公开(公告)号：US5576361A

公开(公告)日：1996-11-19

申请号：US421269

申请日：1995-04-20

申请人： Gary P. Craun

发明人： Gary P. Craun

IPC分类号： C08L63/00 ,  C09D133/06 ,  C09D151/08 ,  C09D163/00 ,  C09D167/00 ,  C08K3/20

CPC分类号： C09D133/064 ,  C09D151/08 ,  C09D163/00 ,  C09D167/00 ,  C08L2205/18 ,  C08L63/00

摘要： Protective coating compositions free of volatile organic solvents and particularly useful as can coatings are produced based on an aqueous dispersed microgel polymeric binder comprising between about 1% and 70% low molecular weight polyester diluent, between about 1% and 70% epoxy resin, between about 10% and 80% addition copolymer, and between about 1% and 40% low molecular weight diepoxide crosslinking resin. The aqueous dispersed solvent free microgel polymer is produced by mixing the polyester diluent with high molecular weight epoxy to produce a fluid resin mixture, copolymerizing in-situ ethylenically unsature monomers including carboxyl monomers in the presence of the fluid resin mixture and dispersing the resulting polymeric mixture into water. Low molecular weight diepoxide resin is added and crosslinked with carboxyl functionality to produce the microgel polymers.

摘要翻译： 基于包含约1％至70％的低分子量聚酯稀释剂，约1％至70％的环氧树脂之间的含水分散的微凝胶聚合物粘合剂，在约 10％和80％的加成共聚物，和约1％至40％的低分子量二环氧化物交联树脂。 通过将聚酯稀释剂与高分子量环氧树脂混合以产生流体树脂混合物，在流体树脂混合物存在下共聚原位含烯属不完全单体（包括羧基单体）并分散所得聚合物混合物来制备水分散无溶剂微凝胶聚合物 进水 加入低分子量二环氧化物树脂并用羧基官能团交联以产生微凝胶聚合物。

公开(公告)号：US5104928A

公开(公告)日：1992-04-14

申请号：US464210

申请日：1990-01-12

申请人： Gary P. Craun ,  David L. Trumbo ,  Frank A. Wickert

发明人： Gary P. Craun ,  David L. Trumbo ,  Frank A. Wickert

IPC分类号： C08F283/00 ,  C08G18/83 ,  C09D175/04

CPC分类号： C08F283/00 ,  C08G18/833 ,  C09D175/04

摘要： Thermosetting coating compositions are based on a binder comprising carboxyl functional polyurethane, acrylic copolymer, and if desired a carbodiimide crosslinker. The binder is produced by synthesizing an isocyanate terminated, carboxyl functional urethane prepolymer in the absence of water and organic solvent but in the presence of ethylenic monomers. The organic phase urethane prepolymer dispersed in ethylenic monomers is inverted into water whereupon the urethane prepolymer is extended by reaction with a primary or secondary polyamine such as diamine to produce a high molecular weight polyurethane-urea. Thereafter, the ethylenic monomers are copolymerized to form an aqueous dispersed polyurethane-urea and acrylic copolymer mixture. The resulting polymeric binder is useful in protective surface coatings applied to plastic substrates. A carbodiimide can be added to provide thermosetting crosslinking with the carboxyl functional polyurethane.

摘要翻译： 热固性涂料组合物基于包含羧基官能聚氨酯，丙烯酸共聚物和如果需要的碳二亚胺交联剂的粘合剂。 粘合剂通过在不存在水和有机溶剂的情况下合成异氰酸酯封端的羧基官能氨基甲酸酯预聚物，但在烯属单体的存在下制备。 分散在乙烯单体中的有机相氨基甲酸酯预聚物倒入水中，通过与伯胺或仲胺如二胺反应来延长氨基甲酸酯预聚物以产生高分子量聚氨酯 - 脲。 此后，将乙烯类单体共聚形成水分散的聚氨酯 - 脲和丙烯酸共聚物混合物。 所得聚合物粘合剂可用于施加到塑料基材上的保护性表面涂层。 可以加入碳二亚胺以提供与羧基官能聚氨酯的热固性交联。

公开(公告)号：US5093425A

公开(公告)日：1992-03-03

申请号：US437181

申请日：1989-11-16

申请人： Gary P. Craun ,  Barbara L. Kunz

发明人： Gary P. Craun ,  Barbara L. Kunz

IPC分类号： C08L33/14 ,  C09D133/14

CPC分类号： C09D133/14 ,  C08L2205/02 ,  C08L33/14

摘要： Thermosetting coating compositions are based on thermosetting polymeric binder comprising a blocked sulfonic acid functional addition polymer of copolymerized monomers, including sulfonic acid monomer, adapted to coreact upon heating with amine crosslinker.

摘要翻译： 热固性涂料组合物基于热固性聚合物粘合剂，其包含共聚单体的封端的磺酸官能加成聚合物，包括磺酸单体，适于在用胺交联剂加热时进行共核反应。

公开(公告)号：US4906693A

公开(公告)日：1990-03-06

申请号：US157249

申请日：1988-02-18

申请人： Gary P. Craun ,  David L. Trumbo

发明人： Gary P. Craun ,  David L. Trumbo

IPC分类号： C08F8/14 ,  C08L67/00 ,  C09D125/14 ,  C09D133/06 ,  C09D167/00 ,  C09D201/06

CPC分类号： C09D201/06 ,  C08F8/14 ,  C09D125/14 ,  C09D133/066 ,  C09D167/00 ,  C08L67/00

摘要： Transesterification curing of ester polymers and hydroxyl polymers is effected by the inclusion of a transesterification catalyst comprising a catalytic amount of epoxy resin and certain inorganic salts.

摘要翻译： 酯聚合物和羟基聚合物的酯交换固化通过包含含有催化量的环氧树脂和某些无机盐的酯交换催化剂来实现。

公开(公告)号：US4666964A

公开(公告)日：1987-05-19

申请号：US722050

申请日：1985-04-11

申请人： Wood E. Hunter ,  Gary P. Craun

发明人： Wood E. Hunter ,  Gary P. Craun

IPC分类号： C08J3/12 ,  C08K5/19 ,  C08K5/16 ,  C08K5/32

CPC分类号： C08J3/124 ,  C08J2300/14 ,  Y10S524/912 ,  Y10S524/916

摘要： The instant invention is directed to a method for preparing free-flowing, water-soluble polymer gels comprising:(a) reducing the size of water-soluble polymer gels by a size-reduction means, so as to produce polymer gel particles which are less than 1/2 inch in their longest dimension; and(b) adding to the size-reduced polymer gels of Step (a) 0.001 to 20 percent, by weight, of an amphipathic compound, thereby reducing the adhesion of said gel particles to themselves and other substances.The instant invention is also directed to a free-flowing, water-soluble polymer gel admixture comprising:(a) size-reduced, water-soluble polymer gel particles, wherein said gel particles are less than 1/2 inch in their longest dimension; and(b) an amphipathic compound.

摘要翻译： 本发明涉及一种制备自由流动的水溶性聚合物凝胶的方法，其包括：（a）通过减小尺寸的方法减小水溶性聚合物凝胶的尺寸，以便产生较少的聚合物凝胶颗粒 超过1/2英寸的最长尺寸; 和（b）向步骤（a）的尺寸减小的聚合物凝胶中加入0.001至20重量％的两亲性化合物，从而降低所述凝胶颗粒对其自身和其它物质的粘附性。 本发明还涉及一种自由流动的水溶性聚合物凝胶混合物，其包含：（a）尺寸减小的水溶性聚合物凝胶颗粒，其中所述凝胶颗粒的最长尺寸小于1/2英寸; 和（b）两亲性化合物。

公开(公告)号：US20120022186A1

公开(公告)日：2012-01-26

申请号：US13147839

申请日：2010-03-02

申请人： Gary P. Craun ,  Guy J. Stella ,  Kenneth J. Gardner ,  David J. Telford

发明人： Gary P. Craun ,  Guy J. Stella ,  Kenneth J. Gardner ,  David J. Telford

IPC分类号： C08K5/09 ,  B05D3/10

CPC分类号： C08F289/00 ,  B32B27/285 ,  C08G65/14 ,  C08L61/06 ,  C08L61/24 ,  C08L61/26 ,  C08L61/28 ,  C08L67/00 ,  C08L69/00 ,  C08L71/02 ,  C08L71/08 ,  C08L75/00 ,  C09D151/00 ,  C09D191/00 ,  C08L2666/14 ,  C08L2666/02 ,  C08L2666/18

摘要： Hydroxyl functional oil polyols are disclosed which can be used to produce coating compositions and coated surfaces. In some embodiments, the coating compositions are used to coat substrates such as packaging materials and the like for the storage of food and beverages. The hydroxyl functional oil polyols can be prepared by reacting an epoxidized vegetable oil with a hydroxyl functional material in the presence of an acid catalyst. Coating compositions can be prepared by crosslinking the hydroxyl functional oil polyols with a crosslinker.

摘要翻译： 公开了可用于生产涂料组合物和涂布表面的羟基官能油多元醇。 在一些实施方案中，涂料组合物用于涂覆诸如包装材料等的基材以用于储存食品和饮料。 羟基官能油多元醇可以通过在酸催化剂存在下使环氧化植物油与羟基官能物质反应来制备。 涂料组合物可以通过用交联剂交联羟基官能油多元醇来制备。

公开(公告)号：US07049357B2

公开(公告)日：2006-05-23

申请号：US09839049

申请日：2001-04-23

申请人： Gary P. Craun ,  Jude Thomas Rademacher

发明人： Gary P. Craun ,  Jude Thomas Rademacher

IPC分类号： C08K5/092

CPC分类号： C08K5/10 ,  C08L67/04

摘要： An aqueous ambient dry decorative or protective coating comprising a film forming matrix polymer of an aqueous emulsion polymer of aqueous copolymerized ethylenically unsaturated monomers modified with at least 3% by weight of a low molecular weight oligomer of copolymerized hydroxy alkanoic acid having 2 to 4 carbon atoms having a number average molecular weight between 300 and 10,000 to provide a film forming binder substantially free of volatile organic coalescing solvents. Preferred oligomers are homopolymers and copolymers of polymerized lactic acid or polymerized glycolic acid.

摘要翻译： 一种水性环境干燥装饰或保护涂层，其包含用至少3重量％的具有2至4个碳原子的共聚羟基链烷酸的低分子量低聚物改性的含水共聚烯键式不饱和单体的水性乳液聚合物的成膜基质聚合物 数均分子量在300和10,000之间，以提供基本上不含挥发性有机聚结溶剂的成膜粘合剂。 优选的低聚物是聚合的乳酸或聚合的乙醇酸的均聚物和共聚物。

公开(公告)号：US06646085B1

公开(公告)日：2003-11-11

申请号：US09665024

申请日：2000-09-19

申请人： Gary P. Craun ,  Kenneth G. Hahn ,  George P. Rosekelly

发明人： Gary P. Craun ,  Kenneth G. Hahn ,  George P. Rosekelly

IPC分类号： C08F12068

CPC分类号： C08F220/68 ,  C08F222/26

摘要： An ambient dry water dispersed coating composition substantially free of volatile organic coalescing solvents, the coating composition containing a polymer film forming binder comprises between 40% and 50% copolymerized non-conjugated, unsaturated fatty acid triglyceride, between 40% and 55% copolymerized ethylenic monomer including styrene, and between 3% and 12% copolymerized maleic anhydride. The film forming copolymer is produced by first reacting maleic anhydride with the fatty acid triglyceride at high temperatures between 140° C. to form a maleinized triglyceride having a pendent maleic anhydride structure. The maleinized triglyceride is then styrenated at temperatures between about 80° C. and 200° C. in the presence of at least 4% peroxide initiator based on the weight of monomers copolymerized to form a styrenated, maleinized fatty acid triglyceride copolymer having anhydride groups. The anhydride groups are neutralized with amine or ammonia and the neutralized copolymer is dispersed in water.

摘要翻译： 基本上不含挥发性有机聚结溶剂的环境干燥水分散涂料组合物，含有聚合物膜形成粘合剂的涂料组合物包含40％至50％共聚的非共轭不饱和脂肪酸甘油三酯，40％至55％的共聚乙烯单体 包括苯乙烯，以及3％至12％的共聚马来酸酐。 成膜共聚物通过首先使马来酸酐与脂肪酸甘油三酸酯在140℃的高温下反应，以形成具有悬挂马来酸酐结构的马来酸甘油三酯。 然后，在至少4％过氧化物引发剂的存在下，在约80℃和200℃之间的温度下，将马来化甘油三酸酯苯乙烯基于共聚合形成具有酸酐基团的苯乙烯化马来酸化脂肪酸甘油三酯共聚物的单体重量。 酸酐基团用胺或氨中和，中和的共聚物分散在水中。

公开(公告)号：US5877239A

公开(公告)日：1999-03-02

申请号：US916716

申请日：1997-08-18

申请人： Gary P. Craun ,  Beth A. Smith ,  Neal S. Williams

发明人： Gary P. Craun ,  Beth A. Smith ,  Neal S. Williams

IPC分类号： C08F8/08 ,  C09D201/06 ,  C08K3/20 ,  C08L33/02 ,  C08L63/00 ,  C08L63/02

CPC分类号： C09D201/06 ,  C09D201/08

摘要： An aqueous protective coating composition particularly useful for can coatings based on a polymeric binder comprises diepoxide crosslinked microgel particles. The microgel polymer is produced by dispersing into water a carboxyl functional acrylic-epoxy copolymer and combined with a carboxyl functional latex polymer along with a low molecular weight diepoxide, followed by coreaction and crosslinking between the carboxyl polymers and the diepoxide to form stable aqueous dispersed microgel particles. In a preferred aspect of the invention, the carboxyl latex polymer is a swollen latex polymer.

摘要翻译： 特别适用于基于聚合物粘合剂的罐涂层的水性保护涂料组合物包含二环氧化物交联的微粒凝胶颗粒。 微凝胶聚合物通过将羧基官能丙烯酸 - 环氧共聚物分散在水中并与羧基官能胶乳聚合物一起与低分子量二环氧化物一起分散，然后在羧基聚合物和二环氧化物之间进行核化和交联以形成稳定的水分散微凝胶 粒子。 在本发明的优选方面，羧基胶乳聚合物是溶胀的胶乳聚合物。

公开(公告)号：US5508325A

公开(公告)日：1996-04-16

申请号：US374885

申请日：1995-01-19

申请人： Gary P. Craun ,  David J. Telford ,  Henry J. DeGraaf

发明人： Gary P. Craun ,  David J. Telford ,  Henry J. DeGraaf

IPC分类号： C08L63/00 ,  C09D133/06 ,  C09D151/08 ,  C09D163/00 ,  C09D167/00

CPC分类号： C09D133/064 ,  C09D151/08 ,  C09D163/00 ,  C09D167/00 ,  C08L2205/18 ,  C08L63/00

摘要： An aqueous protective coating composition particularly useful for can coatings is based on a polymeric binder comprising epoxy crosslinked microgel particles. The microgel polymer is produced by dispersing into water a carbon grafted, carboxyl functional acrylic-epoxy copolymer, and combined with low molecular weight diepoxide, followed by coreaction and crosslinking between the carboxyl copolymer and diepoxide to form stable aqueous dispersed microgel particles.

摘要翻译： 特别适用于罐涂层的水性保护涂料组合物是基于包含环氧交联的微粒凝胶颗粒的聚合物粘合剂。 该微凝胶聚合物通过将碳分散在羧基官能的丙烯酸 - 环氧共聚物水中分散，并与低分子量二环氧化物结合，然后在羧基共聚物和二环氧化物之间进行核心作用和交联，形成稳定的水分散的微粒凝胶颗粒。