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公开(公告)号:US20180083313A1
公开(公告)日:2018-03-22
申请号:US15813204
申请日:2017-11-15
Inventor: TAKAYUKI NAKATSUTSUMI , RYUICHI NATSUI , NOBUHIKO HOJO
IPC: H01M10/0525 , H01M10/0567 , H01M10/0569 , H01M10/0568 , H01M4/505 , H01M4/525 , C01G45/00 , C01G51/00 , C01G53/00
Abstract: A battery includes a positive electrode including a positive electrode active material, a negative electrode, and an electrolytic solution including an additive. The positive electrode active material includes a compound having a crystal structure belonging to a space group FM3-M and represented by Compositional Formula (1): LixMeyOαFβ, where, Me is one or more elements selected from the group consisting of Mn, Co, Ni, Fe, Al, B, Ce, Si, Zr, Nb, Pr, Ti, W, Ge, Mo, Sn, Bi, Cu, Mg, Ca, Ba, Sr, Y, Zn, Ga, Er, La, Sm, Yb, V, and Cr; and subscripts x, y, α, and β satisfy the following requirements: 1.7≦x≦2.2, 0.8≦y 1.3, 1≦α≦2.5, and 0.5≦β≦2. The additive is at least one selected from dinitrile compounds and diisocyanate compounds.
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公开(公告)号:US20170358827A1
公开(公告)日:2017-12-14
申请号:US15604657
申请日:2017-05-25
Inventor: HIROTETSU SUZUKI , NOBUHIKO HOJO
IPC: H01M10/0569
CPC classification number: H01M10/0569 , H01M10/052 , H01M10/054 , H01M10/0568 , H01M2300/0034 , H01M2300/0037
Abstract: A battery electrolyte comprises: a non-aqueous solvent including a perfluoropolyether that is functionalized at only one molecule end, the perfluoropolyether including perfluoroalkyl chains and oxygen atoms in such a manner that a perfluoroalkyl chain and an oxygen atom are alternately bound to each other; and a metal salt that is a magnesium salt, an alkaline earth metal salt, or an alkali metal salt, and that is dissolved in the non-aqueous solvent.
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公开(公告)号:US20170117534A1
公开(公告)日:2017-04-27
申请号:US15285065
申请日:2016-10-04
Inventor: AKIRA KANO , YUKIHIRO UMETANI , SHUJI ITO , NOBUHIKO HOJO
IPC: H01M4/133 , H01M4/587 , H01M4/62 , H01M10/0525
CPC classification number: H01M4/133 , H01M4/587 , H01M4/62 , H01M10/052 , H01M10/0525
Abstract: A negative electrode material includes a carbon material including boron. In a B1s spectrum of the carbon material which is measured by X-ray photoelectron spectroscopy, the ratio of the area of a peak that occurs at a binding energy of 187.0 eV or more and 188.5 eV or less to the total area of peaks that occur at a binding energy of 184.0 eV or more and 196.5 eV or less is 50% or more.
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公开(公告)号:US20180337423A1
公开(公告)日:2018-11-22
申请号:US15959290
申请日:2018-04-23
Inventor: TETSUYUKI OKANO , TAKAYUKI NAKATSUTSUMI , MAYUMI MAENISHI , MASAHIRO TAKAHATA , JUNKO MATSUSHITA , AKIRA KANO , NOBUHIKO HOJO
Abstract: A negative-electrode active material comprises a graphite including boron and nitrogen. A ratio R1 satisfies 0.5≤R1≤1, where R1=SBN/SB, and SB denotes a total peak area of a boron 1s spectrum of the graphite obtained by X-ray photoelectron spectroscopy, and SBN denotes a peak area of a spectrum assigned to boron bonded to nitrogen in the boron 1s spectrum. A ratio R2 satisfies 0
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公开(公告)号:US20180331392A1
公开(公告)日:2018-11-15
申请号:US15937807
申请日:2018-03-27
Inventor: TOMOFUMI HAMAMURA , NOBUHIKO HOJO , HIROTETSU SUZUKI
IPC: H01M10/0569 , H01M10/0567 , H01M10/0525
CPC classification number: H01M10/0569 , H01M10/0525 , H01M10/0567 , H01M2300/0034 , H01M2300/0037
Abstract: A nonaqueous electrolyte includes a nonaqueous solvent and an alkali metal salt dissolved in the nonaqueous solvent. The nonaqueous solvent contains a polar organic solvent, a perfluoropolyether, and a diester compound represented by a formula R1—O—C(═O)—[—(CF2)—]a—C(═O)—O—R2, where a is an integer of 1 to 4, and each of R1 and R2 represents one selected from the group consisting of an alkyl group having a carbon number of 1 to 4 and a hydrocarbon group which has a carbon number of 1 to 4 and in which at least one hydrogen atom is substituted with fluorine.
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公开(公告)号:US20180090790A1
公开(公告)日:2018-03-29
申请号:US15813210
申请日:2017-11-15
Inventor: TAKAYUKI NAKATSUTSUMI , RYUICHI NATSUI , NOBUHIKO HOJO
IPC: H01M10/0569 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/0568
Abstract: A battery includes a positive electrode including a positive electrode active material, a negative electrode, and an electrolytic solution including a nonaqueous solvent. The positive electrode active material includes a compound having a crystal structure belonging to a space group FM3-M and represented by Compositional Formula (1): LixMeyOαFβ, where, Me is one or more elements selected from the group consisting of Mn, Co, Ni, Fe, Al, B, Ce, Si, Zr, Nb, Pr, Ti, W, Ge, Mo, Sn, Bi, Cu, Mg, Ca, Ba, Sr, Y, Zn, Ga, Er, La, Sm, Yb, V, and Cr; and subscripts x, y, α, and β satisfy the following requirements: 1.7≦x≦2.2, 0.8≦y≦1.3, 1≦α≦2.5, and 0.5≦β≦2. The nonaqueous solvent includes a solvent having at least one fluoro group.
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公开(公告)号:US20180076484A1
公开(公告)日:2018-03-15
申请号:US15814874
申请日:2017-11-16
Inventor: TAKAYUKI NAKATSUTSUMI , RYUICHI NATSUI , NOBUHIKO HOJO
IPC: H01M10/0567 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M4/485 , H01M4/62
Abstract: A battery includes a positive electrode including a positive electrode active material, a negative electrode, and an electrolytic solution including a lithium hexafluorophosphate and an additive. The positive electrode active material includes a compound having a crystal structure belonging to a space group FM3-M and represented by Compositional Formula (1): LixMeyOαFβ. The additive is at least one selected from the group consisting of difluorophosphates, tetrafluoroborates, bis(oxalate)borate salts, bis(trifluoromethanesulfonyl)imide salts, and bis(fluorosulfonyl)imide salts.
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公开(公告)号:US20180048004A1
公开(公告)日:2018-02-15
申请号:US15796650
申请日:2017-10-27
Inventor: NOBUHIKO HOJO
IPC: H01M8/04276 , H01M8/18
CPC classification number: H01M8/04283 , H01M8/18 , H01M8/188 , Y02E60/528
Abstract: A redox flow battery includes first and second electrodes, a separator separating the first and second electrodes, an active material, an electrolytic solution containing a redox species, and a circulation mechanism. The active material is insoluble in the electrolytic solution. The circulation mechanism circulates the electrolytic solution between the first electrode and the active material. The redox species performs oxidation and reduction at the first electrode and is oxidized and reduced by the active material. The circulation mechanism includes an electrolytic solution container containing the active material and a permeation preventing unit. The electrolytic solution is brought into contact with the active material in the electrolytic solution container, and the redox species is oxidized and reduced by the active material. The permeation preventing unit is disposed adjacent the outlet for the electrolytic solution of the electrolytic solution container and prevents permeation of the active material.
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公开(公告)号:US20160351959A1
公开(公告)日:2016-12-01
申请号:US15158593
申请日:2016-05-19
Inventor: HIROTETSU SUZUKI , NOBUHIKO HOJO
IPC: H01M10/0565 , H01M10/0525
CPC classification number: H01M10/0565 , H01M10/0525 , H01M10/0567 , H01M10/0568 , H01M10/0569 , H01M2300/0034 , H01M2300/0037
Abstract: Provided is an electrolytic solution including a nonaqueous solvent and an alkali metal salt. The alkali metal salt is dissolved in the nonaqueous solvent. The nonaqueous solvent contains a perfluoropolyether having a weight-average molecular weight of 350 or more and less than 760. Also provided is a battery including the electrolytic solution, a positive electrode containing a positive electrode active material that can occlude and release an alkali metal cation, and a negative electrode containing a negative electrode active material that can occlude and release the alkali metal cation.
Abstract translation: 提供了包含非水溶剂和碱金属盐的电解液。 将碱金属盐溶解在非水溶剂中。 非水溶剂含有重均分子量为350以上且小于760的全氟聚醚。还提供了包含电解液的电池,含有能够吸留和释放碱金属阳离子的正极活性物质的正极 以及含有负极活性物质的负极,所述负极活性物质可以封闭和释放碱金属阳离子。
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公开(公告)号:US20160351958A1
公开(公告)日:2016-12-01
申请号:US15158592
申请日:2016-05-19
Inventor: HIROTETSU SUZUKI , NOBUHIKO HOJO
IPC: H01M10/0565 , H01M10/0525
CPC classification number: H01M10/0565 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M2300/0034 , H01M2300/0037
Abstract: Provided is an electrolytic solution including a nonaqueous solvent and an alkali metal salt. The alkali metal salt is dissolved in the nonaqueous solvent. The nonaqueous solvent contains a perfluoropolyether. The molecular ends of the perfluoropolyether are each an unsubstituted alkyl ether or an unsubstituted carboxylate. The perfluoropolyether has a repeating unit composed of a perfluoroalkyl chain and an oxygen atom. Also provided is a battery including the electrolytic solution, a positive electrode containing a positive electrode active material that can occlude and release an alkali metal cation, and a negative electrode containing a negative electrode active material that can occlude and release the alkali metal cation.
Abstract translation: 提供了包含非水溶剂和碱金属盐的电解液。 将碱金属盐溶解在非水溶剂中。 非水溶剂含有全氟聚醚。 全氟聚醚的分子末端各自为未取代的烷基醚或未取代的羧酸酯。 全氟聚醚具有由全氟烷基链和氧原子组成的重复单元。 还提供一种电池,包括电解液,含有可以封闭和释放碱金属阳离子的正极活性物质的正极和含有可以封闭和释放碱金属阳离子的负极活性物质的负极。
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