公开(公告)号：US20100168333A1

公开(公告)日：2010-07-01

申请号：US12647596

申请日：2009-12-28

Applicant: Jae Keun HONG ,  Byeong Do LEE ,  Ho Ryong SUN ,  Young Sub JIN ,  Hwan Seok PARK ,  Sung Kwan KIM ,  Sa Chun BAE

Inventor： Jae Keun HONG ,  Byeong Do LEE ,  Ho Ryong SUN ,  Young Sub JIN ,  Hwan Seok PARK ,  Sung Kwan KIM ,  Sa Chun BAE

IPC: C08L51/04 ,  C08L33/24

CPC classification number: C08L51/04 ,  C08L35/06 ,  C08L2205/02 ,  C08L2666/24 ,  C08L2666/04

Abstract: The present invention provides a thermoplastic resin composition that can have excellent heat resistance and impact strength comprising a rubber-modified styrene resin and a copolymer of N-substituted maleimide compound and aromatic vinyl compound.

Abstract translation: 本发明提供一种能够具有优异的耐热性和冲击强度的热塑性树脂组合物，其包含橡胶改性苯乙烯树脂和N-取代马来酰亚胺化合物与芳族乙烯基化合物的共聚物。

公开(公告)号：US06777483B2

公开(公告)日：2004-08-17

申请号：US10213223

申请日：2002-08-06

Applicant: Byeong-Do Lee ,  Ki-bo Chang ,  Kwang-Yeol Lim ,  Dong-Won Jun

Inventor： Byeong-Do Lee ,  Ki-bo Chang ,  Kwang-Yeol Lim ,  Dong-Won Jun

IPC: C08L2904

CPC classification number: C08J3/03

Abstract: A method of preparing a diene rubber latex having large size particles, good stability and reduced coagulum during polymerization wherein the method comprises: (a) pretreating a seed diene rubber latex with an anionic emulsifier and a non-ionic emulsifier, (b) adjusting the pH of an unsaturated carboxylic acid-containing copolymer latex to about 5 to 11 and adjusting the solids content of the copolymer latex to about 1 to 10% by weight solids content to produce an agglomerating latex solution, and (c) adding the pretreated seed diene rubber latex of step (a) to the agglomerating latex solution of step (b). Step (c) must be carried out by adding the pretreated seed diene rubber latex to the agglomerating latex. If the agglomerating latex is added to the rubber latex, an undesirable level of coagulum is produced.

Abstract translation: 一种制备具有大粒径的二烯橡胶胶乳的方法，在聚合过程中具有良好的稳定性和降低的凝结物，其中该方法包括：（a）用阴离子乳化剂和非离子乳化剂预处理种子二烯橡胶胶乳，（b） 将不饱和羧酸的共聚物胶乳的pH调节至约5至11，并将共聚物胶乳的固体含量调节至约1至10重量％的固体含量以产生凝聚胶乳溶液，和（c）将预处理的种子二烯 步骤（a）的橡胶胶乳到步骤（b）的凝聚胶乳溶液。步骤（c）必须通过将预处理的种子二烯橡胶胶乳添加到附聚胶乳中来进行。 如果将聚结胶乳加入到橡胶胶乳中，则产生不期望的水平的凝结物。

公开(公告)号：US06365669B1

公开(公告)日：2002-04-02

申请号：US09177840

申请日：1998-10-22

Applicant: Byeong-do Lee ,  Dong-un Jin

Inventor： Byeong-do Lee ,  Dong-un Jin

IPC: C08K541

CPC classification number: C08F265/04 ,  C08C1/07 ,  C08F136/06 ,  C08F2/26

Abstract: A method for preparing a polybutadiene latex comprises providing an emulsion polymerization medium by reacting a mixture of water, butadiene monomers, a surfactant, a chain transfer agent, an initiator and an electrolyte, preferably at a temperature of about 60˜80° C., preferably for about 8˜16 hours, and agglomerating the resulting emulsion polymerization medium, preferably at a temperature of about 5˜20° C. higher than the polymerization temperature, preferably for about 4˜12 hours by adding a surfactant and an agglomerating agent to the emulsion polymerization medium in consecutive order. The agglomerating agent is prepared a method comprising a first step of forming agglomerating seeds by batch polymerization of an alkyl acrylate of C1˜C12, an anionic surfactant and an anionic initiator, a second step of growing the agglomerating agent in semi-batch polymerization by adding an alkyl acrylate of C1˜C12 and anionic comonomer to the resulting polymer of the first step, and a third step of copolymerizing the ionic comonomer at the surface of the agglomerating agent to be prepared in a sufficient amount, by adding an alkyl acrylate of C1˜C12, an ionic comonomer and an anionic initiator to the resulting polymer of the second step.

Abstract translation: 制备聚丁二烯胶乳的方法包括通过使水，丁二烯单体，表面活性剂，链转移剂，引发剂和电解质的混合物，优选在约60〜80℃的温度下反应来提供乳液聚合介质， 优选约8〜16小时，并将所得乳液聚合介质，优选在比聚合温度高约5〜20℃的温度下聚集，优选加入表面活性剂和附聚剂至约4〜12小时 乳液聚合介质连续顺序。 附聚剂的制备方法包括：通过间歇聚合C1〜C12烷基酯，阴离子表面活性剂和阴离子引发剂来形成团聚种子的第一步骤，第二步，通过加入在半间歇式聚合中生长附聚物 将C1〜C12的丙烯酸烷基酯和阴离子共聚单体与第一步所得的聚合物进行反应，第三步是通过加入C1的丙烯酸烷基酯共聚作用于附聚物表面的离子性共聚单体， 〜C12，离子共聚单体和阴离子引发剂，得到第二步的聚合物。