摘要:
Fluids are injected into porous strata for many purposes. These include, for example, well stimulation, secondary-type oil recovery, mobility control, regulation of formation "wetness" and regulation of the encroachment of fluids. Fluids used for the above purposes are readily selected using nuclear magnetic resonance (NMR) measurements in the laboratory to measure the interaction between the fluids being injected into the reservoir rock and the in situ fluids or between injected fluids and the porous material. NMR measurements are taken for each component of sample fluids proposed to be injected in the reservoir for a desired purpose, or the sample fluid per se and each of the in situ fluids. NMR measurements are then taken of the interaction between the nuclei of sample fluids injected, the reservoir rock, and the nuclei of fluids in situ.If the injected fluid is to be used for some purposes, for example, well stimulation or secondary-type oil recovery, the fluids are selected which interact least with the rock and with in situ fluids. If the wetness of the reservoir is to be changed, then the fluid is selected which interacts well with the reservoir rock. If a material is to be precipitated or formed in situ, the fluid is selected which interacts well with either the reservoir rock or the formation fluids. Additionally, the best combination of components for a particular fluid to be injected can also be determined using NMR, preferably pulsed, detection devices.
摘要:
The ability of nuclear magnetic resonance spectroscopy to distinguish between compounds and between parts of compounds is substantially increased by the use of certain rare earth chelate shift reagents. The preferred shift reagents are the europium III chelates of substituted or unsubstituted dicampholyl ligands, and europium III chelates of substituted or unsubstituted nopinato compounds. The reagents are particularly useful in determining the enantiomeric purity of compositions containing mixtures of enantiomers.
摘要:
A system for the generation of a plurality of equally spaced repetitive spin-echo signals from an RF ''''input'''' pulse and an RF ''''recall'''' pulse utilizing a sample of titanium dioxide (rutile) preferably having an irregular shape and being doped with iron group transition group ions to produce paramagnetic defect centers in the order of 1 X 1016 defect centers/cm3.
摘要:
A system for providing data on the content of subsurface formations on the basis of the magnetic resonance of certain atomic structures of interest. The system incorporates a mobile unit for moving a source of directional electromagnetic radiation along the earth''s surface, directing the radiation substantially vertically into the earth. A probe senses the energy content of the radiated energy pattern (including reflections) to detect distance-related changes which are indicative of groups of atom portions of interest. The sensed radiation is plotted along with a gamma radiation plot for an interpretation indicative of the subsurface formation content.
摘要:
A thermostatic system for nuclear gyromagnetic resonance spectroscopic permanent magnet apparatus comprising a thermostatic oven structure consisting of a first and second thermostatic ovens enclosing a permanent magnet is disclosed. The temperature of the first thermostatic oven is controlled and maintained at a predetermined temperature higher than ambient temperature. The second thermostatic oven is disposed between the permanent magnet and the first thermostatic oven, and its temperature is controlled and maintained at a predetermined temperature higher than the temperature of the first thermostatic oven. In this manner, the permanent magnet is held at a temperature substantially equal to the temperature of the second thermostatic oven.
摘要:
A magnetic resonance spectrometer employing a pseudorandom binary sequence to simultaneously excite magnetic resonance of a plurality of resonance lines in the spectrum of a sample under analysis, the driving radio frequency field being applied to the sample in a train of pulses in each binary sequence, the timing or phase of the pulses being changed in a stochastic manner in the sequence, the composite noise excited resonance signal being detected in a receiver and sampled in a multitude of time displaced intervals in correlation with the binary sequence and stored in an accumulative manner in the associated channels of a memory of subsequent processing, read-out and display, the receiver being activated during the time intervals between the application of the radio frequency pulses to the sample.
摘要:
A method and apparatus provided for reducing the effect of magnetic materials, such as magnetite, in an earth formation on the electrical A.C. signal induced by protons of earth formation fluids precessing under the influence of the earth''s magnetic field after the establishment and interruption of a polarizing field,d in an earth formation traversed by a wellbore. In accordance with the present invention, before the polarizing field, say of magnitude Hp gauss, is established within the earth formation (by passing a direc
摘要:
Double nuclear magnetic resonance coil structure and a spectrometer using same are disclosed. The coil structure comprises three radio frequency coils disposed with their respective magnetic axis in substantially orthoganal relation to each of the other two coils, whereby the coils are magnetically decoupled from each other while being radio frequency magnetic coupled to a nuclear sample disposed within the surrounding coils.
摘要:
In an electron paramagnetic resonance cavity resonator having a line sample therein, a dielectric material positioned near the sample and along at least a portion of its length, and extending into the RF electric field region near the sample, changes the gradient of the electric field intensity and, as a result, the RF magnetic field intensity along the line sample so as to make both the RF electric and magnetic field intensities more uniform along