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11.
公开(公告)号:US20200017399A1
公开(公告)日:2020-01-16
申请号:US16512953
申请日:2019-07-16
Applicant: CORNING INCORPORATED
Inventor: Carol Ann Click , Indrajit Dutta , James Howard Edmonston , Michael S. Fischer , Qiang Fu , Ozgur Gulbiten , Jill Marie Hall , Mathieu Gerard Jacques Hubert , Dhananjay Joshi , Andrew Peter Kittleson , Rohit Rai , John Robert Saltzer, JR. , Charlene Marie Smith , Matthew Daniel Trosa , Matthew Artus Tuggle , James Clark Walck, JR. , Alana Marie Whittier , Zheming Zheng
Abstract: A glass-ceramic article having one or more crystalline phases; a residual glass phase; a compressive stress layer extending from a first surface to a depth of compression (DOC); a maximum central tension greater than 70 MPa; a stored tensile energy greater than 22 J/m2; a fracture toughness greater than 1.0 MPa√m; and a haze less than 0.2.
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公开(公告)号:US12281036B2
公开(公告)日:2025-04-22
申请号:US16924777
申请日:2020-07-09
Applicant: CORNING INCORPORATED
Inventor: I-Wen Chou , Carol Ann Click , Shuo Cui , James Howard Edmonston , Mathieu Gerard Jacques Hubert , Katherine Weber Kroemer
IPC: C03B32/02
Abstract: A method for forming glass ceramic articles includes heating a stack of glass sheets to a nucleation temperature to create a nucleated crystallizable stack of sheets; heating the nucleated crystallizable stack of glass sheets to a crystallization temperature; and maintaining the crystallization temperature for a predetermined period of time to produce the glass-ceramic articles. The stack of glass sheets has a mass index of less than or equal to 35.
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公开(公告)号:US12071364B2
公开(公告)日:2024-08-27
申请号:US18133106
申请日:2023-04-11
Applicant: CORNING INCORPORATED
Inventor: Carol Ann Click , James Howard Edmonston , Qiang Fu , Jill Marie Hall , Mathieu Gerard Jacques Hubert , Dhananjay Joshi , Andrew Peter Kittleson , Katherine Weber Kroemer , Galan Gregory Moore , Rohit Rai , John Richard Ridge , John Robert Saltzer, Jr. , Charlene Marie Smith , Erika Lynn Stapleton , Matthew Daniel Trosa , Ljerka Ukrainczyk , Shelby Kerin Wilson , Bin Yang , Zheming Zheng
CPC classification number: C03C10/0027 , C03C4/18 , H05K5/03 , C03C2204/00 , H05K5/0017
Abstract: A glass ceramic article including a lithium disilicate crystalline phase, a petalite crystalline phased, and a residual glass phase. The glass ceramic article has a warp (μm) 0.91×10(2-0.03t) of electromagnetic radiation wavelengths from 450 nm to 800 nm, where t is the thickness of the glass ceramic article in mm.
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14.
公开(公告)号:US20240150221A1
公开(公告)日:2024-05-09
申请号:US18383535
申请日:2023-10-25
Applicant: CORNING INCORPORATED
Inventor: Carol Ann Click , Mathieu Gerard Jacques Hubert
CPC classification number: C03C3/097 , C03B32/02 , C03C1/002 , C03C10/00 , C03C21/002 , H05K5/03 , C03C2204/00
Abstract: A cover substrate for an electronic device including greater than or equal to 1% by weight post-consumer recycled cover substrate. A method of forming the cover substrate including the steps of (i) determining the composition of the post-consumer recycled cover substrate, (ii) determining the maximum amount of the post-consumer recycled cover substrate that can be added to a predetermined batch without causing the resulting cover substrate to fall out of specification, and (iii) forming the cover substrate from the combined recycled post-consumer cover substrate and the predetermined batch. Additionally, a method that includes steps of (i) determining the composition of the post-consumer recycled cover substrate, (ii) determining a target weight percentage of the post-consumer recycled cover substrate in a cover substrate, and (iii) determining weight percentages of other oxides to be added to the target weight percentage for the resulting combination to produce the cover substrate with a desired composition.
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15.
公开(公告)号:US20230348319A1
公开(公告)日:2023-11-02
申请号:US18211702
申请日:2023-06-20
Applicant: CORNING INCORPORATED
Inventor: Carol Ann Click , Qiang Fu , Mathieu Gerard Jacques Hubert , Charlene Marie Smith , Alana Marie Whittier
CPC classification number: C03C10/0027 , C03C4/02 , C03C10/0036 , C03C21/002 , C03C21/005
Abstract: A glass-ceramic article comprises: a center-volume composition comprising (on an oxide basis): 55-75 mol % SiO2; 0.2-10 mol % Al2O3; 0-5 mol % B2O3; 15-30 mol % Li2O; 0-2 mol % Na2O; 0-2 mol % K2O; 0-5 mol % MgO; 0-2 mol % ZnO; 0.2-3.0 mol % P2O5; 0.1-10 mol % ZrO2; 0-4 mol % TiO2; and 0-1.0 mol % SnO2. Lithium disilicate and either β-spodumene or β-quartz are the two predominant crystalline phases (by weight) of the glass-ceramic article. The glass-ceramic article further comprises tetragonal ZrO2 as a crystalline phase. The composition of the glass-ceramic article from a primary surface into a thickness of the glass-ceramic article can comprise over 10 mol % Na2O (on an oxide basis), with the mole percentage of Na2O decreasing from the primary surface towards the center-volume. The glass-ceramic article exhibits a ring-on-ring load-to-failure of at least 120 kgf, when the thickness of the glass-ceramic article is 0.3 mm to 2.0 mm.
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公开(公告)号:US11649187B2
公开(公告)日:2023-05-16
申请号:US17237272
申请日:2021-04-22
Applicant: CORNING INCORPORATED
Inventor: Carol Ann Click , James Howard Edmonston , Qiang Fu , Jill Marie Hall , Mathieu Gerard Jacques Hubert , Dhananjay Joshi , Andrew Peter Kittleson , Katherine Weber Kroemer , Galan Gregory Moore , Rohit Rai , John Richard Ridge , John Robert Saltzer, Jr. , Charlene Marie Smith , Erika Lynn Stapleton , Matthew Daniel Trosa , Ljerka Ukrainczyk , Shelby Kerin Wilson , Bin Yang , Zheming Zheng
CPC classification number: C03C10/0027 , C03C4/18 , H05K5/03 , C03C2204/00 , H05K5/0017
Abstract: A glass ceramic article including a lithium disilicate crystalline phase, a petalite crystalline phased, and a residual glass phase. The glass ceramic article has a warp (μm) 0.91×10(2−0.03t) of electromagnetic radiation wavelengths from 450 nm to 800 nm, where t is the thickness of the glass ceramic article in mm.
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公开(公告)号:US20250145515A1
公开(公告)日:2025-05-08
申请号:US18928625
申请日:2024-10-28
Applicant: CORNING INCORPORATED
Inventor: Jaymin Amin , Carol Ann Click , Timothy Michael Gross , Kristy Lynn Smith , Jingshi Wu
Abstract: A glass comprising a coefficient of thermal expansion (CTE) of 70×10−7/° C. or less, a liquidus viscosity of at least 150 kP, and Li2O in an amount of 0.1 wt. % or less, wherein the glass is ion-exchangeable. A glass, comprising SiO2 in an amount of 64-73 wt. %, Al2O3 in an amount of 7-15 wt. %, B2O3 in an amount of 9-11 wt. %, Na2O in an amount of 6-9.5 wt. %, K2O in an amount of 0.5-3 wt. %, CaO in an amount of at least 0.05 wt. %, and Li2O in an amount of less than 0.1 wt. %, wherein a weight ratio of Na2O/Al2O3 is less than or equal to 0.9. A method of recycling glass, the method comprising heating a composition to form a melt, the composition comprising glass cullet in an amount of at least 60 wt. %, and raw materials in an amount of 40 wt. % or less.
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18.
公开(公告)号:US20250109059A1
公开(公告)日:2025-04-03
申请号:US18899279
申请日:2024-09-27
Applicant: CORNING INCORPORATED
Inventor: Carol Ann Click , Qiang Fu , Kayla Nicole Horton , Charlene Marie Smith , Ljerka Ukrainczyk , Alana Marie Whittier , Shelby Kerin Wilson
Abstract: A glass-ceramic includes greater than or equal to 55 wt % to less than or equal to 75 wt % SiO2; greater than or equal to 2 wt % to less than or equal to 10 wt % Al2O3; greater than or equal to 8 wt % to less than or equal to 15 wt % Li2O; greater than or equal to 2 wt % to less than or equal to 4 wt % P2O5; greater than or equal to 0.05 wt % and less than or equal to 4.0 wt % CaO; greater than or equal to 5 wt % to less than or equal to 15 wt % ZrO2; and a phase assemblage comprising a crystalline phase and a glass phase, wherein: a ratio of Li2O to Al2O3 is greater than 2 and less than or equal to 4; and a ratio of Li2O to ZrO2 is greater than or equal to 1.2 and less than or equal to 1.7.
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公开(公告)号:US11834363B2
公开(公告)日:2023-12-05
申请号:US16511171
申请日:2019-07-15
Applicant: CORNING INCORPORATED
Inventor: Carol Ann Click , Indrajit Dutta , Ozgur Gulbiten , Jill Marie Hall , Mathieu Gerard Jacques Hubert , Andrew Peter Kittleson , Rohit Rai , John Robert Saltzer, Jr. , Matthew Daniel Trosa , Zheming Zheng
IPC: C03B32/02
CPC classification number: C03B32/02
Abstract: A method for ceramming a glass article to a glass-ceramic includes placing a glass article into a heating apparatus, and heating the glass article to a first hold temperature at a first predetermined heating rate. The glass article is held at the first hold temperature for a first predetermined duration. The viscosity of the glass article is maintained within log viscosity ±1.0 poise during the first predetermined duration. The glass article is then heated from the first hold temperature to a second hold temperature at a second predetermined heating rate. The glass article is held at the second hold temperature for a second duration. A density of the glass article is monitored from the heating of the glass article from the first hold temperature through the second duration, and the second duration is ended when an absolute value of a density rate of change of the glass article is less than or equal to 0.10 (g/cm3)/min.
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公开(公告)号:US11724961B2
公开(公告)日:2023-08-15
申请号:US17358818
申请日:2021-06-25
Applicant: CORNING INCORPORATED
Inventor: Carol Ann Click , Qiang Fu , Mathieu Gerard Jacques Hubert , Charlene Marie Smith , Alana Marie Whittier
CPC classification number: C03C10/0027 , C03C4/02 , C03C10/0036 , C03C21/002 , C03C21/005
Abstract: A glass-ceramic article comprises: a center-volume composition comprising (on an oxide basis): 55-75 mol % SiO2; 0.2-10 mol % Al2O3; 0-5 mol % B2O3; 15-30 mol % Li2O; 0-2 mol % Na2O; 0-2 mol % K2O; 0-5 mol % MgO; 0-2 mol % ZnO; 0.2-3.0 mol % P2O5; 0.1-10 mol % ZrO2; 0-4 mol % TiO2; and 0-1.0 mol % SnO2. Lithium disilicate and either β-spodumene or β-quartz are the two predominant crystalline phases (by weight) of the glass-ceramic article. The glass-ceramic article further comprises tetragonal ZrO2 as a crystalline phase. The composition of the glass-ceramic article from a primary surface into a thickness of the glass-ceramic article can comprise over 10 mol % Na2O (on an oxide basis), with the mole percentage of Na2O decreasing from the primary surface towards the center-volume. The glass-ceramic article exhibits a ring-on-ring load-to-failure of at least 120 kgf, when the thickness of the glass-ceramic article is 0.3 mm to 2.0 mm.
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