- 专利标题: Ultra-stable rare earth Y-type molecular sieve and preparation method therefor
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申请号: US14365489申请日: 2012-04-13
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公开(公告)号: US09789475B2公开(公告)日: 2017-10-17
- 发明人: Xionghou Gao , Haitao Zhang , Zhengguo Tan , Di Li , Dong Ji , Hongchang Duan , Chenxi Zhang
- 申请人: Xionghou Gao , Haitao Zhang , Zhengguo Tan , Di Li , Dong Ji , Hongchang Duan , Chenxi Zhang
- 申请人地址: CN Beijing
- 专利权人: Petrochina Company Limited
- 当前专利权人: Petrochina Company Limited
- 当前专利权人地址: CN Beijing
- 代理机构: Meunier Carlin & Curfman LLC
- 优先权: CN201110420931 20111215
- 国际申请: PCT/CN2012/000509 WO 20120413
- 国际公布: WO2013/086768 WO 20130620
- 主分类号: B01J29/06
- IPC分类号: B01J29/06 ; C01B39/24 ; B01J29/08 ; C10G11/05 ; C01B39/02 ; B01J35/02 ; B01J37/30 ; B01J35/10
摘要:
The present invention provides an ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment. The molecular sieve comprises 1 to 20% by weight of rare earth oxide, not more than 1.2% by weight of sodium oxide, has a crystallinity of 51 to 69%, and a lattice parameter of 2.451 nm to 2.469 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 μm and a D(v,0.9) of not more than 20 μm. Cracking catalysts using the molecular sieve as an active component is characterized by a high heavy-oil-conversion capacity and a high yield of valuable target products.
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