发明授权
- 专利标题: Method for polymerizing cycloolefin polymer containing polar functional groups and electronic devices employing the polymerized cycloolefins
- 专利标题(中): 聚合包含极性官能团的环烯烃聚合物的方法和使用聚合环烯烃的电子器件
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申请号: US10502185申请日: 2003-12-03
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公开(公告)号: US07718744B2公开(公告)日: 2010-05-18
- 发明人: Sung-Cheol Yoon , Sung-Ho Chun , Won-Kook Kim , Tae-Sun Lim , Heon Kim , Jung-Min Lee
- 申请人: Sung-Cheol Yoon , Sung-Ho Chun , Won-Kook Kim , Tae-Sun Lim , Heon Kim , Jung-Min Lee
- 申请人地址: KR
- 专利权人: LG Chem, Ltd.
- 当前专利权人: LG Chem, Ltd.
- 当前专利权人地址: KR
- 代理机构: Cantor Colburn LLP
- 优先权: KR10-2002-0076925 20021205; KR10-2003-0086705 20031202
- 国际申请: PCT/KR03/02634 WO 20031203
- 国际公布: WO2004/050726 WO 20040617
- 主分类号: C08F4/80
- IPC分类号: C08F4/80 ; C08F10/00 ; C08F36/00 ; C08F38/00 ; C08F32/00 ; C08F210/00
摘要:
Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising: preparing a catalyst mixture including i) a precatalyst, containing a Group 10 transition metal having a ligand containing oxygen ions bonded to the metal; ii) a first cocatalyst which is an organic compound containing a Group 15 element; and iii) a second cocatalyst which is capable of providing an anion and weakly coordinating to the metal of the precatalyst; and subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, at a temperature of 80-200° C., the total amount of the organic solvent being 50-800% by weight based on the total weight of the monomer contained in the monomer solution, and the product yield of the polymer being 50% by weight or more based on the total weight of the monomer.
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