- 专利标题: Magnesium modified ultra-stable rare earth Y-type molecular sieve and preparation method therefor
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申请号: US14365432申请日: 2012-04-13
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公开(公告)号: US09840422B2公开(公告)日: 2017-12-12
- 发明人: Xionghou Gao , Haitao Zhang , Hongchang Duan , Chaowei Liu , Di Li , Xueli Li , Zhengguo Tan , Yunfeng Zheng , Xiaoliang Huang , Jinjun Cai , Chenxi Zhang
- 申请人: Xionghou Gao , Haitao Zhang , Hongchang Duan , Chaowei Liu , Di Li , Xueli Li , Zhengguo Tan , Yunfeng Zheng , Xiaoliang Huang , Jinjun Cai , Chenxi Zhang
- 申请人地址: CN Beijing
- 专利权人: PetroChina Company Limited
- 当前专利权人: PetroChina Company Limited
- 当前专利权人地址: CN Beijing
- 代理机构: Meunier Carlin & Curfman LLC
- 优先权: CN201110419914 20111215
- 国际申请: PCT/CN2012/000506 WO 20120413
- 国际公布: WO2013/086765 WO 20130620
- 主分类号: B01J29/06
- IPC分类号: B01J29/06 ; C01B39/24 ; B01J29/08 ; B01J29/80 ; B01J35/10 ; C10G11/05 ; B01J35/02 ; C01B39/02 ; B01J37/08 ; B01J37/30
摘要:
The present invention provides a magnesium-modified ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment, and finally to a magnesium modification. The molecular sieve comprises 0.2 to 5% by weight of magnesium oxide, 1 to 20% by weight of rare earth oxide, and not more than 1.2% by weight of sodium oxide, and has a crystallinity of 46 to 63%, and a lattice parameter of 2.454 nm to 2.471 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 μm and a D(v,0.9) of not more than 20 μm. Such a molecular sieve has both high stability and high selectivity for the target product, while cracking catalysts using the molecular sieve as an active component is characterized by a high heavy-oil-conversion capacity and a high yield of valuable target products.
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