公开(公告)号：US4925928A

公开(公告)日：1990-05-15

申请号：US210678

申请日：1988-06-23

Applicant: Athanassios Tzikas

Inventor： Athanassios Tzikas

IPC: C09B62/04 ,  C09B62/44

CPC classification number: C09B62/4403 ,  C09B62/043

Abstract: Reactive dyes suitable in particular for dyeing or printing cellulose-containing fiber materials by the exhaust method or by continuous methods and, while giving a high dyeing yield, produce dyes and prints having good fastness properties; having the formula ##STR1## in which D is the radical or a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thiozanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye, R, B.sub.1 and B.sub.2 are independently of each other hydrogen or alkyl which has 1 to 4 carbon atoms and which can be substituted by halogen, hydroxyl, cyano, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, carboxyl, sulfamoyl, sulfo or sulfato, X and Y independently of each other are fluorine, chlorine, bromine, sulfo C.sub.1 -C.sub.4 alkylsulfonyl or phenylsulfonyl, A is an amino substituent which contains at least one group of the formula--SO.sub.2 --Z(2)z is .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-acyloxyethyl, .beta.-haloethyl or vinyl, and Q is 1 or 2 substituents from the group consisting of hydrogen, C.sub.1 -C.sub.4 alkyl, (1), wherein D is phthalocyanine and Y is fluorine.

Abstract translation: 适用于特别用于通过排气法或连续方法染色或印刷含纤维素纤维材料的活性染料，同时产生高染色产率，产生具有良好牢度性质的染料和印花; 具有式（1）其中D为自由基或单偶氮，多偶氮，金属络合物偶氮，蒽醌，酞菁，甲an，偶氮甲碱，二恶嗪，吩嗪，二苯乙烯，三苯甲烷，呫吨，硫呫吨，硝基芳基，萘醌，芘醌 羟基，氰基，C 1 -C 4 - 烷氧基，C 1 -C 4烷氧基羰基，羧基，氨磺酰基，氨基甲酰基，氨基甲酰基，氨基甲酰基， 磺基或硫酸根，X和Y彼此独立地是氟，氯，溴，磺基C 1 -C 4烷基磺酰基或苯基磺酰基，A是含有至少一个式-SO 2 -Z（2）的基团的氨基取代基， 硫代乙基，β-硫代乙酰乙基，β-磷酰乙基，β-酰氧基乙基，β-卤代乙基或乙烯基，Q为1或2个选自氢，C 1 -C 4烷基，（1）的取代基，其中D为酞菁，Y为氟 。

公开(公告)号：US4782140A

公开(公告)日：1988-11-01

申请号：US914832

申请日：1986-10-02

Applicant: Athanassios Tzikas

Inventor： Athanassios Tzikas

IPC: C09B62/523 ,  C07C67/00 ,  C07C301/00 ,  C07C303/22 ,  C07C303/30 ,  C07C303/40 ,  C07C317/28 ,  C07C323/25 ,  C09B62/44 ,  C09B62/503 ,  D06P1/38 ,  D06P3/24 ,  D06P3/66 ,  C09B62/02 ,  C09B62/08 ,  C09B62/507 ,  D06P1/382

CPC classification number: C09B62/4403

Abstract: The invention relates to novel useful reactive dyes of the formula I ##STR1## in which: F is a radical selected from the group consisting of metal-free or metal-containing monoazo or disazo dyes containing at least one --SO.sub.3 H group, anthraquinone dyes, sulfophthalocyanine dyes, formazan dyes, phenazine dyes, oxanine dyes and nitroaryl dyes,R is hydrogen, C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted with --COOH or --SO.sub.3 H, cyanoethyl, or hydroxyethyl, X is fluorine, chlorine, bromine, --SO.sub.3 H, phenylsulfonyl or C.sub.1 -C.sub.4 -alkylsulfonyl,P is 1 or 2 andA is a radical of the formula ##STR2## in which: the groups designated "alk" are independently of each other straight or branched polymethylene radicals having 2 to 6 carbon atoms, andZ is .beta.-halogenoethyl, vinyl, .beta.-sulfatoethyl, .beta.-thiosulfatoethyl or .beta.acetoxyethyl.

Abstract translation: 本发明涉及式I（I）的新型有用的活性染料，其中：F是选自含有至少一个-SO 3 H基团的无金属或含金属的单偶氮或双偶氮染料的基团， 蒽醌染料，磺酞菁染料，甲an染料，吩嗪染料，氧杂染料和硝基芳基染料，R为氢，未被取代或被-COOH或-SO 3 H取代的C 1 -C 4烷基，氰基乙基或羟乙基，X为氟，氯，溴 ，-SO 3 H，苯基磺酰基或C 1 -C 4 - 烷基磺酰基，P为1或2，A为式“IMAGE”的基团，其中：指定为“alk”的基团彼此独立地为直链或支链的聚亚甲基基团， 6个碳原子，Z是β-卤代乙基，乙烯基，β-磺基乙基，β-硫代硫代乙基或β-乙酰氧基乙基。

公开(公告)号：US4746732A

公开(公告)日：1988-05-24

申请号：US636363

申请日：1984-07-30

Applicant: Athanassios Tzikas

Inventor： Athanassios Tzikas

IPC: C09B62/002 ,  C09B62/02 ,  C09B62/20 ,  C09B62/44 ,  C09B62/503 ,  C09B62/507 ,  C09B62/51 ,  C09B62/513 ,  C09B67/24 ,  D06P1/38 ,  D06P1/384 ,  C09B62/03 ,  D06P3/66

CPC classification number: C09B62/4424 ,  C09B62/02

Abstract: Reactive dyes of the formula ##STR1## in which D is the radical of a dye of the polyazo or metal complex azo series, R.sub.1 is hydrogen or an unsubstituted or substituted C.sub.1-4 -alkyl radical, and X is the vinyl, .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-chloroethyl or .beta.-acetoxyethyl group, are suitable in particular for dyeing and printing cellulose-containing fibre materials by the cold pad-batch method and produce, in high dyeing yields, dyeings and prints having good fastness properties.

Abstract translation: 式（1）的反应性染料其中D是多偶氮或金属络合物偶氮系列的染料的基团，R 1是氢或未取代或取代的C 1-4 - 烷基，X是乙烯基， β-磺基乙基，β-硫代乙酰基乙基，β-氯乙基或β-乙酰氧基乙基，特别适用于通过冷垫分批法染色和印刷含纤维素纤维材料，并以高染色产率生产染色和印花 坚牢性。

公开(公告)号：US4374989A

公开(公告)日：1983-02-22

申请号：US293985

申请日：1981-08-18

Applicant: Athanassios Tzikas

Inventor： Athanassios Tzikas

IPC: C07D241/38 ,  C09B5/48

CPC classification number: C07D241/38 ,  C09B5/48

Abstract: A process for the manufacture of dianthraquinonyl-N,N'-dihydroazine, which comprises reacting 1-nitroanthraquinone in mixtures of water, alcohols and alkali metal hydroxides at elevated temperature with hydrazine or hydroxylamine compounds, subsequently removing the alcoholic constituents from the reaction mixture, adding dimethyl sulfoxide, and, if desired, further amounts of alkali metal hydroxides, and bringing the reaction to completion at elevated temperature.

Abstract translation: 一种制备二蒽醌-N，N'-二氢吖嗪的方法，其包括将水，醇和碱金属氢氧化物的混合物中的1-硝基蒽醌与肼或羟胺化合物反应，随后从反应混合物中除去醇组分， 加入二甲基亚砜，如果需要，还可加入碱金属氢氧化物，并使反应在升高的温度下完成。

公开(公告)号：US20140173835A1

公开(公告)日：2014-06-26

申请号：US14236364

申请日：2012-06-19

Applicant: Georg Roentgen ,  Athanassios Tzikas ,  Hubert Jean-Luc Christnacher ,  Laszlo Fekete

Inventor： Georg Roentgen ,  Athanassios Tzikas ,  Hubert Jean-Luc Christnacher ,  Laszlo Fekete

IPC: C09B62/533 ,  C09B62/513

CPC classification number: C09B62/533 ,  C09B62/4415 ,  C09B62/513 ,  C09B67/0055 ,  D06P1/38 ,  D06P3/248 ,  D06P3/66

Abstract: Dye mixtures comprising at least one reactive dye of the formula (1) together with at least one reactive dye of the formula (2), wherein one of the radicals A and B denotes NH2, and the other one of the radicals A and B denotes OH, D is a benzene or naphthalene radical, R1 is hydrogen, hydroxy, sulfo, C1-C4alkyl or C1-C4alkoxy unsubstituted or substituted in the alkyl moiety by hydroxy or by sulfato, R2 is hydrogen, C1-C4alkyl, C1-C4alkoxy, C2-C4alkanoylamino or ureido, R3 is C1-C4alkyl, (R4)0-2 denotes 0 to 2 identical or different substituents selected from the group C1-C4alkyl, C1-C4alkoxy or sulfo, X1 is halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Y1, Y2, Y3, Y4 and Y5 are each independently of the other vinyl or a radical —CH2CH2—U and U is a group removable under alkaline conditions, h, k, l, m and n are each independently of the other the number 0, 1 or 2, and p and q are each independently of the other the number 0 or 1, are suitable for dyeing and printing cellulosic or nitrogen-containing fibre materials.

Abstract translation: 包含至少一种式（1）的活性染料与至少一种式（2）的活性染料的染料混合物，其中基团A和B中的一个表示NH 2，基团A和B中的另一个表示 OH，D是苯或萘基，R 1是氢，羟基，磺基，C 1 -C 4烷基或被烷基部分被羟基或硫酸酯取代的C 1 -C 4烷氧基，R 2是氢，C 1 -C 4烷基，C 1 -C 4烷氧基， C 2 -C 4烷酰基氨基或脲基，R 3是C 1 -C 4烷基，（R 4）0-2表示0至2个相同或不同的选自C 1 -C 4烷基，C 1 -C 4烷氧基或磺基，X 1为卤素，3-羧基吡啶-1-基， 吡啶-1-基或3-氨基甲酰基吡啶-1-基，Y 1，Y 2，Y 3，Y 4和Y 5各自独立地为其它乙烯基或基团-CH 2 CH 2 -U，U是在碱性条件下可除去的基团，h，k，l，m 和n各自独立于数字0,1或2中的另一个，并且p和q各自独立于数字0或1中的另一个，适用于染色和印刷c 纤维素或含氮纤维材料。

公开(公告)号：US07905928B2

公开(公告)日：2011-03-15

申请号：US12739079

申请日：2008-10-07

Applicant: Athanassios Tzikas ,  Thomas Verdugo ,  Georg Roentgen

Inventor： Athanassios Tzikas ,  Thomas Verdugo ,  Georg Roentgen

IPC: C09B62/00 ,  C07D498/00

CPC classification number: C09B62/5033 ,  C09B62/465 ,  C09B67/004

Abstract: Reactive dyes of the formula (1) in which Q1, X, V1, V2, B, T and R1, R2, R4 and R5 are defined in the claims and in the disclosure and wherein the reactive dyes are suitable for dyeing widely varying fiber materials, in particular cellulosic fiber materials and produce dyeings with good allround properties.

Abstract translation: 式（1）的活性染料其中Q1，X，V1，V2，B，T和R1，R2，R4和R5在权利要求书和本公开内容中定义，其中活性染料适用于染色广泛变化的纤维 材料，特别是纤维素纤维材料，并产生具有良好全面性能的染色。

公开(公告)号：US20100154145A1

公开(公告)日：2010-06-24

申请号：US12063277

申请日：2006-08-02

Applicant: Hubert Jean Luc Christnacher ,  Athanassios Tzikas ,  Georg Roentgen

Inventor： Hubert Jean Luc Christnacher ,  Athanassios Tzikas ,  Georg Roentgen

IPC: D06P1/38 ,  C09B44/00 ,  B05D5/00

CPC classification number: C09B62/043 ,  C09B62/4416 ,  Y10S8/918

Abstract: Reactive dyes of formula wherein B is an aliphatic bridging member, R1 is C1-C4alkyl, halogen or an —SO2—Z radical, R2 and R3 are each independently of the other C1-C4alkoxy, R4, R5 and R6 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, p is the number 0, 1 or 2, X1 and X2 are each independently of the other halogen, and T is halogen, a non-fibre-reactive substituent or a fibre-reactive radical of formula wherein (R7)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(Hal)-CH2-Hal or —C(Hal)=CH2 group and Hal is halogen, or T is a radical of formula wherein R1, R2, R3, R4, k, p and q each have the definitions given above, are suitable especially for dyeing cotton and yield dyeings having good all-round fastness properties.

Abstract translation: R 1为C 1 -C 4烷基，卤素或-SO 2 - Z基团，R 2和R 3各自独立地为C 1 -C 4烷氧基，R 4，R 5和R 6各自独立地为 其他氢或未取代或取代的C 1 -C 4烷基，k和q各自独立地为数字0或1，p为数0,1或2，X 1和X 2各自独立地为其它卤素，T为卤素 ，非光纤反应性取代基或下式的纤维反应性基团其中（R7）0-2表示0至2个相同或不同的取代基，如卤素，C 1 -C 4烷基，C 1 -C 4烷氧基和磺基，Z是乙烯基 或-CH 2 -CH 2 -U基团，U是在碱性条件下可除去的基团，Q是-CH（Hal）-CH 2 - Hal或-C（Hal）= CH 2基团，Hal是卤素，或T是 其中R1，R2，R3，R4，k，p和q各自具有上述定义的基团，其特别适用于染色棉花和具有良好全部成分的产量染色剂， 圆形坚牢性。

公开(公告)号：US07604669B2

公开(公告)日：2009-10-20

申请号：US12094429

申请日：2006-11-06

Applicant: Jean-Marie Sire ,  Athanassios Tzikas ,  Georg Roentgen

Inventor： Jean-Marie Sire ,  Athanassios Tzikas ,  Georg Roentgen

IPC: C09B62/00

CPC classification number: C09B62/4416 ,  C09B31/057 ,  C09B62/043 ,  C09B62/095 ,  C09B62/4413 ,  C09B62/4415 ,  C09B67/0047 ,  Y10S8/918

Abstract: Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein B1, B2 and B3 are each independently of the others an organic bridging member, Q1 is C1-C4alkyl, halogen or a radical —SO2-Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2, R3, R4, R5, R6, R7, R8 and R9 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2, X3, X4, X5 and X6 are each independently of the others halogen, and T1, T2 and T3 are each independently of the others a non-fiber-reactive substituent or a fiber-reactive radical of formula wherein (R10)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C1-C4alkyl, C1-C4alkoxy and sulfo, Z is vinyl or a radical —CH2—CH2—U and U is a group removable under alkaline conditions, Q is a group —CH(Hal)-CH2-Hal or —C(Hal)=CH2, and Hal is halogen, are suitable especially for the dichromatic or trichromatic dyeing or printing of cellulosic fiber materials and yield dyeings or prints having good reproducibility and good all-round fastness properties.

Abstract translation: 染料混合物，包含至少一种式的染料和至少一种下式基团的染料，其中B1，B2和B3各自独立地为有机桥连构件，Q1为C1-C4烷基，卤素或-SO2- Z，Q2和Q3各自独立地为C 1 -C 4烷氧基，Q 4为C 1 -C 4烷氧基，C 1 -C 4烷基，卤素或磺基Q 5为C 1 -C 4烷氧基，C 1 -C 4烷基，C 1 -C 4烷酰基氨基，脲基，卤素或磺基， R 2，R 3，R 4，R 5，R 6，R 7，R 8和R 9各自独立地为氢或未取代或取代的C 1 -C 4烷基，k和q各自独立地为数个0或1，n和p分别为 独立于数字0,1或2，m是数字0,1,2或3，t是数字1,2或3，X1，X2，X3，X4，X5和X6各自独立于 其他卤素，T1，T2和T3各自独立地为非纤维反应性取代基或下式的纤维反应性基团其中（R 10）0-2表示0至2个相同或不同的取代基 卤素，C1-C4烷基，C1-C4烷氧基和磺基，Z是乙烯基或基团-CH2-CH2-U，U是在碱性条件下可除去的基团，Q是基团-CH（Hal）-CH 2 - Hal或-C（Hal）= CH2，Hal是卤素，特别适用于纤维素纤维材料的双色或三色染色或印花，并且具有良好的再现性和良好的全面牢固性能的产量染色或印花。

公开(公告)号：US20070113356A1

公开(公告)日：2007-05-24

申请号：US10583012

申请日：2004-12-08

Applicant: Veronique Hall-Goulle ,  Athanassios Tzikas

Inventor： Veronique Hall-Goulle ,  Athanassios Tzikas

IPC: D06M13/322 ,  C07H17/02

CPC classification number: D06M15/03

Abstract: A reactive polysaccharide derivative of formula (1a) or (1b), in which A is —O—, —S— or (1c), Q1 is hydrogen, the radical —B—A—Z, C1-C10aryl which is unsubstituted or substituted, C1-C12alkyl which may be interrupted by oxygen and is unsubstituted or substituted, Q2 and Q3 are each independently of the other hydrogen, C1-C12aryl which is unsubstituted or substituted, C1-C12alkyl which may be interrupted by oxygen and is unsubstituted or substituted, B is an aliphatic or aromatic bridge member, Z1 and Z2 are each independently of the other a reactive radical of the vinylsulfonyl series, the haloacryloyl series or the heterocyclic series, PS is a polysaccharide radical, m is 0, 1 or an integer greater than 1, n is 1 or an integer greater than 1, and the sum of n+m corresponds to the original number of hydroxy groups in the polysaccharide molecule, is useful as a finishing agent for textile fibers and for other applications.

Abstract translation: 式（1a）或（1b）的反应性多糖衍生物，其中A是-O-，-S-或（1c），Q 1是氢，基团-BAZ，C _{未被取代或取代的C 1 -C 12烷基，其可以被氧中断，未被取代或被取代，B是脂族或芳族桥连构件Z Z 1和Z 2各自独立地为乙烯基磺酰基系列的反应性基团，卤代丙烯酰基系列或杂环系列，PS为多糖基团，m为0， 1或大于1的整数，n为1或大于1的整数，n + m的和对应于多糖分子中原始的羟基数， 可用作纺织纤维和其他应用的整理剂。}

公开(公告)号：US20070032641A1

公开(公告)日：2007-02-08

申请号：US10576056

申请日：2004-10-11

Applicant: Athanassios Tzikas ,  Georg Roentgen ,  Laszlo Fekete

Inventor： Athanassios Tzikas ,  Georg Roentgen ,  Laszlo Fekete

IPC: C09D11/00 ,  C09B46/00

CPC classification number: D06P1/38 ,  C09B67/0072 ,  C09D11/32 ,  D06P3/10 ,  D06P3/66 ,  D06P5/30

Abstract: Dye mixtures comprising at least one dye of formula (1) together with at least one dye from the group of formulae (2a) and (2b), wherein the radicals are as defined in the claim, are suitable for dyeing or printing cellulosic fibre materials while having a good build-up behaviour and yield dyeings of a deep shade having good fastness properties.

Abstract translation: 包含至少一种式（1）染料与至少一种式（2a）和（2b）基团的染料的染料混合物，其中所述基团如权利要求中所定义，适用于染色或印刷纤维素纤维材料 同时具有良好的积聚行为和产生具有良好牢度性质的深色调的染色。