公开(公告)号：US4683287A

公开(公告)日：1987-07-28

申请号：US895594

申请日：1986-08-14

Applicant: Joseph V. Koleske ,  Linda A. Domeier

Inventor： Joseph V. Koleske ,  Linda A. Domeier

IPC: C08F220/28 ,  C08F299/02 ,  C08G63/08 ,  C08G63/10

CPC classification number: C08F220/28 ,  C08F299/026 ,  C08G63/08

Abstract: Described herein are compositions containing a reactive monomer derived from the reaction product of a hydroxyalkyl acrylate or methacrylate and a lactone. These compositions can be reacted with other ethlenically unsaturated monomers to produce curable oligomers and polymers than can be made into high quality industrial finishes by incorporation of various conventional crosslinking agents, plus other normally used formulating ingredients.

Abstract translation: 本文描述的是含有源自丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯和内酯的反应产物的反应性单体的组合物。 这些组合物可以与其它不饱和单体反应生成可固化的低聚物和聚合物，而不仅仅是通过掺入各种常规的交联剂加其他通常使用的配方成分制成高质量的工业涂饰。

公开(公告)号：US4629779A

公开(公告)日：1986-12-16

申请号：US546113

申请日：1983-10-27

Applicant: Joseph V. Koleske

Inventor： Joseph V. Koleske

IPC: C08G18/58 ,  C08G59/14 ,  C08G63/91 ,  C09D161/20 ,  C09D163/00 ,  C09D167/00 ,  C09D167/04 ,  C09D175/00 ,  C09D175/04 ,  C08G59/00 ,  C08G59/68 ,  C08G65/04

CPC classification number: C09D163/00

Abstract: This invention is directed to adducts of a polycaprolactone polyol and a polyepoxide comprising the reaction product of at least one polycaprolactone polyol and a polyepoxide containing two or more epoxy groups per molecule in a molar ratio of polycaprolactone polyol to polyepoxide of from about 2:1 to about 3:1, said adducts having an oxirane content of less than about 0.10 percent and a viscosity of less than about 3700 centistokes at 54.5.degree. C. The adducts are useful in the formulation of high solids coating compositions, polyurethane elastomers, inks, sealants, adhesives and the like.

公开(公告)号：US4622349A

公开(公告)日：1986-11-11

申请号：US464558

申请日：1983-02-07

Applicant: Joseph V. Koleske ,  Neil J. McCarthy, Jr.

Inventor： Joseph V. Koleske ,  Neil J. McCarthy, Jr.

IPC: C08F2/50 ,  C08F299/02 ,  C08G59/14 ,  C08G59/68 ,  C08G59/24 ,  C08G59/62

CPC classification number: C08G59/68 ,  C08F299/026 ,  C08G59/145

Abstract: Described herein are compositions suitable for photocopolymerization comprising (a) an epoxide containing two or more epoxy groups, and (b) a hydroxyl substituted cycloaliphatic monoepoxide. The composition may additionally contain a poly (active hydrogen) organic compound and/or a photoinitiator. A coating produced from such a composition has a good combination of properties. Especially preferred are compositions further containing a vinyl cycloaliphatic monoepoxide and diazonium or onium photoinitiator.

Abstract translation: 本文描述的是适用于光聚合的组合物，其包含（a）含有两个或多个环氧基的环氧化物和（b）羟基取代的脂环族单环氧化物。 该组合物可另外含有聚（活性氢）有机化合物和/或光引发剂。 由这种组合物制成的涂层具有良好的性能组合。 特别优选的是还含有乙烯基脂环族单环氧化物和重氮鎓或鎓光引发剂的组合物。

公开(公告)号：US4294746A

公开(公告)日：1981-10-13

申请号：US160287

申请日：1980-06-17

Applicant: Eskel B. Blair ,  Joseph V. Koleske

Inventor： Eskel B. Blair ,  Joseph V. Koleske

IPC: C08L33/00 ,  C08G18/00 ,  C08G18/58 ,  C08G59/00 ,  C08G59/62 ,  C08G59/68 ,  C08K5/16 ,  C08K5/29 ,  C08K5/315 ,  C08K7/14 ,  C08L7/00 ,  C08L21/00 ,  C08L33/02 ,  C08L33/18 ,  C08L63/00 ,  C08L67/00 ,  C08G59/72

CPC classification number: C08K5/29 ,  C08G18/58 ,  C08G59/68 ,  C08K5/315

Abstract: Described herein are stabilizers for curable compositions containing cycloaliphatic epoxides and a catalyst. A molded article produced from such a composition possesses high mechanical properties.

Abstract translation: 本文描述了含有脂环族环氧化物和催化剂的可固化组合物的稳定剂。 由这种组合物制成的成型体具有高机械性能。

公开(公告)号：US4163029A

公开(公告)日：1979-07-31

申请号：US898104

申请日：1978-04-20

Applicant: Oliver W. Smith ,  Joseph V. Koleske

Inventor： Oliver W. Smith ,  Joseph V. Koleske

IPC: C08G63/12 ,  C08G63/664 ,  C09D161/28 ,  C09D167/04 ,  C09D175/06 ,  C08L67/04 ,  C08G63/76 ,  C08L61/32

CPC classification number: C09D167/04 ,  C08G63/12 ,  C08G63/664 ,  C09D161/28 ,  C09D175/06

Abstract: High solids coating compositions comprising a polycaprolactone derivative and a mixture of a methylolated melamine and a low molecular weight polyol; and, optionally, solvent and catalyst. The polycaprolactone derivative used in the coating compositions is the reaction products of a polycaprolactone polyol, a diepoxide and an anhydride of a polycarboxylic acid; the polycaprolactone polyol has an average of at least two hydroxyl groups in the molecule, a hydroxyl number of from about 15 to about 600 and an average molecular weight of from about 290 to about 6,000. The carboxylic acid anhydride mentioned has at least one intramolecular carboxylic anhydride group. The polycaprolactone derivatives are water insoluble.

Abstract translation: 包含聚己内酯衍生物和羟甲基化三聚氰胺与低分子量多元醇的混合物的高固含量涂料组合物; 和任选的溶剂和催化剂。 用于涂料组合物中的聚己内酯衍生物是聚己内酯多元醇，二环氧化物和多元羧酸酐的反应产物; 聚己内酯多元醇在分子中平均具有至少两个羟基，羟基数为约15至约600，平均分子量为约290至约6,000。 所述羧酸酐具有至少一个分子内羧酸酐基团。 聚己内酯衍生物是水不溶性的。

公开(公告)号：US4137279A

公开(公告)日：1979-01-30

申请号：US864754

申请日：1977-12-27

Applicant: Oliver W. Smith ,  Joseph V. Koleske

Inventor： Oliver W. Smith ,  Joseph V. Koleske

IPC: C08G63/06 ,  C09D167/06 ,  C08L67/06

CPC classification number: C08G63/06 ,  C09D167/06

Abstract: Mixtures of the unsaturated maleic anhydride modified adduct of a polycaprolactone polyol and an ethylenically unsaturated monomer are copolymerized. The resulting polymers are useful as coatings or in the production of films and shaped molded articles.

Abstract translation: 聚己内酯多元醇和烯键式不饱和单体的不饱和马来酸酐改性加合物的混合物共聚。 所得聚合物可用作涂料或用于制备薄膜和成型模制品。