公开(公告)号：US4320070A

公开(公告)日：1982-03-16

申请号：US213511

申请日：1980-12-08

申请人： James A. Cook, Jr. ,  William A. Keim

发明人： James A. Cook, Jr. ,  William A. Keim

IPC分类号： C07C329/00 ,  C07C155/02 ,  C07C154/00

CPC分类号： C07C329/00

摘要： Chlorothiolformates are prepared by reacting a mercaptan with phosgene in the presence of a catalytic amount of anion exchange resin in the neutral salt form. Preferably the resin has quaternary ammonium functionality.

摘要翻译： 氯代硫代甲酸酯通过在催化量的中性盐形式的阴离子交换树脂的存在下使硫醇与光气反应来制备。 优选地，树脂具有季铵官能团。

公开(公告)号：US3971649A

公开(公告)日：1976-07-27

申请号：US598485

申请日：1975-07-23

申请人： Don R. Baker

发明人： Don R. Baker

IPC分类号： C07C333/02 ,  C07C155/02 ,  A01N9/12

CPC分类号： C07C333/02

摘要： The novel compound S-methyl-N-[4-(4'-chlorophenoxy)phenyl]thiolcarbamate, ##SPC1##Is useful as a post-emergence herbicide, particularly as a post-emergence, post-flooding herbicide for use in connection with rice cultivation.

摘要翻译： 新型化合物S-甲基-N- [4-（4'-氯苯氧基）苯基]硫代氨基甲酸酯，有用作为除草剂后处理剂，特别是作为后期后处理，后处理除草剂，用于与米糠生产有关。

公开(公告)号：US3954729A

公开(公告)日：1976-05-04

申请号：US454619

申请日：1974-03-25

申请人： Zenichi Sato ,  Keiichiro Takagi ,  Masamichi Shimizu

发明人： Zenichi Sato ,  Keiichiro Takagi ,  Masamichi Shimizu

IPC分类号： C07C333/02 ,  C07C67/00 ,  C07C325/00 ,  C07C333/04 ,  C07D295/21 ,  C07C155/02

CPC分类号： C07D295/21

摘要： Thiolcarbamates are prepared by reacting a secondary amine having the formula ##EQU1## wherein R.sub.1 and R.sub.2 are the same or different and each represent hydrogen, lower alkyl, alkoxy, alkenyl, alkoxyalkyl, cycloalkyl, hydroxyalkyl, benzyl or phenyl or R.sub.1 and R.sub.2 combined is a nitrogen containing heterocyclic ring with carbonylsulfide to form an intermediate of an amine salt of a thiolcarbamic acid having the formula ##EQU2## wherein R.sub.1 and R.sub.2 are defined as above, in an organic solvent having the formula ##SPC1##Wherein n is 0, 1 or 2 and R' is hydrogen, halogen or a lower alkyl group which solvent is sparingly soluble or insoluble in water and which dissolves the amine salt of the thiolcarbonic acid, and then reacting the intermediate with an alkyl halide having the formulaX -- CH.sub.2 -- R.sub.3wherein X represents halogen, and R.sub.3 represents hydrogen, lower alkyl or naphthyl or phenyl which can be substituted with halogen, alkyl, alkoxy, alkylthio, cyano or nitro, to yield a thiolcarbamate having the formula ##EQU3##

摘要翻译： 硫代氨基甲酸盐通过使具有式R 1 ANGLE NH R 2的仲胺反应制备，其中R 1和R 2相同或不同，各自代表氢，低级烷基，烷氧基，烯基，烷氧基烷基，环烷基，羟基烷基，苄基或苯基或R 1和R 2组合 是具有羰硫基的含氮杂环，以形成具有式R 1，R 2，R 2，R 2，R 2，R 2和R 2如上定义的硫代氨基甲酸的胺盐的中间体，其中R 1和R 2如上定义， 具有式WHEREIN N IS 0,1或2的有机溶剂，R'是氢，卤素或低级烷基，其溶剂微溶或不溶于水，并溶解硫醇碳酸的胺盐，然后使中间体 与具有式X-CH 2 -R 3的烷基卤化物，其中X表示卤素，R 3表示氢，可被卤素，烷基，烷氧基，烷硫基，氰基o取代的低级烷基或萘基或苯基 r硝基，得到具有式R1O平行角N-C-S-CH2-R3的硫代氨基甲酸酯。 R2

公开(公告)号：US3914270A

公开(公告)日：1975-10-21

申请号：US41289873

申请日：1973-11-05

申请人： KUMIAI CHEMICAL INDUSTRY CO

发明人： KONNAI MAKOTO ,  KAMATA HIROSHI ,  KADO MASARU

IPC分类号： A23K1/16 ,  C07C333/02 ,  C07D295/14 ,  C07C155/02

CPC分类号： C07D295/14 ,  A23K20/111 ,  C07C333/02

摘要： This invention relates to a novel compound of S-(4chlorobenzyl)-N,N-diethylthiocarbamate, which is useful as an active ingredient of herbicidal composition, a feed additive for growing chicken and a fungicide for sclerotium of Pellicularia Oryzae.

摘要翻译： 本发明涉及可用作除草组合物的活性成分的S-（4-氯苄基）-N，N-二乙基硫代氨基甲酸酯的新型化合物，用于生长鸡的饲料添加剂和Pellicularia Oryzae的菌核的杀真菌剂。

公开(公告)号：US3853966A

公开(公告)日：1974-12-10

申请号：US25090772

申请日：1972-05-08

申请人： KOHN G ,  BROWN M

发明人： BROWN M ,  KOHN G

IPC分类号： C07C381/08 ,  C07C155/02

CPC分类号： C07C381/08

摘要： N-chlorothio ureas are produced by the reaction of sulfur dichloride and an urea having at least one hydrogen substituted on an urea nitrogen atom in the presence of an acid acceptor. The N-chlorothio ureas are useful intermediates in the preparation of pesticides.

摘要翻译： 在硫酸存在下，通过硫二氯化物与具有至少一个在脲氮原子上取代的氢原子的脲的反应产生N-氯硫脲。 N-氯硫脲是制备农药的有用中间体。

公开(公告)号：US3852319A

公开(公告)日：1974-12-03

申请号：US40047473

申请日：1973-09-24

申请人： DOW CHEMICAL CO

发明人： EDAMURA F ,  GIACOBBE T

IPC分类号： C07C333/00 ,  C07C333/02 ,  C07C155/02 ,  C07C155/08

CPC分类号： C07C333/00 ,  C07C333/02

摘要： Compounds useful as herbicides and fungicides defined as substituted (thio- and dithio-)carbanilate compounds and derivatives thereof.

摘要翻译： 用作除草剂和杀真菌剂的化合物，其定义为取代（硫代和二硫代）氨基甲酸酯化合物及其衍生物。

公开(公告)号：US3849464A

公开(公告)日：1974-11-19

申请号：US39436873

申请日：1973-09-04

申请人： STAUFFER CHEMICAL CO

发明人： TEACH E

IPC分类号： C07C333/02 ,  C07C155/02

CPC分类号： C07C333/02

摘要： 1. A COMPOUND HAVING THE FORMULA

1-(R-X-),3-(R1-Y-CO-NH-)-BENZENE

IN WHICH X IS OXYGEN OR SULFUR; Y IS SULFUR; R IS ALKYL OF FROM 1 TO 10 CARBON ATOMS, INCLUSIVE, LOWER ALKENYL, VINYLOXYALKYL IN WHICH THE TOTAL CARBON CONTENT IS FROM 3 TO 7 CARBON ATOMS, INSLUSIVE, KETOALKYL HAVING FROM 2 TO 6 CARBON ATOMS, INCLUSIVE, OR ALKYLTHIOALKYL IN WHICH THE TOTAL CARBON CONTENT ID FROM 2 TO 7 CARBON ATOMS, INCLUSIVE; R1 IS LOWER ALKYL OR LOWER ALKENYL.

公开(公告)号：US3621048A

公开(公告)日：1971-11-16

申请号：US3621048D

申请日：1968-03-14

申请人： COLGATE PALMOLIVE CO

发明人： BAUMAN ROBERT ANDREW

IPC分类号： C07C275/14 ,  C07C155/02 ,  C07C155/08

CPC分类号： C07C275/14

摘要： Quaternary ammonium carbamate, thiocarbamate, dithiocarbamate and carbamide compounds. Typical examples are (C4H9NHCOO(CH2)2N (CH3)2C12H25)Br (C4H9NHCSO(CH2)2N (CH3)2C12H25)Br (CH3NHCSS(CH2)2N (CH3)2C12H25)Br (C2H5NHCONH(CH2)2N (CH3)2C12H25)Br These compounds are effective against gram positive bacteria and fungi and reduce caries and inhibit formation of oral calculus. The thiocarbamates can be prepared by converting amino alcohols to sodium salts thereof with metallic sodium and reacting isothiocyanates with the sodium salts followed by quaternization. The carbamates can be prepared by reacting isocyanates with amino alcohols followed by quaternization. The dithiocarbamates can be prepared by reacting isothiocyanates with sodium salts of aminoalkanethiols followed by quaternization. The carbimides can be prepared by reacting isocyanates with alkanediamines followed by quaternization.

公开(公告)号：US3597467A

公开(公告)日：1971-08-03

申请号：US3597467D

申请日：1968-11-26

申请人： VELSICOL CHEMICAL CORP

发明人： RICHTER SIDNEY B ,  BARNAS EUGENE F

IPC分类号： A01N47/06 ,  C07C233/12 ,  C07C101/66 ,  C07C154/00 ,  C07C155/02

CPC分类号： A01N47/06 ,  C07C233/12

摘要： THIS INVENTION DISCLOSES NEW CHEMICAL COMPOSITIONS OF MATTER AND MORE PARTICULARLY NEW COMPOUNDS SELECTED FROM THE GROUP CONSISTING OF

1-X1,2-R1-O-,3-R2-O-N(-CO-R3)-CO-,4-X2-BENZENE

AND THEIR ISOMERIC FORM

1-X1,2-R1-O-,3-R2-O-N=C(-OOC-R3)-,4-X2-BENZENE

WHEREIN X1 AND X2 ARE HALOGEN; R1 AND R2 ARE ALKYL, AND R3 IS SELECTED FROM THE GROUP CONSISTING OF ALKYL, ALKENYL, ALKOXY AND ALKYTHIO. THE COMPOUNDS OF THE ABOVE DESCRIPTION ARE USEFUL AS ACARICIDES.

公开(公告)号：US4714772A

公开(公告)日：1987-12-22

申请号：US809688

申请日：1985-12-16

申请人： Howard A. Colvin ,  Kirkwood S. Cottman ,  Dane K. Parker

发明人： Howard A. Colvin ,  Kirkwood S. Cottman ,  Dane K. Parker

IPC分类号： C07C273/18 ,  C07C275/24 ,  C07C275/40 ,  C07D211/46 ,  C08F12/26 ,  C08G18/72 ,  C07C155/02

CPC分类号： C07C273/1827 ,  C07D211/46 ,  C08F12/26 ,  C08G18/728

摘要： This invention is directed to the preparation of polymerizable monomers that are prepared from 1-(1-isocyanato-1-methylethyl)-3-(1-methylethenyl) benzene (m-TMI) and 1-(1-isocyanato-1-methylethyl)-4-(1-methylethenyl) benzene (p-TMI). The monomers prepared from m- and p-TMI can contain numerous chemical moieties, and when polymerized, produce polymers that have chemically bonded to the polymeric backbone the functional moiety. More specifically, these TMI derived monomers may contain chain breaking antioxidant moieties, peroxide decomposing antioxidant moieties, ultraviolet stabilizing moieties, triplet quenching moieties, and other chemical moieties that are useful in polymers.

摘要翻译： 本发明涉及由1-（1-异氰酸基-1-甲基乙基）-3-（1-甲基乙烯基）苯（m-TMI）和1-（1-异氰酸基-1-甲基乙基酯）制备的可聚合单体的制备 ）-4-（1-甲基乙烯基）苯（p-TMI）。 由m-和p-TMI制备的单体可以含有许多化学部分，当聚合时，产生化学键合到聚合物主链功能部分的聚合物。 更具体地，这些TMI衍生的单体可以含有断链抗氧化剂部分，过氧化物分解抗氧化剂部分，紫外线稳定部分，三重峰淬灭部分和可用于聚合物的其它化学部分。