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    Process for the catalytic reforming of a charge passing through at least two catalyst beds
    22.
    发明授权
    Process for the catalytic reforming of a charge passing through at least two catalyst beds 失效
    用于催化重整通过至少两个催化剂床的电荷的方法

    公开(公告)号：US4737262A

    公开(公告)日：1988-04-12

    申请号：US10596

    申请日：1987-02-03

    申请人： Jean-Pierre Franck ,  Jean-Paul Bournonville

    发明人： Jean-Pierre Franck ,  Jean-Paul Bournonville

    IPC分类号： B01J27/00 ,  B01J27/13 ,  B01J31/00 ,  B01J31/12 ,  B01J31/22 ,  C10G35/04 ,  C10G35/085 ,  C10G35/09 ,  C10G50/00 ,  C10G59/02

    CPC分类号： C10G35/09 ,  C10G59/02

    摘要： A process for the catalytic reforming of a hydrocarbon charge wherein the charge passes successively through at least two catalyst beds, the first one being a bed of a first catalyst whose carrier contains platinum, rhenium and at least one halogen, at least the last bed being a moving bed of a second catalyst whose carrier contains platinum, at least one additional metal M selected from the group consisting of tin, gallium, germanium, indium, lead and thallium and at least one halogen, said metal M being introduced onto this carrier by means of an organometallic compound and the proportion by weight of said second catalyst being from 25 to 55% of the total catalyst mass used in all the catalyst beds. The charge preferably passes through at least two fixed beds of the first catalyst and at least one moving bed of the second catalyst, the carrier of the two catalysts being preferably alumina.By this process high grade gasolines (of Research Octane Number higher than 95) are produced over long periods.

    摘要翻译： 一种用于烃电荷的催化重整的方法，其中电荷依次通过至少两个催化剂床，第一个是载体包含铂，铼和至少一个卤素的第一催化剂的床，至少最后一个床是 载体包含铂的第二催化剂的移动床，选自锡，镓，锗，铟，铅和铊的至少一种另外的金属M和至少一种卤素，所述金属M通过 有机金属化合物的手段和所述第二催化剂的重量比例在所有催化剂床中使用的总催化剂质量的25-55％。 电荷优选通过第一催化剂的至少两个固定床和第二催化剂的至少一个移动床，两种催化剂的载体优选为氧化铝。 通过这种方法，高品质汽油（研究辛烷值高于95）长期生产。

    Catalytic reforming process
    23.
    发明授权
    Catalytic reforming process 失效
    催化重整过程

    公开(公告)号：US4588495A

    公开(公告)日：1986-05-13

    申请号：US704456

    申请日：1985-02-22

    申请人： Jean-Pierre Franck ,  Jean-Paul Bournonville

    发明人： Jean-Pierre Franck ,  Jean-Paul Bournonville

    IPC分类号： C10G35/09 ,  B01J21/04 ,  B01J27/00 ,  B01J27/13 ,  B01J27/135 ,  C10G59/02 ,  C10G35/06

    CPC分类号： C10G59/02

    摘要： In a catalytic reforming process wherein a charge is circulated successively through a first catalyst bed and then at least one further catalyst bed, the improvement wherein the catalyst of the first bed comprises a carrier of alumina base and, by weight in proportion to the carrier, 0.05-0.6% of platinum, 0.005-3% of rhenium and 0.1-15% of at least one halogen and wherein each catalyst of the other beds contains a carrier of alumina base and, by weight with respect to the carrier, 0.05-0.6% of platinum, 0.05-3% of at least one metal promoter selected from the group consisting of tin, thallium and indium and 0.1-15% of at least one halogen, the proportion by weight of the catalyst containing platinum and rhenium ranging from 8 to 40% with respect to the total catalyst mass used in all the catalyst beds.

    摘要翻译： 在催化重整过程中，其中电荷依次通过第一催化剂床和至少一个另外的催化剂床循环，其中第一床的催化剂包含氧化铝碱的载体，并且按载体的重量比例， 0.05-0.6％的铂，0.005-3％的铼和0.1-15％的至少一种卤素，其中每个催化剂的其它床层含有氧化铝基质的载体，相对于载体的重量比为0.05-0.6 铂的含量为0.05-3％，选自锡，铊和铟的至少一种金属促进剂和0.1-15％的至少一种卤素，含有铂和铼的催化剂的重量比为8 相对于在所有催化剂床中使用的总催化剂质量至40％。

    Process for manufacturing a hydrocarbon conversion catalyst and catalyst prepared by said process
    24.
    发明授权
    Process for manufacturing a hydrocarbon conversion catalyst and catalyst prepared by said process 失效
    用于制造烃转化催化剂的方法和通过所述方法制备的催化剂

    公开(公告)号：US4548918A

    公开(公告)日：1985-10-22

    申请号：US607110

    申请日：1984-05-04

    申请人： Jean-Paul Bournonville ,  Chan T. Dinh

    发明人： Jean-Paul Bournonville ,  Chan T. Dinh

    IPC分类号： B01J23/62 ,  C10G35/09 ,  B01J31/28

    CPC分类号： B01J23/622 ,  C10G35/09

    摘要： The invention concerns the manufacture of a solid acid catalyst comprising: (a) a carrier, (b) a metal of the platinum family and (c) an additional metal selected from tin, germanium and lead. Halogen may be present.The additional metal is added to the catalytic mass dissolved in a hydrocarbon solvent, in the form of an organometallic compound, for example tetrabutyl tin.The invention is particularly applicable to the manufacture of catalysts for hydrocarbon reforming or aromatic hydrocarbons production.

    摘要翻译： 本发明涉及固体酸催化剂的制造，其包括：（a）载体，（b）铂族金属和（c）选自锡，锗和铅的另外的金属。 卤素可能存在。 将另外的金属加入到溶解在烃溶剂中的催化物质中，以有机金属化合物，例如四丁基锡的形式。 本发明特别适用于制备用于烃重整或芳族烃生产的催化剂。