公开(公告)号：US5358051A

公开(公告)日：1994-10-25

申请号：US141442

申请日：1993-10-22

Applicant: Klein A. Rodrigues

Inventor： Klein A. Rodrigues

IPC: C09K8/512 ,  E21B33/138

CPC classification number: C09K8/512

Abstract: A method of forming a gel in the subsurface formation is provided whereby a self crosslinking monomer selected from hydroxy unsaturated carbonyl compounds is polymerized in the formation by a suitable initiator. In a preferred embodiment, the initiator is selected from ago compounds which are temperature activated over a range of temperatures. The method is particularly useful to substantially terminate or at least decrease the flow of water from a subterranean formation into a wellbore penetrating the formation

Abstract translation: 提供了一种在地下地层中形成凝胶的方法，其中选自羟基不饱和羰基化合物的自交联单体通过合适的引发剂在地层中聚合。 在优选的实施方案中，引发剂选自在温度范围内温度活化的化合物。 该方法特别有用于基本上终止或至少减少从地下地层到穿透地层的井筒中的水流

公开(公告)号：US08106118B2

公开(公告)日：2012-01-31

申请号：US12887028

申请日：2010-09-21

Applicant: Klein A. Rodrigues ,  James C. Long

Inventor： Klein A. Rodrigues ,  James C. Long

IPC: C08K5/405 ,  C08L67/00

CPC classification number: C08F220/04 ,  C03C25/28 ,  C03C25/40 ,  C08L33/14 ,  C08L43/04 ,  C08L2666/04 ,  C09J133/04 ,  Y10T428/2964

Abstract: A glass adhesion composition containing a copolymer having an acid and a substituted amide, silanol, or amine oxide functionality. The substituted amide, silanol, or amine oxide functionality provide excellent adhesion of the copolymer to glass, silica, sand and other silicon-based substances. The copolymer is useful as a fiberglass binder, and also useful in providing protective coatings on glass sheets. A fiberglass sizing composition is also provided having a copolymer that includes at least one acid group derived from at least one acid monomer, a hydrophobic comonomer, and a crosslinker. Additives can be added to the compositions to provide other functionality such as corrosion inhibitors, hydrophobic additives, additives for reducing leaching of glass, release agents, acids for lowering pH, anti-oxidants/reducing agents, emulsifiers, dyes, pigments, oils, fillers, colorants, curing agents, anti-migration aids, biocides, plasticizers, waxes, anti-foaming agents, coupling agents, thermal stabilizers, flame retardants, enzymes, wetting agents, and lubricants.

Abstract translation: 含有具有酸和取代酰胺，硅烷醇或胺氧化物官能团的共聚物的玻璃粘合组合物。 取代的酰胺，硅烷醇或胺氧化物官能团提供了共聚物对玻璃，二氧化硅，沙子和其它硅基物质的极好的粘附性。 共聚物可用作玻璃纤维粘合剂，也可用于在玻璃板上提供保护涂层。 还提供了具有包含至少一种衍生自至少一种酸单体，疏水性共聚单体和交联剂的酸基的共聚物的玻璃纤维上胶组合物。 可以向组合物中加入添加剂以提供其它功能，例如腐蚀抑制剂，疏水添加剂，用于减少玻璃浸出的添加剂，脱模剂，用于降低pH的酸，抗氧化剂/还原剂，乳化剂，染料，颜料，油，填料 ，着色剂，固化剂，抗迁移助剂，杀生物剂，增塑剂，蜡，消泡剂，偶联剂，热稳定剂，阻燃剂，酶，润湿剂和润滑剂。

公开(公告)号：US20120009279A1

公开(公告)日：2012-01-12

申请号：US13237817

申请日：2011-09-20

Applicant: Thomas W. Kaaret ,  Darin K. Griffith ,  Klein A. Rodrigues ,  William L. Smith

Inventor： Thomas W. Kaaret ,  Darin K. Griffith ,  Klein A. Rodrigues ,  William L. Smith

IPC: D06L3/08 ,  A01N59/00 ,  A01P1/00 ,  A61L2/18 ,  B08B3/00 ,  D06L1/16 ,  C11D3/60 ,  B82Y99/00

CPC classification number: C08F2/18 ,  C08F8/44 ,  C08F212/08 ,  C08F220/06 ,  C08F2800/20 ,  C11D3/3757 ,  C11D3/3765 ,  C11D3/3956 ,  C11D3/42 ,  C08F2/44

Abstract: The invention provides an aqueous bleaching solution for substrate treatment comprising a source of oxidant and a suspended polymer matrix having a plurality of optically functional particles associated with one or more copolymers present in the polymer matrix. The plurality of optically functional particles are associated with the copolymer during polymerization of at least one hydrophobic and at least one hydrophilic monomer so as to form a polymer matrix useful to impart an aqueous bleaching solution with optically functional properties providing a benefit to the solutions during storage, use and application to substrates for treatment. In accordance with various embodiments of the invention, the suspended polymer matrix forms a substantially stable dispersion of the optically functional particles in the aqueous bleaching solution, and provides compositions, methods and kits for employing aqueous bleaching solutions having optically functional properties that are maintained over substantially long storage times.

Abstract translation: 本发明提供了用于底物处理的水性漂白溶液，其包括氧化剂源和悬浮聚合物基质，其具有与存在于聚合物基质中的一种或多种共聚物相关联的多个光学功能性颗粒。 在至少一种疏水性和至少一种亲水性单体的聚合过程中，多种光学功能性颗粒与共聚物相关联，以便形成聚合物基质，其可用于赋予具有光学功能性质的水性漂白溶液以提供储存期间的溶液的益处 ，使用和应用于底物进行治疗。 根据本发明的各种实施方案，悬浮聚合物基质形成水性漂白溶液中的光学功能性颗粒的基本上稳定的分散体，并且提供了使用具有光学功能特性的水性漂白溶液的组合物，方法和试剂盒， 长存储时间。

公开(公告)号：US20110085995A1

公开(公告)日：2011-04-14

申请号：US12973084

申请日：2010-12-20

Applicant: Klein A. Rodrigues ,  Darin K. Griffith

Inventor： Klein A. Rodrigues ,  Darin K. Griffith

IPC: C08F2/04 ,  A61K8/81 ,  C11D3/37 ,  B01J13/18

CPC classification number: C08F220/06 ,  C08F2/18 ,  C08F8/44 ,  C11D3/3757 ,  Y10T428/3162 ,  Y10T428/3163 ,  Y10T428/31692 ,  Y10T428/31855

Abstract: A self-stabilizing dispersion composition having a copolymer having at least one polymerizable acid-containing moiety, wherein the at least one acid-containing moiety is at least partially neutralized before or during polymerization, and at least one hydrophobic moiety. A process for producing such compositions is also provided, as well as a process for encapsulating water-insoluble actives in such copolymers.

Abstract translation: 一种自稳定分散体组合物，其具有含至少一个含可聚合酸的部分的共聚物，其中所述至少一个含酸部分在聚合之前或期间至少部分中和，以及至少一个疏水部分。 还提供了一种制备这种组合物的方法，以及一种将水不溶性活性物质包封在这种共聚物中的方法。

公开(公告)号：US06867173B2

公开(公告)日：2005-03-15

申请号：US10239047

申请日：2001-03-27

Applicant: Klein A. Rodrigues

Inventor： Klein A. Rodrigues

IPC: C11D3/37 ,  C11D11/00 ,  C11D3/34 ,  B08D3/04

CPC classification number: C11D11/0023 ,  C11D3/3757 ,  C11D3/378

Abstract: An automatic dishwashing composition is presented having 0.01 to 90 percent by weight of a detergency builder and 0.1 to 20 percent by weight of at least one polymer, wherein said polymer or polymers comprises carboxylate groups and sulfonate groups. The composition is useful in liquid, tablet and granular compositions. The composition reduces filming and spotting of glass and plastics.

Abstract translation: 提供了一种自动餐具洗涤组合物，其具有0.01至90重量％的洗涤助洗剂和0.1至20重量％的至少一种聚合物，其中所述聚合物或聚合物包含羧酸盐基团和磺酸盐基团。 该组合物可用于液体，片剂和颗粒组合物。 该组合物减少了玻璃和塑料的成膜和斑点。

公开(公告)号：US06498136B2

公开(公告)日：2002-12-24

申请号：US09274977

申请日：1999-03-23

Applicant: Klein A. Rodrigues

Inventor： Klein A. Rodrigues

IPC: C11D337

CPC classification number: C11D3/228 ,  C11D3/373 ,  C11D3/3761 ,  C11D3/3769 ,  C11D3/378

Abstract: A powder detergent composition which is effective for removing and dispersing organic non-polar and polar soils from fabrics in wash liquors. The powder detergent composition comprises a polymer having a hydrophilic backbone and at least one hydrophobic moiety. The hydrophilic backbone is prepared from a monomer selected from ethylenically unsaturated hydrophilic monomers, polymerizable hydrophilic cyclic monomers, and non-ethylenically unsaturated polymerizable hydrophilic monomers selected from glycerol and other polyhydric alcohols. The hydrophobic moiety is prepared from a monomer selected from siloxanes, saturated or unsaturated alkyl and hydrophobic alkoxygroups, aryl and aryl-alkyl groups. The polymers also boost the cleaning performance of hard surface and dishware detergent compositions.

Abstract translation: 一种粉末洗涤剂组合物，其有效地从洗涤液中除去和分散织物中的有机非极性和极性污垢。 粉末洗涤剂组合物包含具有亲水性主链和至少一个疏水部分的聚合物。 亲水性主链由选自烯属不饱和亲水单体，可聚合亲水环状单体和选自甘油和其他多元醇的非烯属不饱和可聚合亲水单体的单体制备。 疏水部分由选自硅氧烷，饱和或不饱和的烷基和疏水性烷氧基，芳基和芳基 - 烷基的单体制备。 聚合物还提高了硬表面和餐具洗涤剂组合物的清洁性能。

公开(公告)号：US06369023B1

公开(公告)日：2002-04-09

申请号：US09225768

申请日：1999-01-05

Applicant: Klein A. Rodrigues ,  Allen M. Carrier ,  Michael C. Hazlewood

Inventor： Klein A. Rodrigues ,  Allen M. Carrier ,  Michael C. Hazlewood

IPC: C11D338

CPC classification number: D06M15/53 ,  D06M15/263

Abstract: The use of polyether hydroxycarboxylate copolymers in textile manufacturing and treating processes. The polyether hydroxycarboxylate copolymer has the structure wherein M+ is a cation wherein M is independently selected from the group consisting of hydrogen, ammonia, alkali metals, alkaline earth metals, zinc, copper, organic amines, amino acids, and amino saccharides; R1 is the residue of an ethylenically unsaturated comonomer having at least one functional group which is selected from the group consisting of carboxylic acid, sulfonic acid and phosphonic acid; R2 and R3 are independently selected from the group consisting of hydrogen, and a substituted or unsubstituted alkyl group having 1 to 4 carbon atoms; n is from about 2 to about 100; X1 and X2 are independently 0 or 1; a is from 0 to 100 mole percent; and b is from 100 to 0 mole percent, provided that (a+b) is 100 mole percent. The copolymers chelate heavy metal ions forming soluble complexes which help stabilize bleach, reduce scale, prevent redeposition of particulate soils, prevent deposition of metals, and disperse dyes.

Abstract translation: 聚醚羟基羧酸酯共聚物在纺织品制造和处理过程中的应用。 聚醚羟基羧酸酯共聚物具有其中M +为阳离子的结构，其中M独立地选自氢，氨，碱金属，碱土金属，锌，铜，有机胺，氨基酸和氨基糖; R1是具有至少一个选自羧酸，磺酸和膦酸的官能团的烯属不饱和共聚单体的残基; R2和R3独立地选自氢和取代或未取代的具有1至4个碳原子的烷基; n为约2至约100; X1和X2独立地为0或1; a为0〜100摩尔％ 并且b为100至0摩尔％，条件是（a + b）为100摩尔％。 共聚物螯合形成可溶性络合物的重金属离子，有助于稳定漂白，减少垢，防止颗粒污垢的再沉积，防止金属沉积和分散染料。

公开(公告)号：US06337313B1

公开(公告)日：2002-01-08

申请号：US09441714

申请日：1999-11-16

Applicant: Klein A. Rodrigues

Inventor： Klein A. Rodrigues

IPC: C11D337

CPC classification number: D06P5/158 ,  D06L1/14 ,  D06L4/12 ,  D06M11/40 ,  D06M15/03 ,  D06M15/09 ,  D06M15/227 ,  D06M15/233 ,  D06M15/263 ,  D06M15/27 ,  D06M15/285 ,  D06M15/333 ,  D06M15/353 ,  D06M15/3562 ,  D06M15/3566 ,  D06M15/53 ,  D06P1/16 ,  D06P1/228 ,  D06P1/48 ,  D06P1/50 ,  D06P1/5207 ,  D06P1/5221 ,  D06P1/5228 ,  D06P1/5242 ,  D06P1/525 ,  D06P1/5257 ,  D06P1/613 ,  D06P5/08

Abstract: A method to prevent the backstaining of denim during a stonewashing process comprising treating the denim with a solution or dispersion of a hydrophobically modified polymer having a hydrophilic backbone and at least one hydrophobic moiety, wherein said hydrophilic backbone is prepared from at least one monomer selected from the group consisting of ethylenically unsaturated hydrophilic monomer selected from the group consisting of unsaturated C1-C6 acid, amide, ether, alcohol, aldehyde, anhydride, ketone and ester; polymerizable hydrophilic cyclic monomer; non-ethylenically unsaturated polymerizable hydrophilic monomer which is selected from the group consisting of glycerol and other polyhydric alcohols; and combinations thereof, wherein said hydrophilic backbone is optionally substituted with one or more amino, amine, amide, sulfonate, sulfate, phosphonate, hydroxy, carboxyl or oxide groups; wherein said hydrophobic moiety is prepared from at least one hydrophobic monomer or a chain transfer agent, said hydrophobic monomer is selected from the group consisting of a siloxane, saturated or unsaturated alkyl and hydrophobic alkoxygroup, aryl and aryl-alkyl group, alkyl sulfonate, aryl sulfonate, and combinations thereof, and said chain transfer agent has 1 to 24 carbon atoms and is selected from the group consisting of a mercaptan, amine, alcohol, and combinations thereof, wherein said hydrophobically modified polymer is present in an amount of from 0.001 to 50 weight percent, based on the total weight of the solution or dispersion.

Abstract translation: 一种防止在石洗过程中对牛仔布进行背面染色的方法，包括用具有亲水主链和至少一个疏水部分的疏水改性聚合物的溶液或分散体处理牛仔布，其中所述亲水性主链由至少一种选自 由不饱和C 1 -C 6酸，酰胺，醚，醇，醛，酸酐，酮和酯组成的组中的烯属不饱和亲水单体组成的组; 可聚合的亲水环状单体; 非烯属不饱和可聚合亲水单体，其选自甘油和其他多元醇; 其中所述亲水性骨架任选被一个或多个氨基，胺，酰胺，磺酸盐，硫酸盐，膦酸盐，羟基，羧基或氧化物基团取代; 其中所述疏水部分由至少一种疏水性单体或链转移剂制备，所述疏水性单体选自硅氧烷，饱和或不饱和的烷基和疏水性烷氧基，芳基和芳基 - 烷基，烷基磺酸酯，芳基 磺酸盐及其组合，所述链转移剂具有1至24个碳原子，并且选自硫醇，胺，醇及其组合，其中所述疏水改性聚合物的存在量为0.001至 50重量％，基于溶液或分散体的总重量。

公开(公告)号：US06291594B1

公开(公告)日：2001-09-18

申请号：US09047051

申请日：1998-03-24

Applicant: Klein A. Rodrigues

Inventor： Klein A. Rodrigues

IPC: C08F12008

CPC classification number: D06M15/53 ,  D06M15/233 ,  D06M15/263 ,  D06M15/27 ,  D06M15/285 ,  D06M2200/40

Abstract: Compositions useful for textile sizes which contain anhydride based graft copolymers. The anhydride based graft copolymers are the reaction product of an ethylenically unsaturated monomer, an anhydride monomer selected from maleic anhydride and itaconic anhydride, either a monofunctional polyglycol having a hydroxyl or amine terminal group or a polyfunctional polyglycol having a weight average molecular weight of greater than 5,000 and at least one terminal hydroxyl group, and a free radical initiator. The anhydride based graft copolymers provide lubrication during sizing and a thorough removal of waxes and oils during desizing and scouring.

Abstract translation: 可用于含有酸酐基接枝共聚物的纺织品尺寸的组合物。 基于酸酐的接枝共聚物是烯键式不饱和单体，选自马来酸酐和衣康酸酐的酸酐单体，具有羟基或胺末端基团的单官能聚二醇或重均分子量大于的多官能聚乙二醇的反应产物 5,000和至少一个末端羟基，以及自由基引发剂。 基于酸酐的接枝共聚物在上浆过程中提供润滑，并在脱浆和精练期间彻底除去蜡和油。

公开(公告)号：US06228783B1

公开(公告)日：2001-05-08

申请号：US09223942

申请日：1998-12-31

Applicant: Alvie L. Foster, Jr. ,  Ivonne C. Weidner ,  Klein A. Rodrigues ,  Allen M. Carrier

Inventor： Alvie L. Foster, Jr. ,  Ivonne C. Weidner ,  Klein A. Rodrigues ,  Allen M. Carrier

IPC: C08G1200

CPC classification number: C11D3/0021 ,  C11D3/3723 ,  C11D17/049 ,  Y10T442/2508 ,  Y10T442/2582 ,  Y10T442/2861 ,  Y10T442/2918

Abstract: A laundry article effective for inhibiting transfer of extraneous dyes and soil to articles in a wash liquor, said laundry article comprising a support matrix and a functionalized polyamine attached to or entrapped in the support matrix. The functionalized polyamine comprises the reaction product of (A) a cyano- or guanidino-containing compound and (B) a polyamine prepared from at least one monomeric amine. The laundry article inhibits dye transfer, soil redeposition, and provides color protection to fabrics in a wash liquor. In addition, the laundry article does not interfere with the removal of stains from fabrics washed in the presence of the laundry article. Furthermore, the laundry article containing the functionalized polyamines are economical and environmentally safe.

Abstract translation: 一种洗衣物品，其有效地用于抑制洗涤液中的外来染料和污物转移到物品上，所述洗衣物品包括附着在或包埋在载体基质中的载体基质和官能化多胺。 官能化的多胺包括（A）含氰基或胍基的化合物和（B）由至少一种单体胺制备的多胺的反应产物。 洗衣物品抑制染料转移，污垢再沉积，并为洗涤液中的织物提供颜色保护。 此外，洗衣物品不妨碍在洗涤物品的存在下洗涤的织物上的污渍的去除。 此外，含有官能化多胺的衣物是经济且环境安全的。