公开(公告)号：US4273684A

公开(公告)日：1981-06-16

申请号：US152176

申请日：1980-05-22

申请人： Tetsuya Nagashima ,  Yasunori Usuba ,  Takahisa Ogawa ,  Masahiro Takehara

发明人： Tetsuya Nagashima ,  Yasunori Usuba ,  Takahisa Ogawa ,  Masahiro Takehara

IPC分类号： C11D1/10 ,  C11D3/32 ,  C11D17/00 ,  C11D3/43 ,  C11D11/00

CPC分类号： C11D3/0094 ,  C11D1/10 ,  C11D17/0095 ,  C11D3/32

摘要： A transparent detergent bar possessing good foaming power and detergency in hard water is formulated consisting essentially of at least one salt of a N-long chain acyl-optically active acidic amino acid neutralized with a basic amino acid in the ratio of 1 mol of the former to 1 to 2 mols of the latter and water in the range of 5 to 35% based on the weight of the bar apart from water. Other adjuvents may be present.

摘要翻译： 在硬水中具有良好发泡力和去污力的透明洗涤剂条配制成基本上由至少一种以碱性氨基酸中和的N-长链酰基 - 光学活性酸性氨基酸的盐与前者1摩尔 至1至2摩尔的后者，水的范围为5至35％，基于除了水的重量。 可能存在其它佐剂。

公开(公告)号：US4108891A

公开(公告)日：1978-08-22

申请号：US765203

申请日：1977-02-03

申请人： Kenichi Hattori ,  Bunji Miya ,  Morio Matsuda ,  Mutsuo Ishii ,  Hisashi Saito ,  Hiroshi Watanabe ,  Hidemitu Takizawa

发明人： Kenichi Hattori ,  Bunji Miya ,  Morio Matsuda ,  Mutsuo Ishii ,  Hisashi Saito ,  Hiroshi Watanabe ,  Hidemitu Takizawa

IPC分类号： C07C59/105 ,  B01J23/00 ,  B01J23/44 ,  C07B61/00 ,  C07C51/00 ,  C07C51/31 ,  C07C67/00 ,  C07C51/26 ,  C07C59/17

CPC分类号： B01J23/44 ,  C07C51/313

摘要： Monosaccharides are oxidized by an oxygen-containing gas in the presence of a special palladium-carbon catalyst which is prepared by adsorbing palladium on active carbon at a temperature lower than 60.degree. C while the active carbon is suspended in an aqueous solution of an alkali metal hydroxide or carbonate and then reducing the palladium with formaldehyde.

摘要翻译： 在特殊的钯 - 碳催化剂的存在下，单糖被氧化，该催化剂是通过在低于60℃的温度下将钯吸附在活性炭上而将活性炭悬浮在碱金属的水溶液中 氢氧化物或碳酸盐，然后用甲醛还原钯。

公开(公告)号：US20130338055A1

公开(公告)日：2013-12-19

申请号：US13684853

申请日：2012-11-26

申请人： KAWAKEN FINE CHEMICALS CO., LTD.

发明人： Shou OOSHIDA ,  Hiroki SUDA

IPC分类号： C11D3/00 ,  C11D3/30

CPC分类号： C11D3/0094 ,  A61K8/45 ,  A61Q5/02 ,  A61Q19/10 ,  C11D1/44 ,  C11D3/30

摘要： The object of the present invention is to provide foam booster which the speed of lathering is excellent by using together with foaming surfactant such as anionic surfactants, nonionic surfactants, amphoteric surfactants, dipolar-ionic surfactants, semipolar surfactants and cationic surfactants, a detergent composition containing the same.The present invention is a foam booster comprises aliphatic amine alkylene oxide adduct represented by the general formula (1): [wherein R1 is an alkyl group having 6 to 10 carbon atoms, A1O and A2O represent an oxyethylene group and/or an oxypropylene group and independently from each other, m and n are each independently a whole number more than 0, with 1≦m+n≦2.]

摘要翻译： 本发明的目的是提供通过与阴离子表面活性剂，非离子表面活性剂，两性表面活性剂，偶极离子表面活性剂，半极性表面活性剂和阳离子表面活性剂等发泡表面活性剂一起使用，起泡速度优异的泡沫助剂，含有 一样。 本发明是一种泡沫增效剂，其包含由通式（1）表示的脂肪族胺氧化烯加成物：[其中R1是碳原子数6〜10的烷基，AlO和A2O表示氧化乙烯基和/或氧化亚丙基， 独立地，m和n各自独立地为大于0的整数，其中1≤m+ n2。]

公开(公告)号：US07067471B2

公开(公告)日：2006-06-27

申请号：US11098370

申请日：2005-04-05

申请人： Toyofumi Ito ,  Hiroshi Higuchi

发明人： Toyofumi Ito ,  Hiroshi Higuchi

IPC分类号： C11D3/20 ,  C11D3/32

CPC分类号： C11D3/0026 ,  A61K8/42 ,  A61K8/49 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/10 ,  C07C231/12 ,  C07C231/24 ,  C07C233/18 ,  C07C233/20 ,  C11D1/526

摘要： A refined product of a polyoxypropylene fatty acid isopropanolamide surfactant, having a high stability in storage and a very small change in smell thereof, is obtained by heat-treating an addition-reaction mixture prepared from a compound of the formula (III) and propylene oxide in a molar amount of 0.5 to 10 times that of the compound of the formula (III), and containing the target compound of the formula (I) and an oxazoline compound of the formula (II) produced as a by-product with water or an alkaline aqueous solution at 50 to 100° C., to hydrolyze the oxyazoline compound and to control the content of the oxyazoline compound to 0.1% by mass or less; and a detergent composition containing the refined product in a content of 1 to 50% by mass, exhibits enhanced thickening, foaming, emulsifying, dispersing and dissolving properties. [R1═C1–C19alkyl or alkenyl group, X=oxypropylene group, n=average number of addition-reacted X groups of 0.5 to 10]

摘要翻译： 通过对由式（III）的化合物和环氧丙烷制备的加成反应混合物进行热处理，得到具有高储存稳定性和非常小的气味变化的聚氧丙烯脂肪酸异丙醇酰胺表面活性剂的精制产物 摩尔量为式（III）化合物的0.5〜10倍，含有式（I）的目标化合物和式（II）的恶唑啉化合物作为副产物与水或 在50〜100℃的碱性水溶液中进行水解，并且使唑烷化合物的含量控制在0.1质量％以下。 含有1〜50质量％的精制物的洗涤剂组合物，具有增稠，发泡，乳化，分散，溶解等特性。 [R 1-1 -C 1 -C 19烷基或链烯基，X =氧亚丙基，n =加成反应的X基团的平均数 为0.5〜10]

公开(公告)号：US20050187135A1

公开(公告)日：2005-08-25

申请号：US11098370

申请日：2005-04-05

申请人： Toyofumi Ito ,  Hiroshi Higuchi

发明人： Toyofumi Ito ,  Hiroshi Higuchi

IPC分类号： A61K8/42 ,  A61K8/49 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/10 ,  C07C231/12 ,  C07C231/24 ,  C07C233/18 ,  C07C233/20 ,  C11D1/52 ,  C11D3/00 ,  C11D17/00

CPC分类号： C11D3/0026 ,  A61K8/42 ,  A61K8/49 ,  A61Q5/02 ,  A61Q5/12 ,  A61Q19/10 ,  C07C231/12 ,  C07C231/24 ,  C07C233/18 ,  C07C233/20 ,  C11D1/526

摘要： A refined product of a polyoxypropylene fatty acid isopropanolamide surfactant, having a high stability in storage and a very small change in smell thereof, is obtained by heat-treating an addition-reaction mixture prepared from a compound of the formula (III) and propylene oxide in a molar amount of 0.5 to 10 times that of the compound of the formula (III), and containing the target compound of the formula (I) and an oxazoline compound of the formula (II) produced as a by-product with water or an alkaline aqueous solution at 50 to 100° C., to hydrolyze the oxyazoline compound and to control the content of the oxyazoline compound to 0.1% by mass or less; and a detergent composition containing the refined product in a content of 1 to 50% by mass, exhibits enhanced thickening, foaming, emulsifying, dispersing and dissolving properties. [R1=C1-C19alkyl or alkenyl group, X=oxypropylene group, n=average number of addition-reacted X groups of 0.5 to 10]

摘要翻译： 通过对由式（III）的化合物和环氧丙烷制备的加成反应混合物进行热处理，得到具有高储存稳定性和非常小的气味变化的聚氧丙烯脂肪酸异丙醇酰胺表面活性剂的精制产物 摩尔量为式（III）化合物的0.5〜10倍，含有式（I）的目标化合物和式（II）的恶唑啉化合物作为副产物与水或 在50〜100℃的碱性水溶液中进行水解，并且使唑烷化合物的含量控制在0.1质量％以下。 含有1〜50质量％的精制物的洗涤剂组合物，具有增稠，发泡，乳化，分散，溶解等特性。 烷基或链烯基，X =氧化丙烯基，n =加成反应的X基团的平均数，R 1，R 2，R 3， 为0.5〜10]

公开(公告)号：US4894457A

公开(公告)日：1990-01-16

申请号：US135392

申请日：1987-12-21

申请人： Masaaki Kubo ,  Hiroshi Umezawa ,  Kazuhiro Okura

发明人： Masaaki Kubo ,  Hiroshi Umezawa ,  Kazuhiro Okura

IPC分类号： C07B61/00 ,  C07D471/04

CPC分类号： C07D471/04

摘要： A 7-bromo-.beta.-carboline compound of the formula (I): ##STR1## wherein R.sup.1 =H or C.sub.1 -C.sub.5 alkyl and R.sup.2 =C.sub.1 -C.sub.5 alkyl or benzyl, is produced by reacting a .beta.-carboline compound of the formula (II): ##STR2## wherein R.sup.1 and R.sup.2 are as defined above and R.sup.3 =H, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.5 alkoxy or benzyloxy, with a brominating agent in an organic solvent in the presence of an alkalic and then hydrolyzing the resultant procursory 7-bromo-.beta.-carboline compound of the formula (III): ##STR3## is a solvent in the presence of a mineral acid.

公开(公告)号：US4576647A

公开(公告)日：1986-03-18

申请号：US629709

申请日：1984-08-24

申请人： Noritaka Matsushita

发明人： Noritaka Matsushita

IPC分类号： C07C49/92 ,  C07F5/06 ,  C08K5/00 ,  C08K9/04 ,  C09C3/08 ,  C09D7/12 ,  C09D11/02 ,  C04B14/00

CPC分类号： C09D11/03 ,  C07C49/92 ,  C07F5/069 ,  C08K5/0091 ,  C08K9/04 ,  C09C3/08 ,  C09D7/12 ,  C01P2004/50 ,  C01P2006/22 ,  C01P2006/90

摘要： An oleophilic composition comprising a powdery or granular substance having a hydrophilic surface and a surface modifier comprising an aluminum chelate compound of the formula (I): ##STR1## wherein R.sup.1 is selected from hydrogen and C1-6 alkyl, R.sup.2 is selected from methyl and phenyl, R.sup.3 is selected from R.sup.4 --, R.sup.5 O-- and R.sup.6 NH--, A is selected from R.sup.7 O--, R.sup.8 COO--, R.sup.9 SO.sub.3 --, R.sup.10 OSO.sub.3 --, ##STR2## R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 are C1-22 alkyl or C3-22 alkenyl, aryl, aralkyl or alkylaryl, R.sup.3 may be the same as or different from R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13, with the proviso that at least one of R.sup.3, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12, and R.sup.13 is a substituent having at least 8 carbon atoms or a polymerizable alkenyl group, and m=0.5 to 2.7, n=0.3 to 2.5 and m+n=0.8 to 3.

摘要翻译： 一种亲油性组合物，其包含具有亲水性表面的粉末或颗粒物质和表面改性剂，其包含式（I）的铝螯合物：其中R 1选自氢和C 1-6烷基，R 2选自 R 3选自R 4，R 5，R 6和R 6，其中A选自：R 4，R 5，R 6，R 7，R 8，R 8， R8，R9，R10，R11，R12和R13是C1-22烷基或C3-22链烯基，芳基，芳烷基或烷基芳基，R3可以与R7，R8，R9，R10，R11，R12和R13相同或不同 ，条件是R 3，R 7，R 8，R 9，R 10，R 11，R 12和R 13中的至少一个是具有至少8个碳原子的取代基或可聚合链烯基，并且m = 0.5-2.7，n = 0.3 至2.5和m + n = 0.8至3。

公开(公告)号：US4529555A

公开(公告)日：1985-07-16

申请号：US424452

申请日：1982-09-27

申请人： Noritaka Matsushita

发明人： Noritaka Matsushita

IPC分类号： C07F5/06 ,  C08K5/00 ,  C08K9/04 ,  C09C3/08 ,  C09D11/02

CPC分类号： C09D11/03 ,  C07F5/069 ,  C08K5/0091 ,  C08K9/04 ,  C09C3/08 ,  C01P2004/50 ,  C01P2006/22 ,  C01P2006/90

摘要： A surface modifier for a powdery or granular substance having a hydrophilic surface is provided. The surface modifier comprises an aluminum chelate compound of the formula (I): ##STR1## wherein R.sup.1 is selected from hydrogen and C1-6 alkyl, R.sup.2 is selected from methyl and phenyl, R.sup.3 is selected from R.sup.4 --, R.sup.5 O-- and R.sup.6 NH--, A is selected from R.sup.7 O--, R.sup.8 COO--, R.sup.9 SO.sub.3 --, R.sup.10 OSO.sub.3 --, ##STR2## R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 are C1-22 alkyl or C3-22 alkenyl, aryl, aralkyl or alkylarly, R.sup.3 may be the same as or different from R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13, with the proviso that at least one of R.sup.3, R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12, and R.sup.13 is a substituent having at least 8 carbon atoms of a polymerizable alkenyl group, and m=0.5 to 2.7, n=0.3 to 2.5 and m+n=0.8 to 3.

摘要翻译： 提供了具有亲水性表面的粉状或粒状物质的表面改性剂。 表面改性剂包括式（I）的铝螯合物：其中R1选自氢和C1-6烷基，R2选自甲基和苯基，R3选自R4-，R5O- R6NH-，A选自R7O-，R8COO-，R9SO3-，R10OSO3-，R4A，R4，R5，R6，R7，R8，R9，R10，R11，R12和R13为C1-22烷基或C3- R 3可以与R 7，R 8，R 9，R 10，R 11，R 12和R 13相同或不同，条件是R 3，R 7，R 8，R 9，R 10， R11，R12和R13是具有至少8个可聚合链烯基的碳原子的取代基，m = 0.5-2.7，n = 0.3-2.5，m + n = 0.8-3。