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公开(公告)号：US06887963B2
公开(公告)日：2005-05-03
申请号：US10609080
申请日：2003-06-27
申请人： Darin L. Dotson
发明人： Darin L. Dotson
CPC分类号： C08F110/06 , C08K5/0083 , C08F2500/16
摘要： The present invention relates to methods of producing syndiotactic polypropylene articles through high performance nucleation via the presence of certain novel nucleating agents within molten syndiotactic resins, and subsequently permitting the resultant molten mixture to cool into a selected shape or configuration. Such novel nucleating agents are new classes of hyper-nucleators that promote crystallization within such target syndiotactic resins at levels well above any previously disclosed nucleators. This invention thus also encompasses the articles and compositions of such nucleated syndiotactic polypropylene as well.
摘要翻译： 本发明涉及通过在熔融间规树脂中存在某些新型成核剂，通过高性能成核制备间同立构聚丙烯制品的方法，随后允许所得熔融混合物冷却成选定的形状或构型。 这种新型成核剂是新类型的超成核剂，其在远高于任何先前公开的成核剂的水平下促进在这些目标间同立构树脂中的结晶。 因此，本发明也包括这种成核间规聚丙烯的制品和组合物。
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公开(公告)号：US6121332A
公开(公告)日：2000-09-19
申请号：US322754
申请日：1999-05-28
CPC分类号： A61K8/498 , A61K8/042 , A61K8/345 , A61Q15/00 , A61K2800/262 , Y10S514/944
摘要： This invention relates to gelled compositions formed through the introduction of specific solvents to compositions comprising 2,4-O-(3,4-dimethylbenzylidene)-D-sorbitol. Such compositions provide excellent gelling for any number of potential applications, particularly where translucent gels are desired. In general, these compositions are formed by introducing heated solvents to the specific monobenzylidene sorbitol present in its solid form. The monobenzylidene sorbitol is preferably added in very low amounts to the target solvents in order to generate the desired gelling effect. A method of producing such gelled compositions is also provided.
摘要翻译： 本发明涉及通过将特定溶剂引入到包含2,4-O-（3,4-二甲基亚苄基）-D-山梨糖醇的组合物中而形成的凝胶组合物。 这样的组合物为任何数量的潜在应用提供优异的胶凝，特别是在需要半透明凝胶的情况下。 通常，这些组合物通过将加热的溶剂引入其固体形式存在的特定单亚苄基山梨糖醇中而形成。 优选将单亚苄基山梨糖醇以非常低的量加入到目标溶剂中以产生所需的胶凝效果。 还提供了生产这种凝胶组合物的方法。
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公开(公告)号：US20120043692A1
公开(公告)日：2012-02-23
申请号：US13266331
申请日：2010-02-25
IPC分类号： B29C47/78 , B29C45/72 , C08K5/5317
CPC分类号： C08K5/0083 , B29C47/0014 , B29C47/786 , B29C47/8805 , B29C47/90 , B29C47/904 , C08K5/5317 , C08L23/02
摘要： A composition comprises a thermoplastic and a nucleating agent. The thermoplastic can be a polyolefin selected from the group consisting of polypropylene homopolymers, polypropylene copolymers, polyethylene, polyethylene copolymers, polybutylene, poly(4 methyl 1 pentene) and mixtures thereof. The nucleating agent can comprise a metal salt of a phenylphosphonic acid. The nucleating agent can comprise primary particles having a mean aspect ratio of about two or more. The composition can also comprise an acid scavenger, such as one or more metal salts of stearic acid. The composition can be used to produce thermoplastic articles using, for example, injection molding and thermoforming techniques.
摘要翻译： 组合物包含热塑性和成核剂。 热塑性塑料可以是选自聚丙烯均聚物，聚丙烯共聚物，聚乙烯，聚乙烯共聚物，聚丁烯，聚（4-甲基戊烯）及其混合物的聚烯烃。 成核剂可以包含苯基膦酸的金属盐。 成核剂可以包含具有约两个或更多个平均纵横比的一次粒子。 组合物还可以包含酸清除剂，例如一种或多种硬脂酸金属盐。 组合物可以用于使用例如注射成型和热成型技术来生产热塑性制品。
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公开(公告)号：US20110105664A1
公开(公告)日：2011-05-05
申请号：US12903686
申请日：2010-10-13
IPC分类号： C08K5/098
CPC分类号： C08K5/098 , C07C53/134 , C08K5/0083 , C08K5/0091 , C08L23/02 , Y10S521/908
摘要： A thermoplastic polymer composition comprises a thermoplastic polymer and a nucleating agent. The nucleating agent comprises a compound conforming to the structure of Formula (I) or Formula (II)
摘要翻译： 热塑性聚合物组合物包含热塑性聚合物和成核剂。 成核剂包括符合式（I）或式（II）的结构的化合物，
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15.发明授权公开(公告)号：US06844382B2
公开(公告)日：2005-01-18
申请号：US10286220
申请日：2002-11-01
IPC分类号： A61K8/49 , A61Q15/00 , C07D493/04 , C08G18/18 , C08J9/00 , C08L23/10 , C08K5/15 , C07D323/04
CPC分类号： A61K8/042 , A61K8/498 , A61Q15/00 , C07D493/04 , C08G18/1825 , C08J9/0023 , C08J2375/04 , C08L23/10
摘要： Certain multi-substituted dibenzylidene sorbitol acetals having electron withdrawing groups as constituents and electron donating groups on the other such that the compounds are asymmetric in structure and are dipolar in nature are provided. Polymer compositions comprising such compounds, are also contemplated which may be utilized within, as merely examples, food or cosmetic containers and packaging. These inventive asymmetric dipolar dibenzylidene sorbitol acetals are also useful as gelling agents for water and organic solvents, particularly those used in the preparation of antiperspirant gel sticks.
摘要翻译： 提供了一些具有吸电子基团作为组分和给电子基团的多取代二亚苄基山梨糖醇缩醛，使得化合物在结构上是不对称的并且在本质上是偶极性的。 包含这些化合物的聚合物组合物也被设想为仅作为例子使用的食品或化妆品容器和包装。 这些本发明的不对称偶极二亚苄基山梨糖醇缩醛也可用作水和有机溶剂的胶凝剂，特别是用于制备止汗凝胶棒的那些。
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公开(公告)号：US06642290B1
公开(公告)日：2003-11-04
申请号：US10121400
申请日：2002-04-12
申请人： Darin L. Dotson
发明人： Darin L. Dotson
IPC分类号： C08K509
CPC分类号： C08K5/098 , C08K5/0083 , C08K5/0091 , C08L23/12
摘要： The present invention relates to methods of producing syndiotactic polypropylene articles through high performance nucleation via the presence of certain novel nucleating agents within molten syndiotactic resins, and subsequently permitting the resultant molten mixture to cool into a selected shape or configuration. Such novel nucleating agents are new classes of hyper-nucleators that promote crystallization within such target syndiotactic resins at levels well above any previously disclosed nucleators. This invention thus also encompasses the articles and compositions of such nucleated syndiotactic polypropylene as well.
摘要翻译： 本发明涉及通过在熔融间规树脂中存在某些新型成核剂，通过高性能成核制备间同立构聚丙烯制品的方法，随后允许所得熔融混合物冷却成选定的形状或构型。 这种新型成核剂是新类型的超成核剂，其在远高于任何先前公开的成核剂的水平下促进在这些目标间同立构树脂中的结晶。 因此，本发明也包括这种成核间规聚丙烯的制品和组合物。
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17.发明授权Metals salts of hexahydrophthalic acid as nucleating additives for crystalline thermoplastics 有权六氢邻苯二甲酸的金属盐作为结晶热塑性塑料的成核添加剂公开(公告)号：US06599971B2
公开(公告)日：2003-07-29
申请号：US09820569
申请日：2001-03-29
申请人： Darin L. Dotson , X. Edward Zhao
发明人： Darin L. Dotson , X. Edward Zhao
IPC分类号： C08K504
摘要： Compounds and compositions comprising specific metal salts of hexahydrophthalic acid (HHPA) in order to provide highly desirable properties within thermoplastic articles are provided. The inventive HHPA derivatives are useful as nucleating and/or clarifying agents for such thermoplastics, are practical and easy to handle. Such compounds provide excellent crystallization temperatures, stiffness, and acid scavenger compatibility within target polyolefins. Also, such compounds exhibit very low hygroscopicity and therefore excellent shelf stability as powdered or granular formulations. Thermoplastic additive compositions and methods of producing polymers with such compounds are also contemplated within this invention.
摘要翻译： 提供了包含六氢邻苯二甲酸（HHPA）的特定金属盐以便在热塑性制品中提供高度期望性能的化合物和组合物。 本发明的HHPA衍生物可用作这种热塑性塑料的成核剂和/或澄清剂，实用且易于处理。 这些化合物在目标聚烯烃内提供优异的结晶温度，刚度和酸清除剂相容性。 此外，这些化合物显示出非常低的吸湿性，因此表现出作为粉末或颗粒制剂的优异的贮存稳定性。 本发明也考虑了热塑性添加剂组合物和用这些化合物生产聚合物的方法。
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18.发明授权Asymmetric monofluorinated benzaldehyde alditol derivatives and compositions and articles containing same 有权不对称单氟苯甲醛醛糖衍生物及含有它们的组合物和制品公开(公告)号：US06512030B2
公开(公告)日：2003-01-28
申请号：US09815631
申请日：2001-03-23
IPC分类号： C08K515
CPC分类号： A61K8/042 , A61K8/498 , A61Q15/00 , C07D493/04 , C08L23/10
摘要： Plastic additives which are useful as nucleating agents and which are especially useful for improving the optical properties of polymeric materials are provided. More particularly, this invention relates to certain asymmetric DBS compounds comprising monofluoro- or mono(trifluoroalkyl)-pendant groups on one ring of the aforementioned DBS and the other ring system cannot be monofluorinated. Such compounds may be added to or incorporated within polymer compositions which may then be utilized within, as merely examples, food or cosmetic containers and packaging. These inventive asymmetric benzylidene sorbitol acetals are also useful as gelling agents for water and organic solvents, particularly those used in the preparation of antiperspirant gel sticks.
摘要翻译： 提供可用作成核剂并且可用于改善聚合物材料的光学性能的塑料添加剂。 更具体地，本发明涉及在上述DBS的一个环上包含单氟或单（三氟烷基） - 侧基的某些不对称DBS化合物，另一个环系不能是单氟化的。 这样的化合物可以加入或掺入聚合物组合物中，然后这些化合物可以仅用于食品或化妆品容器和包装。 这些本发明的不对称亚苄基山梨糖醇缩醛也可用作水和有机溶剂的胶凝剂，特别是用于制备止汗凝胶棒的那些。
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公开(公告)号：US06500964B2
公开(公告)日：2002-12-31
申请号：US09815487
申请日：2001-03-23
IPC分类号： C07D32314
CPC分类号： C07D319/06 , C07D317/20 , C07D317/54
摘要： This invention relates to a process for preparing alditol acetals, such as dibenzylidene sorbitols, monobenzylidene sorbitols, and the like, through the reaction of unsubstituted or substituted benzaldehydes with alditols (such as sorbitol, xylitol, and ribitol) in the presence of a mineral acid and at least one surfactant having at least one pendant group of 6 carbon chains in length. Such a reaction provides a cost-effective, relatively safe procedure that provides excellent high yields of alditol acetal product. Furthermore, such a specific reaction is also the best known procedure for the production of certain compounds which can be easily separated from other formed isomers. Additionally, such a procedure facilitates the production of certain asymmetric alditol acetal compounds and compositions in acceptable yields as well. Such alditol acetals are useful as nucleating and clarifying agents for polyolefin formulations and articles, as one example.
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公开(公告)号：US08835542B2
公开(公告)日：2014-09-16
申请号：US13266331
申请日：2010-02-25
IPC分类号： C08K5/00
CPC分类号： C08K5/0083 , B29C47/0014 , B29C47/786 , B29C47/8805 , B29C47/90 , B29C47/904 , C08K5/5317 , C08L23/02
摘要： A composition comprises a thermoplastic and a nucleating agent. The thermoplastic can be a polyolefin selected from the group consisting of polypropylene homopolymers, polypropylene copolymers, polyethylene, polyethylene copolymers, polybutylene, poly(4 methyl 1 pentene) and mixtures thereof. The nucleating agent can comprise a metal salt of a phenylphosphonic acid. The nucleating agent can comprise primary particles having a mean aspect ratio of about two or more. The composition can also comprise an acid scavenger, such as one or more metal salts of stearic acid. The composition can be used to produce thermoplastic articles using, for example, injection molding and thermoforming techniques.
摘要翻译： 组合物包含热塑性和成核剂。 热塑性塑料可以是选自聚丙烯均聚物，聚丙烯共聚物，聚乙烯，聚乙烯共聚物，聚丁烯，聚（4-甲基戊烯）及其混合物的聚烯烃。 成核剂可以包含苯基膦酸的金属盐。 成核剂可以包含具有约两个或更多个平均纵横比的一次粒子。 组合物还可以包含酸清除剂，例如一种或多种硬脂酸金属盐。 组合物可以用于使用例如注射成型和热成型技术来生产热塑性制品。
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