公开(公告)号：US20170207446A1

公开(公告)日：2017-07-20

申请号：US15059852

申请日：2016-03-03

Applicant: KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Jeung Ku KANG ,  Jung Hyo PARK ,  Kyung Min CHOI ,  Dong Ki LEE ,  Byeong Cheul MOON ,  Sang Rim SHIN

IPC: H01M4/137 ,  G01N21/78 ,  H01M10/0525 ,  G01N21/33

CPC classification number: H01M4/5815 ,  G01N21/78 ,  H01M4/60 ,  H01M10/052 ,  H01M2004/021

Abstract: Provided is an electrode material for an energy storage device, which comprises a metal organic framework, wherein an element having an unshared electron pair is doped to the organic linker of the metal organic framework. The electrode material for an energy storage device comprises a metal organic framework in which an element having an unshared electron pair is doped to the organic linker. The non-shared electron pair of the element doped to the electrode material is bound to high-order polysulfide to prevent the polysulfide from being transferred to lithium metal, thereby providing a good effect upon cycle characteristics and thus improving the cycle characteristics of an energy storage device, such as a lithium-sulfur battery. As a result, the metal organic framework having nitrogen doped thereto improves the cycle characteristics of an energy storage device, such as a lithium-sulfur battery, as a cathode thereof.

公开(公告)号：US20160376716A1

公开(公告)日：2016-12-29

申请号：US14925431

申请日：2015-10-28

Applicant: Korea Advanced Institute of Science and Technology

Inventor： Jeung Ku KANG ,  Dong Ki LEE ,  Gyu Heon LEE ,  Yong-Hoon KIM ,  Ji Il CHOI

IPC: C25B11/04

CPC classification number: C25B11/0478 ,  C02F2305/10 ,  Y02E10/52 ,  Y02P20/134

Abstract: Disclosed is a method for improving solar energy conversion efficiency of a metal oxide semiconductor photocatalyst, which includes rapidly performing hydrogenation and nitrogenation of a metal oxide semiconductor material through an H2/N2 mixed gas plasma treatment in a single process at room temperature, so as to enhance photocatalytic energy conversion efficiency. Specifically, disclosed is a treatment technique in which a plasma ball formed by controlling a mixing ratio of hydrogen gas to nitrogen gas in a range of 1:1 to 1:3 contacts with a surface of a metal oxide material, such that a great amount of oxygen vacancy and nitrogen elements are introduced in the surface of the metal oxide material to improve electron-hole pairs transfer ability thereof and decrease a size of the band-gap. A catalyst including the metal oxide material directly converts the solar energy into a compound by photocatalytic hydrogen generation and CO2 conversion.

Abstract translation: 公开了一种提高金属氧化物半导体光催化剂的太阳能转换效率的方法，其包括在室温下通过H 2 / N 2混合气体等离子体处理在单一工艺中迅速进行金属氧化物半导体材料的氢化和氮化，从而 提高光催化能量转换效率。 具体地说，公开了一种处理技术，其中通过控制氢气与氮气的混合比在1：1至1：3的范围内形成的等离子体球与金属氧化物材料的表面接触，使得大量 的氧空位和氮元素引入金属氧化物材料的表面，以改善其电子 - 空穴对转移能力并减小带隙的尺寸。 包括金属氧化物材料的催化剂通过光催化氢生成和CO 2转化将太阳能直接转化为化合物。

公开(公告)号：US20160079005A1

公开(公告)日：2016-03-17

申请号：US14565052

申请日：2014-12-09

Applicant: KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Jeung Ku KANG ,  Gede Widia Pratama Adhyaksa ,  Dong Ki LEE ,  II Woo OCK

IPC: H01G9/20

CPC classification number: H01G9/2004 ,  H01G9/2022 ,  H01G9/2031 ,  H01G9/2059 ,  H01L51/0093 ,  Y02E10/542 ,  Y02E10/549

Abstract: Disclosed is a technique for fabricating a bio-photovoltaic cell which includes coupling graminoids extracted from natural grasses to a semiconductor electron acceptor, on which plasmonic silver nanoparticles are aligned, by using an organic ligand material. More particularly, disclosed is a technique for fabricating a new renewable energy generation device useable for fabrication of high efficiency bio-photovoltaic cells by improving a photo-electron generation rate of graminoids through a surface plasmon effect of silver nanoparticles and increasing an effective photo-electron amount transferred to the electron acceptor due to optimized bonding between a photo sensitizer and an electron acceptor

Abstract translation: 公开了一种用于制造生物光伏电池的技术，其包括通过使用有机配体材料将从天然草提取的graminids与其上等离子体银纳米粒子对准的半导体电子受体耦合。 更具体地，公开了一种用于制造可用于制造高效率生物光伏电池的新的可再生能源发生装置的技术，其通过银纳米颗粒的表面等离子体效应改善葛氨酸的光电子产生速率并增加有效的光电子 由于光敏剂和电子受体之间的优化结合，转移到电子受体的量

公开(公告)号：US20170014813A1

公开(公告)日：2017-01-19

申请号：US15194985

申请日：2016-06-28

Applicant: KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Jeung Ku KANG ,  Dong Ki LEE ,  Gyu Heon LEE ,  Yong-Hoon KIM ,  Ji Il CHOI

IPC: B01J27/24 ,  B01J23/42 ,  B01J37/02 ,  B01J35/02 ,  B01J37/08 ,  B01J37/34 ,  H01L31/18 ,  B01J35/00

CPC classification number: B01J27/24 ,  B01J21/063 ,  B01J23/755 ,  B01J35/0033 ,  B01J35/004 ,  B01J37/348 ,  B01J37/349

Abstract: The present invention discloses a method for improving solar energy conversion efficiency using metal oxide photocatalysts having an energy band of core-shell structure for ultraviolet (UV) ray and visible light absorption, comprising a first process of forming a nanoparticle thin film layer; a second process of preparing a core-shell metal oxide on metal oxide nanoparticles by a plasma reaction under a hydrogen and nitrogen gas atmosphere, and a third process of depositing a transition metal on surfaces of core-shell metal oxide nanoparticles to produce a photocatalyst for energy conversion. A great amount of oxygen vacancies is formed in a shell region by the core-shell metal oxide to achieve effects of improving transfer ability of electron-hole pairs excited by light, and extending a wavelength range of absorbable light to a visible light region by changing a band-gap structure.

Abstract translation: 本发明公开了一种使用金属氧化物光催化剂提高太阳能转换效率的方法，所述金属氧化物光催化剂具有用于紫外（UV）射线和可见光吸收的核 - 壳结构的能带，包括形成纳米颗粒薄膜层的第一工艺; 在氢气和氮气气氛下通过等离子体反应在金属氧化物纳米颗粒上制备核 - 壳金属氧化物的第二种方法，以及在核 - 壳金属氧化物纳米颗粒的表面上沉积过渡金属以产生光催化剂的第三种方法 能量转换。 通过核 - 壳金属氧化物在壳区域中形成大量的氧空位，以实现改善由光激发的电子 - 空穴对的转移能力的效果，并且通过改变可变光区域将可吸收光的波长范围扩展到可见光区域 带隙结构。