公开(公告)号：US20160359175A1

公开(公告)日：2016-12-08

申请号：US15101063

申请日：2014-12-17

Applicant: NGK SPARK PLUG CO., LTD.

Inventor： Yasuo OKUYAMA ,  Makoto KURIBAYASHI ,  Etsuya IKEDA

IPC: H01M8/0206 ,  H01M8/0228 ,  H01M8/1213 ,  H01M8/2432

CPC classification number: H01M8/0206 ,  H01M8/0228 ,  H01M8/0273 ,  H01M8/0297 ,  H01M8/1213 ,  H01M8/241 ,  H01M8/2432 ,  H01M2008/1293

Abstract: A metal plate-bonded single fuel cell unit according to one aspect of the present invention includes a single cell element having a solid electrolyte and fuel and air electrodes disposed on opposite sides of the solid electrolyte and a metal plate bonded by a brazing material to the single cell element. The metal plate contains Ti and Al and has an Al-Ti-containing oxide layer present on a surface of the metal plate, an Al oxide film present on a surface of the Al-Ti-containing oxide layer and a Ti-containing phase apart from a part of a surface of the Al oxide film in contact with the brazing material while being present on a remaining part of the surface of the Al oxide film. The metal plate-bonded single fuel cell unit has a Ti reaction phase formed at an interface between the solid electrolyte and the brazing material.

Abstract translation: 根据本发明的一个方面的金属板结合单燃料电池单元包括具有固体电解质的单电池元件和设置在固体电解质的相对侧上的燃料和空气电极以及通过钎焊材料粘合到所述固体电解质的金属板 单细胞元素。 金属板包含Ti和Al，并且在金属板的表面上存在Al-Ti的氧化物层，存在于含Al-Ti的氧化物层的表面上的Al氧化物膜和分开的含Ti相 从Al氧化物膜的与钎料接触的表面的一部分，同时存在于Al氧化物膜的表面的剩余部分上。 金属板结合单燃料电池单元具有在固体电解质和钎焊材料之间的界面处形成的Ti反应相。