Copolymeric mordants
    52.
    发明授权
    Copolymeric mordants 失效
    共聚媒染剂

    公开(公告)号:US4424326A

    公开(公告)日:1984-01-03

    申请号:US361422

    申请日:1982-03-24

    IPC分类号: C08F226/06 G03C8/56 G03C1/40

    CPC分类号: C08F226/06 G03C8/56

    摘要: Copolymeric mordant materials containing recurring units according to the following formula are disclosed: ##STR1## In such copolymers, each of R.sup.1, R.sup.2 and R.sup.3 can independently be alkyl; substituted alkyl; cycloalkyl; aryl; aralkyl; alkaryl; or at least two of R.sup.1, R.sup.2 and R.sup.3, together with the quaternary nitrogen atom to which they are bonded, can complete a saturated or unsaturated, substituted or unsubstituted nitrogen-containing heterocyclic ring; and X is an anion. The molar ratio of a:b can range from about 0.1:1 to about 10:1, e.g., about 0.3:1 to about 3:1. The copolymeric mordant materials can be utilized as image-receiving layers and in photographic products and processes of the diffusion transfer type. The mordants are especially adapted to the production of dye images free of objectionable haze, yellowing or related image defects.

    摘要翻译: 公开了含有根据下式的重复单元的共聚媒染材料:在这种共聚物中,R 1,R 2和R 3中的每一个可以独立地为烷基; 取代的烷基; 环烷基 芳基; 芳烷基 烷芳基 或R 1,R 2和R 3中的至少两个与它们所键合的季氮原子一起可以完成饱和或不饱和的,取代或未取代的含氮杂环; X为阴离子。 a:b的摩尔比可以为约0.1:1至约10:1,例如约0.3:1至约3:1。 共聚媒染材料可以用作图像接收层,以及在扩散转移型的照相产品和方法中。 媒染剂特别适用于不产生令人反感的浑浊,变黄或相关图像缺陷的染料图像。

    Temporary polymeric mordants and elements containing same
    53.
    发明授权
    Temporary polymeric mordants and elements containing same 失效
    临时聚合媒染剂和含有其的元素

    公开(公告)号:US4424272A

    公开(公告)日:1984-01-03

    申请号:US289289

    申请日:1981-08-03

    申请人: Lloyd D. Taylor

    发明人: Lloyd D. Taylor

    摘要: Polymeric mordants which are capable of converting to non-mordanting species in an alkaline environment are described. The mordants can be used in photographic elements to temporarily mordant a photographically useful dye material, such as a light-filter or anti-halation dye or a diffusion transfer image dye-providing material, and then release the dye material during processing of the element with an alkaline processing composition.

    摘要翻译: 描述了能够在碱性环境中转化为非媒染物质的聚合媒染剂。 媒染剂可用于照相元件中,以临时媒染一种照相用的染料材料,例如光过滤器或抗晕染染料或扩散转移图像染料提供材料,然后在加工元件期间释放染料, 碱性处理组合物。

    Diffusion transfer products with two timing layers for production of
transparencies
    55.
    发明授权
    Diffusion transfer products with two timing layers for production of transparencies 失效
    扩散转移产品具有两个时间层,用于生产透明胶片

    公开(公告)号:US4359517A

    公开(公告)日:1982-11-16

    申请号:US259102

    申请日:1981-04-30

    CPC分类号: G03C8/52 G03C8/56

    摘要: Image-receiving elements and photographic diffusion transfer products providing diffusion transfer transparency images are described. The image-receiving elements include a transparent support carrying, in sequence, an acid-reacting reagent; a first polymeric timing layer possessing decreasing alkaline solution permeability with increasing temperature; a second timing layer comprising cellulose acetate; and an alkaline solution-permeable and dyeable polymeric image-receiving layer comprising a graft polymer having a polymeric backbone and grafted thereto moieties which provide mordant capability. The utilization in the image-receiving elements of the aforedescribed first and second timing layers permits the provision of elements which can be effectively processed over a range of processing temperatures and which are adapted to the provision of transparencies which exhibit desired images without the distracting or otherwise objectionable image defects associated with reticulation.

    摘要翻译: 描述了提供扩散转移透明度图像的图像接收元件和照相扩散转移产物。 图像接收元件包括依次携带酸反应试剂的透明载体; 第一聚合时序层随温度升高而具有降低的碱溶液渗透性; 包含醋酸纤维素的第二时间层; 以及碱性溶液可渗透和可染色的聚合物图像接收层,其包含具有聚合物主链并接枝到其上的接枝聚合物,其提供媒染能力。 在上述第一和第二定时层的图像接收元件中的利用允许提供能够在一定范围的加工温度下有效处理的元件,并且适用于提供展现所需图像的透明胶片,而不会分心或以其他方式 与网状相关的令人反感的图像缺陷。

    Process for preparing cationic polymers
    56.
    发明授权
    Process for preparing cationic polymers 失效
    制备阳离子聚合物的方法

    公开(公告)号:US4340522A

    公开(公告)日:1982-07-20

    申请号:US142637

    申请日:1980-04-22

    摘要: A process for preparing a solution of a copolymer of a vinylpyridine and an ethylenically-unsaturated copolymerizable vinylbenzyl quaternary salt is disclosed. The process comprises polymerizing, in the presence of a polymerization medium comprising water and a lower alcohol, a vinylpyridine and a copolymerizable vinylbenzyl quaternary ammonium salt having the formula ##STR1## wherein each of R.sup.1, R.sup.2 and R.sup.3 is independently alkyl; substituted alkyl; cycloalkyl; aryl; aralkyl; alkaryl, or at least two of R.sup.1, R.sup.2 and R.sup.3 together with the quaternary nitrogen atom to which they are bonded complete a saturated or unsaturated, substituted or unsubstituted nitrogen-containing heterocyclic ring. The process provides the desired copolymer in the form of a clear solution useful in the formation of polymeric coatings or layers utilized as image-receiving layers in photographic products and processes.

    摘要翻译: 公开了一种制备乙烯基吡啶和烯属不饱和可共聚的乙烯基苄基季盐的共聚物溶液的方法。 该方法包括在包含水和低级醇的聚合介质,乙烯基吡啶和具有下式的可共聚的乙烯基苄基季铵盐的存在下聚合:其中R1,R2和R3各自独立地为烷基; 取代的烷基; 环烷基 芳基; 芳烷基 烷芳基或R 1,R 2和R 3中的至少两个与它们所键合的季氮原子一起形成饱和或不饱和的,取代或未取代的含氮杂环。 该方法提供所需的共聚物,其形式为可用于形成用作摄影产品和方法中的图像接收层的聚合物涂层或层。

    Photographic elements containing polymers which coordinate with metal
ions
    57.
    发明授权
    Photographic elements containing polymers which coordinate with metal ions 失效
    含有与金属离子配位的聚合物的摄影元素

    公开(公告)号:US4299895A

    公开(公告)日:1981-11-10

    申请号:US102099

    申请日:1979-12-10

    摘要: A photographic element comprising a support, a layer containing an image dye ligand or dye ligand forming material and a layer containing a dye mordant, wherein the mordant layer has associated therewith:(1) a polymer containing groups which form coordination complexes with metal ions; and(2) a source of metal ions.The polymer holds the metal ions in the vicinity of the dye mordant so that the metal ions can metallize the dye or dye forming material at the image receiving layer. These complexes, elements, and receiving elements are particularly useful in diffusion transfer processes. Novel polymers are also described.

    摘要翻译: 包含载体,含有图像染料配体或染料配体形成材料的层和含有染料媒染剂的层的照相元件,其中所述媒染剂层具有相关联:(1)含有与金属离子形成配位络合物的基团的聚合物; 和(2)金属离子源。 聚合物将金属离子保持在染料媒染剂附近,使得金属离子可以在图像接收层上对染料或染料形成材料进行金属化。 这些络合物,元素和接收元素在扩散转移过程中特别有用。 还描述了新型聚合物。

    Non-photosensitive receptor material suited for producing
black-and-white silver images and dye images and a process for the
production of such images therewith
    58.
    发明授权
    Non-photosensitive receptor material suited for producing black-and-white silver images and dye images and a process for the production of such images therewith 失效
    适用于生产黑白银图像和染料图像的非光敏受体材料以及用于生产这种图像的方法

    公开(公告)号:US4288522A

    公开(公告)日:1981-09-08

    申请号:US114082

    申请日:1980-01-22

    CPC分类号: G03C8/56 G03C8/28

    摘要: Receptor material adapted for use in a combined dye transfer and silver complex diffusion transfer process, comprising in order:(i) a support,(ii) a first hydrophilic colloid layer containing a cationic compound capable of mordanting an acid dye, and(iii) a transparent second hydrophilic colloid layer containing development nuclei for catalyzing the reduction therein of silver complex salts to silver and at least one organic compound having an anionic group linked to a carbon atom. The use of the receptor material for the production of a black-and-white silver image in combination with one or more dye images results in silver images of increased density.

    摘要翻译: 适用于组合染料转移和银络合物扩散转移方法的受体材料,其顺序包括:(i)载体,(ii)含有能够赋予酸性染料的阳离子化合物的第一亲水胶体层,和(iii) 透明的第二亲水胶体层,其含有用于催化将银络合盐还原成银的显影核和至少一种具有与碳原子连接的阴离子基团的有机化合物。 使用受体材料制造黑色和白色银色图像与一种或多种染料图像相结合产生增加密度的银图像。

    Photographic element comprising quaternary nitrogen polymeric mordant
    59.
    发明授权
    Photographic element comprising quaternary nitrogen polymeric mordant 失效
    包含季氮聚合物媒染剂的摄影元件

    公开(公告)号:US4147548A

    公开(公告)日:1979-04-03

    申请号:US897456

    申请日:1978-04-18

    摘要: A photographic element comprising a support having thereon at least one layer containing a polymeric mordant containing a repeating unit represented by the general formula (I): ##STR1## wherein R.sub.1 and R.sub.2, which may be the same or different, each represents a hydrogen atom or a lower alkyl group having 1 to 6 carbon atoms; R.sub.3 and R.sub.4, which may be the same or different, each represents a methyl group or an ethyl group; Y represents a halogen atom, a nitro group, a cyano group, a methoxy group, a methoxycarbonyl group or an ethylthio group; and X.crclbar. represents an anion.

    摘要翻译: 一种照相元件,包括其上具有至少一层含有由通式(I)表示的重复单元的聚合物媒染剂的层的载体:其中R1和R2可以相同或不同,各自表示 氢原子或碳原子数1〜6的低级烷基; R 3和R 4可以相同或不同,表示甲基或乙基; Y表示卤素原子,硝基,氰基,甲氧基,甲氧基羰基或乙硫基; X( - )表示阴离子。