公开(公告)号：US20120160438A1

公开(公告)日：2012-06-28

申请号：US13264476

申请日：2010-03-16

申请人： Sheldon Phillip Verrett

发明人： Sheldon Phillip Verrett

IPC分类号： D21H17/24

CPC分类号： D21C3/226 ,  C02F5/10 ,  C02F5/125 ,  C02F5/14 ,  C02F5/145 ,  C02F2103/28 ,  D21C9/008 ,  D21C9/08 ,  D21C9/086 ,  D21C11/106 ,  Y10S210/928

摘要： A method for inhibiting the formation, deposition and adherence of calcium salt scale to metallic and other surfaces in the equipment, vessels and/or piping of a chemical pulp process facility comprising adding an effective scale inhibiting amount of a composition to the alkaline aqueous mixture in the digester of said chemical pulping process. Said composition consists of at least one phosphonate component (I) and at least one component (II) consisting of at least one carboxylated fructan compound.

摘要翻译： 一种用于抑制钙盐垢在化学纸浆加工设备的设备，容器和/或管道中的金属和其它表面的形成，沉积和粘附的方法，包括向碱性水性混合物中加入有效的阻垢量的组合物 所述化学制浆工艺的消化器。 所述组合物由至少一种膦酸酯组分（I）和至少一种由至少一种羧化果聚糖化合物组成的组分（II）组成。

公开(公告)号：US07932091B2

公开(公告)日：2011-04-26

申请号：US11700643

申请日：2007-01-31

申请人： Timothy Keister

发明人： Timothy Keister

IPC分类号： G01N35/08 ,  G01N21/00

CPC分类号： G01N21/31 ,  C02F1/50 ,  C02F5/08 ,  C02F5/125 ,  C02F5/145 ,  C02F2103/023 ,  C02F2303/08 ,  G01N21/85 ,  Y10T436/12 ,  Y10T436/13

摘要： Water-based colorant traced formulations (products) containing one or more water treatment agents, such as phosphonates, polyacrylic acids and/or polymers, co-polymers, terpolymers thereof, azoles, molybdate, polysilicates, phosphates, zinc, polyphosphates, etc., are provided wherein the water-soluble colorant is detectable in the visible light range of about 580-640 nm and is chemically inert relative to the water treatment agent(s). Measurement of an optical property of the colorant in the treated coolant water permits the concentration of the product therein to be ascertained, and the level of the product containing can be adjusted for controlling scale, corrosion, deposition, and/or microbial activity in commercial and/or industrial cooling water systems. These products may be reliably monitored and dosed to maintain a product level in treated water of 5 to 500 mg/L.

摘要翻译： 含有一种或多种水处理剂的水性着色剂追踪配方（产品），例如膦酸盐，聚丙烯酸和/或聚合物，共聚物，其三元共聚物，唑类，钼酸盐，聚硅酸盐，磷酸盐，锌，聚磷酸盐等， 其中所述水溶性着色剂在约580-640nm的可见光范围内是可检测的并且相对于水处理剂是化学惰性的。 在处理过的冷却水中测量着色剂的光学性能可以确定其中产品的浓度，并且可以调节含有产品的含量以控制商业和商业中的污垢，腐蚀，沉积和/或微生物活性 /或工业冷却水系统。 这些产品可以可靠地监测和剂量以维持处理水中的产品水平为5至500mg / L。

公开(公告)号：US20100006800A1

公开(公告)日：2010-01-14

申请号：US12584762

申请日：2009-09-11

申请人： Timothy E. Keister

发明人： Timothy E. Keister

IPC分类号： C02F5/10

CPC分类号： C02F1/42 ,  C02F1/50 ,  C02F5/145

摘要： A method and composition are provided for the operation of an evaporative cooling tower with minimal, or no, blowdown. In some embodiments, the method involves using sodium cation-exchanged softened water as makeup water for the cooling tower, providing a bypass filter for suspended solids removal from the cooling water, treating the cooling water with a composition for control of corrosion and deposition, and using an effective biocide for control of biological growth within the cooling tower system. In some embodiments, a composition is provided that comprises AMPS acrylic terpolymer, sodium silicate, phosphate ions, and polyphosphate ions. When dosed at the recommended levels, the composition controls corrosion of cooling system materials to generally acceptable levels in spite of the extremely corrosive environment resulting from the cycling of sodium cation-exchanged softened water in the cooling tower.

摘要翻译： 提供了一种方法和组合物，用于具有最少或没有排污的蒸发冷却塔的操作。 在一些实施方案中，该方法包括使用钠阳离子交换的软化水作为冷却塔的补充水，提供用于从冷却水中除去悬浮固体的旁路过滤器，用用于控制腐蚀和沉积的组合物处理冷却水，以及 使用有效的杀生物剂来控制冷却塔系统内的生物生长。 在一些实施方案中，提供了包含AMPS丙烯酸三元共聚物，硅酸钠，磷酸根离子和多磷酸根离子的组合物。 当以推荐水平给药时，组合物将冷却系统材料的腐蚀控制在通常可接受的水平，尽管由于在冷却塔中钠阳离子交换的软化水的循环导致极度腐蚀性的环境。

公开(公告)号：US07595000B2

公开(公告)日：2009-09-29

申请号：US12070794

申请日：2008-02-21

申请人： Timothy E. Keister

发明人： Timothy E. Keister

IPC分类号： C02F1/42

CPC分类号： C02F1/42 ,  C02F1/50 ,  C02F5/145

摘要： A method and composition are provided for the operation of an evaporative cooling tower with minimal, or no, blowdown. In some embodiments, the method involves using sodium cation-exchanged softened water as makeup water for the cooling tower, providing a bypass filter for suspended solids removal from the cooling water, treating the cooling water with a composition for control of corrosion and deposition, and using an effective biocide for control of biological growth within the cooling tower system. In some embodiments, a composition is provided that comprises AMPS acrylic terpolymer, sodium silicate, phosphate ions, and polyphosphate ions. When dosed at the recommended levels, the composition controls corrosion of cooling system materials to generally acceptable levels in spite of the extremely corrosive environment resulting from the cycling of sodium cation-exchanged softened water in the cooling tower.

摘要翻译： 提供了一种方法和组合物，用于具有最少或没有排污的蒸发冷却塔的操作。 在一些实施方案中，该方法包括使用钠阳离子交换的软化水作为冷却塔的补充水，提供用于从冷却水中除去悬浮固体的旁路过滤器，用用于控制腐蚀和沉积的组合物处理冷却水，以及 使用有效的杀生物剂来控制冷却塔系统内的生物生长。 在一些实施方案中，提供了包含AMPS丙烯酸三元共聚物，硅酸钠，磷酸根离子和多磷酸根离子的组合物。 当以推荐水平给药时，组合物将冷却系统材料的腐蚀控制在通常可接受的水平，尽管由于在冷却塔中钠阳离子交换的软化水的循环导致极度腐蚀性的环境。

公开(公告)号：US07297257B1

公开(公告)日：2007-11-20

申请号：US11419732

申请日：2006-05-22

申请人： LeRoy Henery Terry

发明人： LeRoy Henery Terry

IPC分类号： C02F5/00

CPC分类号： C02F5/145 ,  C02F1/688 ,  C02F2201/006 ,  Y10T137/4891

摘要： A mechanical release system and method for eliminating scale conditions in water are described. The mechanical release system may include a pressure vessel comprising a head that has a through hole extending from an inlet to an outlet on opposite sides of the head, the through hole divided by at least a circumferential partial rib into an inlet section and an outlet section. Implementations may work without restricting water flow or “water-starving” equipment and control water before it enters equipment and create a scale-eliminating environment within water for extended periods of time (e.g., up to six months or more).

摘要翻译： 描述了用于消除水中的水垢状况的机械释放系统和方法。 机械释放系统可以包括压力容器，该压力容器包括头部，该头部具有从头部的相对侧上的入口到出口延伸的通孔，所述通孔至少由周向部分肋分隔成入口部分和出口部分 。 在水进入设备并在水中长时间（例如至多六个月或更长时间）之间形成消除水垢的环境时，实施可能会在不限制水流或“水淹没”设备的情况下工作。

公开(公告)号：US06331513B1

公开(公告)日：2001-12-18

申请号：US09301248

申请日：1999-04-28

申请人： Gene H. Zaid ,  Beth Ann Wolf

发明人： Gene H. Zaid ,  Beth Ann Wolf

IPC分类号： C02F510

CPC分类号： C02F5/10 ,  C02F1/683 ,  C02F5/14 ,  C02F5/145 ,  C02F2209/06 ,  C09K8/528 ,  C23G1/14 ,  Y10S423/14 ,  Y10S507/927

摘要： A scale dissolver composition and method for using the composition is provided. Broadly, the dissolver compositions are formed by adding a base such as ammonium hydroxide to a mixture comprising a salt of a chelating agent, a carbonate, and a component selected from the group consisting of organophosphorus compounds, carboxylic acids, and mixtures thereof. The preferred organophosphorus compound is aminotristmethylidine diphosphonic acid while the preferred chelating agent salt is EDTA tetrasodium salt. In use, the dissolver composition is preferably heated to a temperature of from about 100-170° F. and then contacted with the target scale. The compositions are particularly useful for removing barium sulfate and calcium sulfate scales from gas and oil well and pipeline equipment in an efficient and cost-effective manner.

摘要翻译： 提供了一种使用该组合物的鳞屑溶解器组合物和方法。 广泛地，通过将​​诸如氢氧化铵的碱加入到包含螯合剂，碳酸盐和选自有机磷化合物，羧酸及其混合物的组分的组分的混合物中来形成溶解组合物。 优选的有机磷化合物是氨基三甲基二膦酸，而优选的螯合剂盐是EDTA四钠盐。 在使用中，溶解组合物优选加热至约100-170°F的温度，然后与目标垢接触。 该组合物特别可用于以高效和成本有效的方式从气井和油井以及管道设备中除去硫酸钡和硫酸钙。

公开(公告)号：US4869827A

公开(公告)日：1989-09-26

申请号：US197069

申请日：1988-05-18

申请人： Harold A. Chagnard, Jr. ,  Mark K. Brayden ,  Thomas R. LeBlanc

发明人： Harold A. Chagnard, Jr. ,  Mark K. Brayden ,  Thomas R. LeBlanc

IPC分类号： C02F5/14 ,  C23F11/08 ,  F02B75/02

CPC分类号： C23F11/08 ,  C02F5/145 ,  F02B2075/027

摘要： This invention relates to an improved composition and method which inhibit the corrosion of and the formation of scale on metals present in an aqueous system. The composition comprises a water soluble copolymer having moieties derived from acrylic acid and from lower alkyl hydroxy acrylates, and a combination of a manganese compound and an aminoalkylenephosphonic acid derivative or its salts.

摘要翻译： 本发明涉及一种改进的组合物和方法，其抑制在水性体系中存在的金属上的氧化皮的腐蚀和形成。 该组合物包含具有衍生自丙烯酸和低级烷基羟基丙烯酸酯的部分的水溶性共聚物，以及锰化合物和氨基亚烷基膦酸衍生物或其盐的组合。

公开(公告)号：US4671934A

公开(公告)日：1987-06-09

申请号：US853612

申请日：1986-04-18

申请人： John P. Terry ,  Oscar W. May

发明人： John P. Terry ,  Oscar W. May

IPC分类号： C02F5/00 ,  C02F5/08 ,  C02F5/10 ,  C02F5/12 ,  C02F5/14 ,  C23F11/08 ,  C23F11/167 ,  C23F11/18 ,  C23F11/16 ,  C02F1/00 ,  C09K3/00

CPC分类号： C23F11/08 ,  C02F5/145 ,  C23F14/02

摘要： A method of controlling the corrosion of a metal surface in contact with an aqueous system while at the same time preventing the precipitation of potentially scale-forming calcium phosphate. The water in such systems is treated with a combination of a source of orthophosphate ion and a mixture of methylene phosphonic acid derivatives of C.sub.6 diamines, or the salts thereof. A composition for preventing the precipitation of calcium phosphate containing a mixture of methylene phosphonic acid derivatives of C.sub.6 diamines or the salts thereof.

公开(公告)号：US4606890A

公开(公告)日：1986-08-19

申请号：US584055

申请日：1984-02-27

申请人： Peter R. Fisk

发明人： Peter R. Fisk

IPC分类号： C02F5/14 ,  C23C22/83 ,  C23F11/08 ,  C23F11/167 ,  C23F11/16

CPC分类号： C02F5/145 ,  C23C22/83 ,  C23F11/08 ,  C23F11/1676

摘要： Process for conditioning metal surfaces to inhibit their corrosion and/or to inhibit scale deposition thereon by treating said surfaces:(A) prior to contact with a corrosive or scaling environment, with 2-hydroxy-phosphonoacetic acid or a metal salt thereof and optionally with a metal ion component (b) as hereinafter defined(B) during contact with an aqueous system capable of corroding said metal surfaces or depositing scale thereon, with a combination of:(a) 2-hydroxy-phosphonacetic acid or a water-soluble salt thereof; and(b) a metal ion which enhances, synergistically, the metal conditioning effected, individually, by 2-hydroxy-phosphonoacetic acid and the metal ion.

摘要翻译： 用于通过处理所述表面来调节金属表面以抑制其腐蚀和/或抑制其沉积物沉积的方法：（A）在与腐蚀性或结垢环境接触之前，用2-羟基 - 膦酰基乙酸或其金属盐和任选地与 在与能够腐蚀所述金属表面或沉积在其上的水系统接触期间，以下定义的（B）金属离子组分（b），其组合为：（a）2-羟基 - 膦酸或水溶性盐 的; 和（b）金属离子，其增强协同地由2-羟基 - 膦酰基乙酸和金属离子分别进行的金属调节。

公开(公告)号：US4384979A

公开(公告)日：1983-05-24

申请号：US317965

申请日：1981-11-04

申请人： Gerald D. Hansen

发明人： Gerald D. Hansen

IPC分类号： C02F1/10 ,  C02F5/14 ,  C23F11/08 ,  C23F11/16 ,  C23F11/12

CPC分类号： C02F1/10 ,  C02F5/145 ,  C23F11/08

摘要： The waters used for cooling generally contain hard ions of the group consisting of calcium and magnesium ions concentration of from about 10 to 600 parts per million. Such waters also contain bicarbonate ions. When cooling waters are recirculated through a cooling tower, they are saturated with oxygen and tend to be corrosive and tend to promote formation of calciferous scale. Such propensities are inhibited by the injection of appropriate chemicals so that the inhibited water contains dispersants effective in dispersing incipient calcium compounds and inhibiting calciferous scale, so that the inhibited water contains a plurality of components forming a dynamic layer on metal surfaces protecting such metal from oxidation. The inhibited water contains about 1 part per million of polyacrylic acid having a molecular weight of about 1,000 and terminated by thioglycolic acid, plus about 2 parts per million of dispersants comprising both sodium sulfonate dispersants and phosphate ester salt types of dispersants plus about 300 parts per billion of a mixture of organic phosphonates selected from the group consisting of diphosphonates, triphosphonates, tetraphosphonates and polyphosphonates, plus about 400 parts per billion of an aromatic trizaole, plus about 6 parts of added phosphate. The effluent from such cooling water has a sufficiently low concentration of toxic components to be suitable for discharge into some natural streams.

摘要翻译： 用于冷却的水通常含有由钙和镁离子浓度为约10至600ppm的硬离子。 这样的水还含有碳酸氢根离子。 当冷却水通过冷却塔再循环时，它们被氧饱和，并且倾向于具有腐蚀性，并且倾向于促进钙质垢的形成。 通过注入合适的化学物质来抑制这种倾向，使得被抑制的水含有有效分散初始钙化合物并抑制钙质垢的分散剂，使得被抑制的水含有在金属表面上形成动态层的多种成分，保护这些金属不被氧化 。 受抑制的水含有约1百万分之一百万分子量为约1,000的聚丙烯酸，并由巯基乙酸封端，加上约2百万分之一分散剂，包括磺酸钠分散剂和磷酸酯盐型分散剂，加上约300份 选自二膦酸盐，三膦酸盐，四磷酸盐和多磷酸盐的有机膦酸盐的混合物，加上约四十分之十十亿的芳族三唑，加上约六份加入的磷酸盐。 来自这种冷却水的流出物具有足够低的有毒成分浓度以适于排放到一些天然气流中。