公开(公告)号：US11666879B2

公开(公告)日：2023-06-06

申请号：US16981444

申请日：2019-04-18

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Wugeng Liang ,  Sagar Sarsani ,  David West ,  James Kauffman ,  Jonathan Banke ,  Hector Perez ,  Robert C. Schucker ,  Tian Gu ,  Vemuri Balakotaiah

IPC: B01J8/02 ,  C07C2/84

CPC classification number: B01J8/0278 ,  B01J8/0285 ,  C07C2/84 ,  B01J2208/00115 ,  B01J2208/022 ,  C07C2523/10

Abstract: Disclosed herein are systems and processes for the conversion of a methane feedstock to C2+ hydrocarbons.

公开(公告)号：US20220387973A1

公开(公告)日：2022-12-08

申请号：US17769879

申请日：2020-09-21

Applicant: SABIC Global Technologies B.V.

Inventor： Wugeng Liang ,  Luanyi Li ,  Hector Perez ,  Pankaj Gautam ,  David West

IPC: B01J23/10 ,  B01J23/02 ,  B01J37/02 ,  B01J37/08 ,  C07C2/84

Abstract: A multilayer supported oxidative coupling of methane (OCM) catalyst composition (support, first single oxide layer, one or more mixed oxide layers, optional second single oxide layer) characterized by formula AaZbEcDdOx/support; A is alkaline earth metal; Z is first rare earth element; E is second rare earth element; D is redox agent/third rare earth element; the first, second, third rare earth element are not the same; a=1.0; b=0.1-10.0; c=0.1-10.0; d=0-10.0; x balances oxidation states; first single oxide layer (Zb1Ox1, b1=0.1-10.0; x1 balances oxidation states) contacts support and one or more mixed oxide layers; one or more mixed oxide layers (Aa2Zb2Ec2Dd2Ox2, a2=1.0; b2=0.1-10.0; c2=0.1-10.0; d2=0-10.0; x2 balances oxidation states; AaZbEcDdOx and Aa2Zb2Ec2Dd2Ox2 are different) contacts first single oxide layer and optionally second single oxide layer, and second single oxide layer (AO), when present, contacts one or more mixed oxide layers and optionally first single oxide layer.

公开(公告)号：US11458458B2

公开(公告)日：2022-10-04

申请号：US16495554

申请日：2018-03-21

Applicant: Sabic Global Technologies, B.V.

Inventor： Wugeng Liang ,  David West ,  Luanyi Li ,  Vidya Sagar Reddy Sarsani ,  Hector Perez ,  James W. Kauffman

IPC: B01J23/10 ,  B01J23/00 ,  B01J37/08 ,  C07C2/84

Abstract: An OCM catalyst composition characterized by general formula AaLabEcDdOx; wherein A is an alkaline earth metal; wherein E is a first rare earth element; wherein D is a redox agent or a second rare earth element; wherein the first rare earth element and second rare earth element are different; wherein a is 1.0; wherein b is 0.01-10.0; wherein c is 0-10.0; wherein d is 0-10.0; and wherein x balances the oxidation states. The alkaline earth metal is selected from the group consisting of Mg, Ca, Sr, Ba, and combinations thereof. The first rare earth element and the second rare earth element can each independently be selected from the group consisting of Sc, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Y, Tb, Dy, Ho, Er, Tm, Yb, Lu, and combinations thereof. The redox agent is selected from the group consisting of Mn, W, Bi, Sb, Sn, Ce, Pr, and combinations thereof.

公开(公告)号：US11091410B2

公开(公告)日：2021-08-17

申请号：US16491398

申请日：2018-03-05

Applicant: SABIC Global Technologies, B.V.

Inventor： Wugeng Liang ,  Sagar Sarsani ,  Aghaddin Mamedov ,  Hector Perez ,  David West ,  Istvan Lengyel

IPC: C07C2/84 ,  B01J23/00 ,  B01J23/10 ,  B01J23/30 ,  B01J35/02 ,  B01J37/00 ,  B01J37/04 ,  B01J37/08

Abstract: A mixed oxide catalyst for the oxidative coupling of methane can include a catalyst with the formula AaBbCcDdOx, wherein: element A is selected from alkaline earth metals; elements B and C are selected from rare earth metals, and wherein elements B and C are different rare earth metals; the oxide of at least one of A, B, C, and D has basic properties; the oxide of at least one of A, B, C, and D has redox properties; and elements A, B, C, and D are selected to create a synergistic effect whereby the catalytic material provides a methane conversion of greater than or equal to 15% and a C2+ selectivity of greater than or equal to 70%. Systems and methods can include contacting the catalyst with methane and oxygen and purifying or collecting C2+ products.