公开(公告)号：US5786402A

公开(公告)日：1998-07-28

申请号：US415290

申请日：1995-04-03

申请人： Bernd Bruchmann ,  Ruth Zschiesche ,  Heinz-Dieter Lutter ,  Claudia Spang ,  Werner Hinz

发明人： Bernd Bruchmann ,  Ruth Zschiesche ,  Heinz-Dieter Lutter ,  Claudia Spang ,  Werner Hinz

IPC分类号： C08J9/02 ,  C08G18/18 ,  C08G18/20 ,  C08J9/12

CPC分类号： C08G18/2027 ,  C08G18/1825 ,  C08G2101/00 ,  C08G2290/00

摘要： The invention relates to a process for the production of (flexible) polyurethane foams having reduced odor and reduced fogging values by reacting a) modified or unmodified organic polyisocyanates with b) relatively high-molecular-weight polyhydroxyl compounds and, if desired,c) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of d) blowing agents, e) catalysts from the group consisting of aminoalkyl- and aminophenylimidazoles of the formula ##STR1## and, if desired, f) additives, and to the use of the aminoalkyl- and aminophenylimidazoles of the formula (I) and/or (II) as catalysts for the preparation of polyisocyanate polyaddition products.

摘要翻译： 本发明涉及通过使a）改性或未改性的有机多异氰酸酯与b）相对高分子量的多羟基化合物和如果需要的话c）低的，生产具有降低的气味和降低雾化值的（柔性）聚氨酯泡沫的方法 - 分子量增链剂和/或交联剂，在d）发泡剂的存在下，e）由下式的氨基烷基 - 和氨基苯基咪唑组成的组中的催化剂：（I）＆lt; IMAGE＆gt;（II） 如果需要，f）添加剂，以及使用式（I）和/或（II）的氨基烷基 - 和氨基苯基咪唑作为制备多异氰酸酯加聚产物的催化剂。

公开(公告)号：US5059632A

公开(公告)日：1991-10-22

申请号：US430607

申请日：1989-11-01

申请人： Peter Horn ,  Gerd Rehmer ,  Heinz-Dieter Lutter ,  Gerhard Ramlow ,  Werner Hinz ,  Hans U. Schmidt

发明人： Peter Horn ,  Gerd Rehmer ,  Heinz-Dieter Lutter ,  Gerhard Ramlow ,  Werner Hinz ,  Hans U. Schmidt

IPC分类号： B01F17/52 ,  C08F216/14 ,  C08F220/28 ,  C08F220/58 ,  C08F226/00 ,  C08F226/06 ,  C08F290/06 ,  C08L75/04

CPC分类号： C08F290/062 ,  C08F216/1416 ,  C08F220/28 ,  C08F220/58 ,  C08F226/00 ,  C08F226/06 ,  C08L75/04 ,  Y10S507/936

摘要： This invention deals with novel copolymers having K values of from 5 to 80 prepared by the radical polymerization of:(A) 20 to 80 weight percent, based on the total weight of (A) and (B), of at least one olefinic unsaturated polyoxyalkylene alcohol adduct or a polyester alcohol adduct;(B) 80 to 20 weight percent, based on the total weight of (A) and (B), of at least one vinyl monomer selected from the group consisting of N-vinylformamide, N-vinyl-2-pyrrolidone, N-vinyl-piperidone, N-vinyl-2-caprolactam, N-vinylimidazole, N-vinyl-2-ethylene-urea and N-vinyl-2-propylene-urea;(C) 0.05 to 40 parts by weight of glycidyl acrylate and/or glycidyl methacrylate;(D) 0 to 10 parts by weight of at least one .alpha.,.beta.-monoolefinic unsaturated acid; and(E) 0 to 30 parts by weight of at least one olefinic unsaturated carboxylic acid amide and or carboxylic acid ester and/or styrene;whereby the parts by weight of (C), (D) and (E) are each based on 100 parts by weight of monomers (A) and (B).The copolymers are used as auxiliaries and/or additives, for example, as dispersing agents and/or emulsification agents or as additives for improving the mechanical properties in formulations for the preparation of polyisocyanate addition polymerization products.

摘要翻译： 本发明涉及通过以下自由基聚合制备的K值为5至80的新型共聚物：（A）基于（A）和（B）的总重量为20至80重量％的至少一种烯属不饱和 聚氧化烯醇加合物或聚酯醇加合物; （B）基于（A）和（B）的总重量的80至20重量％的至少一种乙烯基单体，其选自N-乙烯基甲酰胺，N-乙烯基-2-吡咯烷酮，N-乙烯基 哌啶酮，N-乙烯基-2-己内酰胺，N-乙烯基咪唑，N-乙烯基-2-亚乙基脲和N-乙烯基-2-丙烯 - 脲; （C）0.05〜40重量份丙烯酸缩水甘油酯和/或甲基丙烯酸缩水甘油酯; （D）0至10重量份的至少一种α，β-单烯烃不饱和酸; 和（E）0至30重量份的至少一种烯属不饱和羧酸酰胺和/或羧酸酯和/或苯乙烯; （C），（D）和（E）的重量份分别为100重量份的单体（A）和（B）。 共聚物用作助剂和/或添加剂，例如作为分散剂和/或乳化剂或用作改进用于制备多异氰酸酯加成聚合产物的配方中的机械性能的添加剂。