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    Cyclohexanedione derivatives
    11.
    发明授权
    Cyclohexanedione derivatives 失效
    环己酮衍生物

    公开(公告)号：US5480858A

    公开(公告)日：1996-01-02

    申请号：US373218

    申请日：1995-01-13

    Applicant: Masashi Sakamoto ,  Mitsuru Shibata ,  Ichiro Nasuno ,  Kazuyoshi Koike

    Inventor： Masashi Sakamoto ,  Mitsuru Shibata ,  Ichiro Nasuno ,  Kazuyoshi Koike

    IPC: A01N43/18 ,  C07D335/06 ,  A01N43/16

    CPC classification number: C07D335/06 ,  A01N43/18

    Abstract: Cyclohexanedione derivatives of the formula (I), ##STR1## wherein R.sup.1 is a C.sub.1 -C.sub.6 alkyl group, R.sup.2 is a C.sub.1 -C.sub.4 alkyl group, each of R.sup.3, R.sup.4 and R.sup.5 is independently hydrogen or a C.sub.1 -C.sub.4 alkyl group, and n is an integer of 0 to 2, or salts thereof exhibit high selectivity for corn, wheat and barley, and can control gramineous weeds and broad-leaved weeds at low dosages.

    Abstract translation: PCT No.PCT / JP93 / 01107 Sec。 371日期1995年1月13日 102（e）日期1995年1月13日PCT提交1993年8月6日PCT公布。 出版物WO94 / 0452400 日本3月3日公开了式（I）的环己二酮衍生物，其中R1是C1-C6烷基，R2是C1-C4烷基，R3，R4和R5各自独立地是 氢或C1-C4烷基，n为0〜2的整数，或其盐对玉米，小麦和大麦表现出高选择性，并且可以以低剂量控制禾本科杂草和阔叶杂草。

    Trifluoromethanesulfonamide derivative and a herbicide containing the same
    12.
    发明授权
    Trifluoromethanesulfonamide derivative and a herbicide containing the same 失效
    三氟甲磺酰胺衍生物和含有它们的除草剂

    公开(公告)号：US5035739A

    公开(公告)日：1991-07-30

    申请号：US471108

    申请日：1990-01-26

    Applicant: Mitsuru Shibata ,  Yoshiyuki Hiramatsu ,  Ryoichi Adachi ,  Kenichiro Mitsutake

    Inventor： Mitsuru Shibata ,  Yoshiyuki Hiramatsu ,  Ryoichi Adachi ,  Kenichiro Mitsutake

    IPC: A01N47/02 ,  C07D279/02 ,  C07D311/60 ,  C07D311/68 ,  C07D335/06

    CPC classification number: C07D335/06 ,  A01N47/02 ,  C07D279/02 ,  C07D311/60 ,  C07D311/68

    Abstract: The present invention relates to a trifluoromethanesulfonamide derivative represented by the general formula given below, a herbicide with the derivative as the active ingredient and a method for the preparation of the derivative. ##STR1## [In the formula, X is a hydrogen atom, a halogen atom, an alkyl group having 1 to 4 carbon atoms or a haloalkyl group having 1 to 4 carbon atoms, n is 1, 2 or 3 and A is --O--CR.sup.3 R.sup.4 --, --S--CR.sup.3 R.sup.4 --, --SO--CR.sup.3 R.sup.4 --, --SO.sub.2 --CR.sup.3 R.sup.4 -- or --SO.sub.2 --NR.sup.3 --. And, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.]These compounds are prepared depending on A in the above given general formula by the reaction of an amine derivative and a trifluoromethanesulfonyl halide or trifluoromethanesulfonic anhydride or by the oxidation of a thiochroman ring-containing trifluoromethanesulfonamide derivative.Further, these trifluoromethanesulfonamide derivatives are useful as a herbicide and serve to weeding of weeds without phytotoxicity against crops in upland field. These trifluoromethanesulfonamide derivatives can also be used as a plant growth regulator.

    Abstract translation: 本发明涉及以下通式表示的三氟甲磺酰胺衍生物，该衍生物作为活性成分的除草剂及其衍生物的制备方法。 [式中，X为氢原子，卤素原子，碳原子数1〜4的烷基或碳原子数1〜4的卤代烷基，n为1,2或3，A为-O -CR 3 R 4 - ， - S - CR 3 R 4 - ， - SO-CR 3 R 4 - ， - SO 2 - CR 3 R 4 - 或-SO 2 NR 3 - 。 并且，R 1，R 2，R 3和R 4各自为氢原子或具有1至4个碳原子的烷基。]这些化合物根据上述通式中的A，通过胺衍生物和三氟甲磺酰卤的反应制备 或三氟甲磺酸酐或通过含二氢苯并噻喃环的三氟甲磺酰胺衍生物的氧化。 此外，这些三氟甲磺酰胺衍生物可用作除草剂，并用于在高地田间对作物无植物毒性的杂草除草。 这些三氟甲磺酰胺衍生物也可以用作植物生长调节剂。

    Triketone derivatives
    15.
    发明授权
    Triketone derivatives 失效
    三酮衍生物

    公开(公告)号：US5990049A

    公开(公告)日：1999-11-23

    申请号：US228892

    申请日：1999-01-11

    Applicant: Kazufumi Nakamura ,  Mitsuru Shibata ,  Kazuyoshi Koike

    Inventor： Kazufumi Nakamura ,  Mitsuru Shibata ,  Kazuyoshi Koike

    IPC: A01N43/18 ,  C07D335/06 ,  C07D409/06 ,  A01N43/16

    CPC classification number: C07D335/06 ,  A01N43/18 ,  C07D409/06

    Abstract: A triketone compound of the following formula: ##STR1## wherein Y.sup.1 is C.sub.1 to C.sub.4 alkyl, a halogen or a C.sub.1 to C.sub.4 haloalkyl; each of Y.sup.2 and Y.sup.3 is independently C.sub.1 to C.sub.4 alkyl; Y.sup.4 is hydrogen, C.sub.1 to C.sub.4 alkyl or a halogen; n is 0, 1 or 2; p is 0 or 1; each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4 is independently hydrogen, C.sub.1 to C.sub.4 alkyl or phenyl; or when p is 1, either R.sup.1 or R.sup.2 and either R.sup.3 or R.sup.4 optionally bond to each other to form an intramolecular double bond; and X is a group of the formula ##STR2## in which each of R.sup.5 and R.sup.6 is independently a hydrogen atom, a C.sub.1 to C.sub.4 alkyl group or a phenyl group. The triketone compound is useful as a herbicide to control a broad range of upland weeks at a low dosage without causing phytotoxicity on corn.

    Abstract translation: 下式的三酮化合物：其中Y 1为C 1至C 4烷基，卤素或C 1至C 4卤代烷基; Y2和Y3各自独立地为C1-C4烷基; Y4是氢，C1-C4烷基或卤素; n为0,1或2; p为0或1; R 1，R 2，R 3和R 4各自独立地为氢，C 1至C 4烷基或苯基; 或当p为1时，R 1或R 2以及R 3或R 4任选地彼此键合以形成分子内双键; 并且X是下式的基团，其中R 5和R 6各自独立地为氢原子，C 1至C 4烷基或苯基。 三酮化合物可用作除草剂，以低剂量控制宽范围的高地周期，而不会对玉米造成植物毒性。

    Pyrazole process and intermediates
    16.
    发明授权
    Pyrazole process and intermediates 失效
    吡唑工艺和中间体

    公开(公告)号：US5587484A

    公开(公告)日：1996-12-24

    申请号：US509963

    申请日：1995-08-01

    Applicant: Mitsuru Shibata ,  Masashi Sakamoto ,  Ichiro Nasuno

    Inventor： Mitsuru Shibata ,  Masashi Sakamoto ,  Ichiro Nasuno

    IPC: A01N43/56 ,  C07D335/06 ,  C07D409/06

    CPC classification number: A01N43/56 ,  C07D335/06 ,  C07D409/06

    Abstract: Processes for producing a pyrazole compound by reacting a compound ##STR1## wherein R.sup.1 is a C.sub.1 -C.sub.6 alkyl, each of R.sup.2, R.sup.3, R.sup.4 and R.sup.5 is hydrogen or a C.sub.1 -C.sub.4 alkyl, X.sup.1 is a C.sub.1 -C.sub.4 alkyl or a halogen, n is 1 to 3, and p.sup.1 is 0 to 2, with a compound ##STR2## wherein R.sup.6 is a C.sub.1 -C.sub.4 alkyl and R.sup.7 is hydrogen or a C.sub.1 -C.sub.4 alkyl, to form a pyrazole compound ##STR3## and optionally reacting the pyrazole compound (Ia) with a sulfonic acid halide of the formula Q.sup.2 X.sup.2 (IV)wherein Q.sup.2 is --SO.sub.2 --R.sup.8 or ##STR4## in which R.sup.8 is a C.sub.1 -C.sub.6 alkyl, Y is hydrogen, a C.sub.1 -C.sub.1 alkyl or a halogen, m.sup.1 is 1 to 3, and X.sup.2 is a halogen. Alternatively, the compound of the formula (II) is reacted with a halogenation agent to produce a compound which is reacted with a compound of the formula (III) to produce a compound which is heated to form a compound of the formula (Ia).

    Abstract translation: 通过使化合物（II）（其中R1是C1-C6烷基，R2，R3，R4和R5各自是氢或C1-C4烷基）反应制备吡唑化合物的方法，X1是C1-C4烷基 或卤素，n为1〜3，p1为0〜2，其中R6为C1-C4烷基，R7为氢或C1-C4烷基的化合物（III），形成吡唑化合物 （Ia），并任选地使吡唑化合物（Ia）与式Q2X2（IV）的磺酰卤反应，其中Q 2是-SO 2 -R 8或其中R 8是C 1 -C 6烷基，Y是 氢，C1-C1烷基或卤素，m1为1〜3，X2为卤素。 或者，将式（II）化合物与卤化剂反应，生成与式（III）化合物反应的化合物，生成加热形成式（Ia）化合物的化合物。

    Trifluoromethanesulfonamide derivative, a method for the preparation thereof and a herbicide containing the same
    17.
    发明授权
    Trifluoromethanesulfonamide derivative, a method for the preparation thereof and a herbicide containing the same 失效
    三氟甲磺酰胺衍生物，其制备方法和含有它们的除草剂

    公开(公告)号：US4919705A

    公开(公告)日：1990-04-24

    申请号：US254935

    申请日：1988-09-06

    Applicant: Mitsuru Shibata ,  Yoshiyuki Hiramatsu ,  Ryoichi Adachi ,  Kenichiro Mitsutake

    Inventor： Mitsuru Shibata ,  Yoshiyuki Hiramatsu ,  Ryoichi Adachi ,  Kenichiro Mitsutake

    IPC: A01N47/02 ,  C07D279/02 ,  C07D311/60 ,  C07D311/68 ,  C07D335/06

    CPC classification number: C07D335/06 ,  A01N47/02 ,  C07D279/02 ,  C07D311/60 ,  C07D311/68

    Abstract: The present invention relates to a trifluoromethanesulfonamide derivative represented by the general formula given below, a herbicide with the derivative as the active ingredient and a method for the preparation of the derivative. ##STR1## [In the formula, X is a hydrogen atom, a halogen atom, an alkyl group having 1 to 4 carbon atoms or a haloalkyl group having 1 to 4 carbon atoms, n is 1, 2 or 3 and A is --O--CR.sup.3 R.sup.4 --, --S--CR.sup.3 R.sup.4 --, --SO--CR.sup.3 R.sup.4 --, --SO.sub.2 --CR.sup.3 R.sup.4 -- or --SO.sub.2 --NR.sup.3 --. And, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.]These compounds are prepared depending on A in the above given general formula by the reaction of an amine derivative and a trifluoromethansulfonyl halide or trifluoromethanesulfonic anhydride or by the oxidation of a thiochroman ring-containing trifluoromethanesulfonamide derivative.Further, these trifluoromethanesulfonamide derivatives are useful as a herbicide and serve to weeding of weeds without phytotoxicity against crops in upland field. These trifluoromethanesulfonamide derivatives can also be used as a plant growth regulator.

    Image processing apparatus, image processing method, and program
    18.
    发明授权
    Image processing apparatus, image processing method, and program 有权
    图像处理装置，图像处理方法和程序

    公开(公告)号：US08922629B2

    公开(公告)日：2014-12-30

    申请号：US12924531

    申请日：2010-09-29

    Applicant: Mitsuru Shibata

    Inventor： Mitsuru Shibata

    IPC: H04N13/04 ,  H04N13/00

    CPC classification number: H04N13/398 ,  H04N13/122

    Abstract: An image processing apparatus includes a controller that selects, from multiple images photographed from different viewpoints, a set of images for three-dimensional image display. The controller determines whether or not amount-of-movement information corresponding to a parallax between the images is recorded as attribute information of the images. When the amount-of-movement information is recorded, the controller selects a combination of images having a parallax corresponding to a display size of a display section by using the recorded amount-of-movement information. When the amount-of-movement information is not recorded, the controller selects a combination of images having a parallax corresponding to the display size by determining an amount of movement through use of information resulting from determination of degrees of block matching between images divided into blocks and using information of the determined amount of movement.

    Abstract translation: 一种图像处理装置，包括从不同视点拍摄的多个图像中选择用于三维图像显示的一组图像的控制器。 是否记录与图像之间的视差相对应的移动量信息，作为图像的属性信息。 当记录移动量信息时，控制器通过使用记录的移动量信息来选择具有与显示部分的显示尺寸相对应的视差的图像的组合。 当未记录移动量信息时，控制器通过使用由分割成块的图像之间的块匹配度确定得到的信息来确定移动量来选择具有与显示尺寸相对应的视差的图像的组合 并使用确定的移动量的信息。

    Pyrazole derivatives and herbicides containing the same
    19.
    发明授权
    Pyrazole derivatives and herbicides containing the same 失效
    吡唑衍生物和含有它们的除草剂

    公开(公告)号：US5849926A

    公开(公告)日：1998-12-15

    申请号：US9447

    申请日：1998-01-14

    Applicant: Mitsuru Shibata ,  Kazuyoshi Koike ,  Masashi Sakamoto ,  Yoriyuki Takashima

    Inventor： Mitsuru Shibata ,  Kazuyoshi Koike ,  Masashi Sakamoto ,  Yoriyuki Takashima

    IPC: A01N43/56 ,  A01P13/00 ,  C07D409/06 ,  A01N43/50 ,  C07D335/06

    CPC classification number: C07D409/06 ,  A01N43/56

    Abstract: A pyrazole compound of the formula ##STR1## wherein R.sup.11 is a C.sub.1 -C.sub.6 alkyl; each of R.sup.12, R.sup.13, R.sup.14 and R.sup.15 is hydrogen or C.sub.1 -C.sub.4 alkyl; R.sup.16 is C.sub.1 -C.sub.4 alkyl; R.sup.17 is hydrogen or C.sub.1 -C.sub.4 alkyl; X.sup.3 is C.sub.1 -C.sub.4 alkyl or hydrogen; p is 0, 1 or 2; A.sup.2 is ##STR2## or --CR.sup.18 R.sup.19 in which each of R.sup.18 and R.sup.19 is C.sub.1 -C.sub.4 alkyl; R is 0 to 3; B is C.sub.1 -C.sub.12 alkyl, cycloalkyl or the formula ##STR3## wherein Y is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkyl, nitro or halogen; and n is 1 or 2. The pyrazole compounds are used as herbicides.

    Abstract translation: 式IMA的吡唑化合物，其中R11是C1-C6烷基; R 12，R 13，R 14和R 15各自为氢或C 1 -C 4烷基; R16是C1-C4烷基; R 17是氢或C 1 -C 4烷基; X3是C1-C4烷基或氢; p为0,1或2; 或者-CR18R19，其中R18和R19各自为C1-C4烷基; R为0〜3; B是C 1 -C 12烷基，环烷基或式其中Y是氢，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷基，硝基或卤素; 并且n为1或2.吡唑化合物用作除草剂。

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