol of an alpha olefin with a catalyst system obtainable by contacting a bridged metallocene compound of formula (I) wherein R1 and R2 are an hydrocarbon radical A is a carbon atom, a germanium atom or a silicon atom; m is 1, 2; M is a metal of group 4 of the Periodic Table of the Elements; X, is hydrogen, a halogen atom, or a group R, OR, OSO2CF3, OCOR, SR, NR2 or PR2, wherein the substituents R are hydrocarbon radical; L is a moiety of formula (IIa) or (IIb) wherein T is an oxygen (O) or sulphur (S) atom or a CH2 group; and R3 and R4 are hydrogen atoms or hydrocarbon radicals; one or more alumoxanes or compounds able to form an alkylmetallocene cation; and optionally an organo aluminum compound.

    摘要翻译： 一种聚合1-丁烯的方法，包括在聚合条件下使1-丁烯和任选的0至20摩尔％的α-烯烃与催化剂体系接触的步骤，所述催化剂体系可通过使式（I）的桥连茂金属化合物与其中R1和 R2是烃基A是碳原子，锗原子或硅原子; m为1,2; M是元素周期表第4族的金属; X是氢，卤素原子或基团R，OR，OSO 2 CF 3，OCOR，SR，NR 2或PR 2，其中取代基R是烃基; L是式（IIa）或（IIb）的部分，其中T是氧（O）或硫（S）原子或CH 2基团; 并且R 3和R 4是氢原子或烃基; 一种或多种能够形成烷基茂金属阳离子的铝氧烷或化合物; 和任选的有机铝化合物。