公开(公告)号：US07692045B2

公开(公告)日：2010-04-06

申请号：US11575914

申请日：2005-09-22

Applicant: Joaquim Henrique Teles ,  Beatrice Roessler ,  Thomas Genger ,  Andreas Glass ,  Dieter Baumann ,  Jan-Martin Loening

Inventor： Joaquim Henrique Teles ,  Beatrice Roessler ,  Thomas Genger ,  Andreas Glass ,  Dieter Baumann ,  Jan-Martin Loening

IPC: C07C45/27 ,  C07B41/06 ,  C01B21/22

CPC classification number: B01D53/73 ,  B01D53/14 ,  B01D2257/402 ,  C01B21/22 ,  C07C45/28 ,  C07C49/607 ,  Y02C20/10 ,  Y02P20/153 ,  Y02P20/582 ,  C07C49/395 ,  C07C49/413

Abstract: The present invention relates to a process for purifying a gas mixture comprising dinitrogen monoxide and to the use of a gas mixture purified in this way as an oxidant for olefins. In a further embodiment, the present invention also relates to a process for preparing ketones comprising the oxidation of an olefin with a gas mixture which has been purified in accordance with the invention and comprises dinitrogen monoxide.

Abstract translation: 本发明涉及一种用于纯化包含一氧化二氮的气体混合物的方法，以及使用以这种方式纯化的气体混合物作为烯烃的氧化剂。 在另一个实施方案中，本发明还涉及一种制备酮的方法，其包括用根据本发明纯化并包含一氧化二氮的气体混合物氧化烯烃。

公开(公告)号：US07754172B2

公开(公告)日：2010-07-13

申请号：US12094731

申请日：2006-11-21

Applicant: Joaquim Henrique Teles ,  Beatrice Roessler ,  Dieter Baumann

Inventor： Joaquim Henrique Teles ,  Beatrice Roessler ,  Dieter Baumann

IPC: B01D53/56 ,  C01B21/22

CPC classification number: C07C45/28 ,  B01D53/14 ,  B01D53/1493 ,  B01D2257/402 ,  C01B21/22 ,  C01P2006/80 ,  Y02C20/10 ,  Y02P20/153

Abstract: The present invention relates to a process for purifying a gas mixture G-0 comprising dinitrogen monoxide, at least comprising the absorption of the gas mixture G-0 in an organic solvent, subsequent desorption of a gas mixture G-1 from the laden organic solvent, absorption of the gas mixture G-1 in water and subsequent desorption of a gas mixture G-2 from the laden water, and also to the use of a purified gas mixture which comprises dinitrogen monoxide and is obtainable by such a process as an oxidizing agent for olefins.

Abstract translation: 本发明涉及一种纯化包含一氧化二氮的气体混合物G-0的方法，该方法至少包括在有机溶剂中吸收气体混合物G-0，随后将气体混合物G-1从含有机溶剂中解吸 ，将气体混合物G-1吸收在水中并随后从含水的气体中吸收气体混合物G-2，以及使用包含一氧化二氮的纯化气体混合物，并且可以通过氧化方法 烯烃试剂。

公开(公告)号：US20100018389A1

公开(公告)日：2010-01-28

申请号：US12518659

申请日：2007-12-07

Applicant: Dieter Baumann ,  Beatrice Roessler ,  Joaquim Henrique Teles

Inventor： Dieter Baumann ,  Beatrice Roessler ,  Joaquim Henrique Teles

IPC: B01D53/14

CPC classification number: C01B21/22 ,  B01D53/1406 ,  B01D53/1418 ,  B01D53/77 ,  B01D2257/402 ,  Y02C20/10 ,  Y02P20/153

Abstract: The present invention relates to a process for purifying a gas mixture G-0 comprising dinitrogen monoxide, at least comprising the contacting of the gas mixture G-0 with a solvent mixture (I) at least comprising 50% by weight of water based on the overall solvent mixture (1), the pH of the solvent mixture (I) being in the range from 3.5 to 8.0, the desorption of a gas mixture G-1 from a composition (A), the contacting of the gas mixture G-1 with a solvent mixture (11) at least comprising 50% by weight of water based on the overall solvent mixture (11), the pH of the solvent mixture (11) being in the range from 2.0 to 8.0, and the desorption of a gas mixture G-2 from a composition (B), the pH being based in each case on a measurement with a glass electrode, and to the use of gas mixtures obtainable by a process according to the invention as oxidizing agents for olefins.

Abstract translation: 本发明涉及一种纯化包含一氧化二氮的气体混合物G-0的方法，该方法至少包括气体混合物G-0与至少包含50重量％水的溶剂混合物（I）的接触，基于 总溶剂混合物（1）中，溶剂混合物（I）的pH在3.5至8.0的范围内，气体混合物G-1从组合物（A）中的解吸，气体混合物G-1 与溶剂混合物（11）的溶剂混合物（11）至少包含基于总溶剂混合物（11）的50重量％的水，溶剂混合物（11）的pH在2.0至8.0的范围内，并且气体的解吸 来自组合物（B）的混合物G-2，在每种情况下，使用玻璃电极进行测量，并且使用可通过根据本发明的方法获得的气体混合物作为烯烃的氧化剂。

公开(公告)号：US07495132B2

公开(公告)日：2009-02-24

申请号：US10587191

申请日：2005-01-28

Applicant: Christian Walsdorff ,  Thorsten Johann ,  Beatrice Roessler ,  Hartmut Hibst ,  Joaquim Henrique Teles ,  Sebastian Storck ,  Jens Klein

Inventor： Christian Walsdorff ,  Thorsten Johann ,  Beatrice Roessler ,  Hartmut Hibst ,  Joaquim Henrique Teles ,  Sebastian Storck ,  Jens Klein

IPC: C07C45/65 ,  B01J23/42

CPC classification number: C07C45/65 ,  B01J23/6445 ,  B01J23/6447 ,  B01J23/6522 ,  B01J23/681 ,  B01J23/8973 ,  B01J35/008 ,  B01J37/0201 ,  B01J37/0221 ,  B01J37/03 ,  C07C47/21 ,  C07C49/603

Abstract: The present invention relates to a catalytically active composition comprising as active component Pd and Bi and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba, or Pd, Rh and Bi and optionally an element selected from the group (a′) consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The present invention further provides a process for dehydrogenating hydrocarbons, preferably oxo-functionalized hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, using the catalytically active composition.

Abstract translation: 本发明涉及包含作为活性成分Pd和Bi的至少一种元素的催化活性组合物和选自由Rh，Au，Sb，V，Cr，W，Mn，Fe，Co，Ni组成的组（a）中的至少一种元素， Na，Cs和Ba或Pd，Rh和Bi以及任选的选自Au，Sb，V，Cr，W，Mn，Fe，Co，Ni，Pt，Cu，Ag， Na，Cs，Mg，Ca和Ba。 本发明还提供了一种使用催化活性组合物使烃优选氧化官能化烃如环戊酮，环己酮和异戊醛脱氢的方法。

公开(公告)号：US08449655B2

公开(公告)日：2013-05-28

申请号：US12518659

申请日：2007-12-07

Applicant: Dieter Baumann ,  Beatrice Roessler ,  Joaquim Henrique Teles

Inventor： Dieter Baumann ,  Beatrice Roessler ,  Joaquim Henrique Teles

IPC: B01D53/14

CPC classification number: C01B21/22 ,  B01D53/1406 ,  B01D53/1418 ,  B01D53/77 ,  B01D2257/402 ,  Y02C20/10 ,  Y02P20/153

Abstract: The present invention relates to a process for purifying a gas mixture G-0 comprising dinitrogen monoxide, at least comprising the contacting of the gas mixture G-0 with a solvent mixture (I) at least comprising 50% by weight of water based on the overall solvent mixture (I), the pH of the solvent mixture (I) being in the range from 3.5 to 8.0, the desorption of a gas mixture G-1 from a composition (A), the contacting of the gas mixture G-1 with a solvent mixture (II) at least comprising 50% by weight of water based on the overall solvent mixture (II), the pH of the solvent mixture (II) being in the range from 2.0 to 8.0, and the desorption of a gas mixture G-2 from a composition (B), the pH being based in each case on a measurement with a glass electrode, and to the use of gas mixtures obtainable by a process according to the invention as oxidizing agents for olefins.

Abstract translation: 本发明涉及一种纯化包含一氧化二氮的气体混合物G-0的方法，该方法至少包括气体混合物G-0与至少包含50重量％水的溶剂混合物（I）的接触，基于 总溶剂混合物（I），溶剂混合物（I）的pH范围为3.5-8.0，气体混合物G-1从组合物（A）中的解吸，气体混合物G-1 基于总溶剂混合物（II），溶剂混合物（II）至少包含50重量％的水，溶剂混合物（II）的pH在2.0至8.0的范围内，并且气体的解吸 来自组合物（B）的混合物G-2，在每种情况下，使用玻璃电极进行测量，并且使用可通过根据本发明的方法获得的气体混合物作为烯烃的氧化剂。