公开(公告)号：US4659688A

公开(公告)日：1987-04-21

申请号：US858973

申请日：1986-05-02

Applicant: Simon G. Kukes ,  Gerhard P. Nowack ,  Robert L. Banks

Inventor： Simon G. Kukes ,  Gerhard P. Nowack ,  Robert L. Banks

IPC: B01J27/18 ,  C07C2/18 ,  C07C2/02

CPC classification number: C07C2/18 ,  B01J27/1817 ,  C07C2527/167

Abstract: Catalyst composition comprising chemically bound copper, phosphorus and oxygen used for oligomerizing olefins to C.sub.5 -C.sub.12 hydrocarbons. The preferred catalyst composition comprises a mixture of copper(II) orthophosphate, zirconium orthophosphate and aluminum orthophosphate, preferably formed by coprecipitation.

Abstract translation: 催化剂组合物包含用于将烯烃低聚成C5-C12烃的化学结合的铜，磷和氧。 优选的催化剂组合物包括正磷酸铜（II），正磷酸锆和正磷酸铝的混合物，优选通过共沉淀形成。

公开(公告)号：US4659453A

公开(公告)日：1987-04-21

申请号：US826406

申请日：1986-02-05

Applicant: Simon G. Kukes ,  Jerald A. Howell

Inventor： Simon G. Kukes ,  Jerald A. Howell

IPC: C10G45/16 ,  C10G47/26 ,  C10G45/04

CPC classification number: C10G47/26 ,  C10G45/16

Abstract: A hydrotreating (hydrovisbreaking) process comprises the step of contacting under suitable conditions (A) a substantially liquid hydrocarbon-containing feed stream containing more than 0.1 weight-% Ramsbottom carbon residue, (B) a hydrogen-containing gas and (C) a liquid catalyst composition, which has been prepared by mixing (a) water, (b) at least one alkali metal sulfide or hydrogen sulfide or ammonium sulfide or hydrogen sulfide and (c) at least one molybdenum-oxygen compound, wherein the atomic ratio of S:Mo in this liquid catalyst composition is in the range of from about 0.6:1 to about 3.0:1, preferably from about 0.8:1 to 2.3:1. Preferably, (b) is (NH.sub.4).sub.2 S and (c) is MoO.sub.3.

Abstract translation: 加氢处理（加氢脱硫）方法包括在合适的条件（A）下接触的步骤（A）含有大于0.1重量％的Ramsbottom碳残余物的基本上液体含烃的进料流，（B）含氢气体和（C）液体 催化剂组合物，其通过混合（a）水，（b）至少一种碱金属硫化物或硫化氢或硫化铵或硫化氢和（c）至少一种钼 - 氧化合物而制备，其中S ：该液体催化剂组合物中的Mo在约0.6:1至约3.0:1的范围内，优选约0.8:1至2.3:1。 优选地，（b）是（NH 4）2 S，（c）是MoO 3。

公开(公告)号：US4612110A

公开(公告)日：1986-09-16

申请号：US589362

申请日：1984-03-14

Applicant: Simon G. Kukes ,  Thomas Davis ,  Howard F. Efner ,  Robert J. Hogan ,  Daniel M. Coombs

Inventor： Simon G. Kukes ,  Thomas Davis ,  Howard F. Efner ,  Robert J. Hogan ,  Daniel M. Coombs

IPC: C10G45/08 ,  C10G45/16 ,  C10G47/12 ,  C10G49/04

CPC classification number: C10G45/08 ,  C10G45/16

Abstract: At least one decomposable molybdenum dithiocarbamate compound is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable molybdenum dithiocarbamate compound is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the decomposable molybdenum dithiocarbamate compound may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occurring in each case.

Abstract translation: 将至少一种可分解​​的二硫代氨基甲酸钼化合物与含烃进料流混合。 然后将含有这种可分解的二硫代氨基甲酸钼化合物的含烃进料流在加氢精制过程中与包含选自氧化铝，二氧化硅和二氧化硅 - 氧化铝的载体的催化剂组合物和包含至少一种选自组 VIB，VIIB和VIII组。 当可催化的新二硫代氨基甲酸酯化合物引入时，可以在每一种情况下发生有益的结果，部分失活或消耗。

公开(公告)号：US4596654A

公开(公告)日：1986-06-24

申请号：US781816

申请日：1985-09-30

Applicant: Simon G. Kukes ,  Stephen L. Parrott ,  Karlheinz K. Brandes

Inventor： Simon G. Kukes ,  Stephen L. Parrott ,  Karlheinz K. Brandes

IPC: B01J23/847 ,  C10G45/06 ,  C10G45/00

CPC classification number: B01J23/8472 ,  C10G45/06

Abstract: A catalyst composition is prepared by dissolving a suitable vanadium and oxygen containing compound, a suitable nickel (II) compound and ammonia in water, mixing this solution with an alumina containing support material, and calcining this mixture. This catalyst composition is used primarily for hydrotreating of hydrocarbon feed stream, which contain nickel, vanadium and sulfur impurities, particularly heavy oils.

Abstract translation: 通过将合适的含钒和含氧化合物，合适的镍（II）化合物和氨在水中溶解，将该溶液与含氧化铝的载体材料混合并煅烧该混合物来制备催化剂组合物。 该催化剂组合物主要用于加氢处理含有镍，钒和硫杂质，特别是重油的烃进料流。

公开(公告)号：US4567159A

公开(公告)日：1986-01-28

申请号：US649341

申请日：1984-09-11

Applicant: Robert L. Banks ,  Simon G. Kukes

Inventor： Robert L. Banks ,  Simon G. Kukes

IPC: C07C6/04 ,  B01J31/02 ,  B01J27/02 ,  B01J27/06 ,  B01J27/14

CPC classification number: C07C6/04

Abstract: Olefins are converted into other olefins having different numbers of carbon atoms by contact with a catalyst comprising an inorganic refractory material containing at least one of tungsten oxide and molybdenum oxide and a promoting amount of at least one treating agent selected from chlorinated silicon compounds, thionyl chloride, and sulfuryl chloride under conditions suitable for the treating agent to promote the activity of tungsten and molybdenum oxides for the disproportionation reaction.

Abstract translation: 通过与包含含有氧化钨和氧化钼中的至少一种的无机耐火材料的催化剂接触并将促进量的至少一种处理剂选自氯化硅化合物，亚硫酰氯，将烯烃转化成具有不同碳原子数的其它烯烃 和磺酰氯在适合于处理剂的条件下促进钨和钼的氧化物用于歧化反应的活性。

公开(公告)号：US4564441A

公开(公告)日：1986-01-14

申请号：US612539

申请日：1984-05-21

Applicant: Simon G. Kukes ,  Edward L. Sughrue, II ,  Robert J. Hogan

Inventor： Simon G. Kukes ,  Edward L. Sughrue, II ,  Robert J. Hogan

IPC: C10G45/04 ,  C10G45/16 ,  C10G45/08 ,  C10G47/12 ,  C10G49/04

CPC classification number: C10G45/16 ,  C10G45/04

Abstract: At least one decomposable compound of a metal selected from the group consisting of copper, zinc and the metals of Group III-B, Group IV-B, Group VB, Group VIB, Group VIIB and Group VIII of the Periodic Table is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable compound is then contacted with a suitable refractory inorganic material to reduce the concentration of metals, sulfur and Ramsbottom carbon residue contained in the hydrocarbon-containing feed stream. The suitable refractory inorganic material may also be slurried with the hydrocarbon-containing feed stream.

Abstract translation: 将选自铜，锌以及元素周期表III-B族，IV-B族，VB族，VIB族，VIIB族和VIII族金属的金属的至少一种可分解​​化合物与 含烃进料流。 然后将含有这种可分解化合物的含烃进料流与合适的耐火无机材料接触，以降低含烃进料流中所含的金属，硫和Ramsbottom碳残余物的浓度。 合适的难熔无机材料也可以与含烃进料流一起浆化。

公开(公告)号：US4555499A

公开(公告)日：1985-11-26

申请号：US576079

申请日：1984-02-01

Applicant: Simon G. Kukes ,  James B. Kimble

Inventor： Simon G. Kukes ,  James B. Kimble

IPC: B01J27/185 ,  B01J27/198 ,  C10G45/06 ,  B01J27/14

CPC classification number: B01J23/002 ,  B01J27/1853 ,  B01J27/198 ,  B01J2523/00 ,  C10G2300/107

Abstract: Metals contained in a hydrocarbon containing feed stream are removed by contacting the hydrocarbon containing feed stream under suitable demetallization conditions with hydrogen and a catalyst composition comprising zirconium phosphate, cobalt phosphate and a metal phosphate where the metal is selected from the group consisting of nickel and vanadium. Molybdenum phosphate may also be added to the catalyst composition if desired. The life and activity of the catalyst composition may be increased by introducing a decomposable metal compound selected from the group consisting of the metals of Group V-B, Group VI-B, Group VII-B and Group VIII of the Periodic Table into the hydrocarbon containing feed stream prior to contacting the hydrocarbon containing feed stream with the catalyst composition.

Abstract translation: 通过在合适的脱金属条件下使含烃进料流与氢气和包含磷酸锆，磷酸钴和金属磷酸盐的催化剂组合物接触来除去含烃进料流中的金属，其中金属选自镍和钒 。 如果需要，也可以将磷酸钼添加到催化剂组合物中。 催化剂组合物的寿命和活性可以通过将选自由VB组，VI-B族，VII-B族和VIII族元素周期表的金属组成的组中的可分解的金属化合物引入到含烃进料中 在将含烃进料流与催化剂组合物接触之前的流。

公开(公告)号：US4524235A

公开(公告)日：1985-06-18

申请号：US649035

申请日：1984-09-10

Applicant: Robert L. Banks ,  Simon G. Kukes

Inventor： Robert L. Banks ,  Simon G. Kukes

IPC: B01J23/24 ,  C07C6/04 ,  C07C6/00

CPC classification number: C07C6/04 ,  B01J23/24

Abstract: An improved olefin disproportionation catalyst produced by contacting an inorganic refractory oxide containing a catalytic amount of tungsten oxide or molybdenum oxide with a promoting amount of at least one elemental metal selected from zinc and manganese.

Abstract translation: 一种改进的烯烃歧化催化剂，其通过使含有催化量的氧化钨或氧化钼的无机难熔氧化物与促进量的至少一种选自锌和锰的元素金属接触而制备。

公开(公告)号：US4465891A

公开(公告)日：1984-08-14

申请号：US518557

申请日：1983-07-29

Applicant: Simon G. Kukes ,  Robert L. Banks

Inventor： Simon G. Kukes ,  Robert L. Banks

IPC: B01J23/24 ,  B01J23/36 ,  C07C6/04 ,  C07C6/00

CPC classification number: B01J23/24 ,  B01J23/36 ,  C07C6/04

Abstract: Olefins are converted into other olefins having different numbers of carbon atoms by contact with a catalyst produced by combining a metal, such as tungsten or a tungsten compound, with a halosilane by adding either water or silica to the suspension of metal and halosilane and then heating to activate the catalyst.

Abstract translation: 通过将金属如钨或钨化合物与卤代硅烷结合而制得的催化剂与金属和卤代硅烷的悬浮液中加入水或二氧化硅，然后加热，将烯烃转化为具有不同碳原子数的其它烯烃 以激活催化剂。

公开(公告)号：US5348928A

公开(公告)日：1994-09-20

申请号：US059234

申请日：1993-05-06

Applicant: Simon G. Kukes ,  P. Donald Hopkins ,  Riitta L. A. Olleandorff ,  Pablo D. Hendler ,  Cynthia D. Ontiveros ,  Don M. Washecheck

Inventor： Simon G. Kukes ,  P. Donald Hopkins ,  Riitta L. A. Olleandorff ,  Pablo D. Hendler ,  Cynthia D. Ontiveros ,  Don M. Washecheck

IPC: B01J23/85 ,  C10G45/08 ,  B01J21/04 ,  B01J23/78 ,  B01J23/88 ,  B01J37/04

CPC classification number: B01J23/85 ,  C10G45/08

Abstract: A catalyst and method of making a catalyst are provided for the selective hydrotreating of a selective hydrotreating feedstock comprising reacting the feedstock with hydrogen at hydrotreating conditions in the presence of a catalyst comprising a hydrogenation component and a support component. The hydrogenation component comprises a Group VIB metal component and a Group VIII metal component wherein the Group VIB metal component is present in an amount ranging from about 4 wt % to about 20 wt % and the Group VIII metal component is present in an amount ranging from about 0.5 wt % to about 10 wt %, both calculated as oxides and based on the total catalyst weight. The support component comprises from about 0.5 wt % to about 50 wt % of a magnesium component and from about 0.02 wt % to about 10 wt % of an alkali metal component, both calculated as oxides and based on the total catalyst weight. The present invention provides a process, catalyst, and method of making a catalyst resulting in higher selective hydrotreating feedstock octane at high levels of desulfurization, among numerous other benefits.

Abstract translation: 提供催化剂和制备催化剂的方法用于选择性加氢处理选择性加氢处理原料，包括在加氢处理条件下，在包含氢化组分和载体组分的催化剂的存在下使原料与氢气反应。 氢化组分包括VIB族金属组分和VIII族金属组分，其中VIB族金属组分的存在量为约4重量％至约20重量％，第VIII族金属组分的存在量范围为 约0.5重量％至约10重量％，均以氧化物计，基于总催化剂重量计算。 载体组分包含约0.5重量％至约50重量％的镁组分和约0.02重量％至约10重量％的碱金属组分，两者以氧化物计，基于总催化剂重量计。 本发明提供一种制备催化剂的方法，催化剂和方法，其产生较高选择性加氢处理高脱硫水平的原料辛烷等许多益处。