发明授权
- 专利标题: Process for transesterification of vegetable or animal oils using heterogeneous catalysts based on titanium, zirconium or antimony and aluminium
- 专利标题(中): 使用基于钛,锆或锑和铝的多相催化剂进行植物油或动物油酯交换的方法
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申请号: US10853725申请日: 2004-05-26
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公开(公告)号: US07592470B2公开(公告)日: 2009-09-22
- 发明人: Thierry Lacome , Gerard Hillion , Bruno Delfort , Renaud Revel , Serge Leporq , Gustave Acakpo
- 申请人: Thierry Lacome , Gerard Hillion , Bruno Delfort , Renaud Revel , Serge Leporq , Gustave Acakpo
- 申请人地址: FR Rùeil Malmaison Cedex
- 专利权人: Institut Francais du Petrole
- 当前专利权人: Institut Francais du Petrole
- 当前专利权人地址: FR Rùeil Malmaison Cedex
- 代理机构: Millen, White, Zelano, Branigan, P.C.
- 优先权: FR0306336 20030526; FR0306337 20030526; FR0306338 20030526
- 主分类号: C11C3/10
- IPC分类号: C11C3/10 ; C09F7/00 ; C07C67/02
摘要:
A novel process is described for producing esters of linear monocarboxylic acids containing 6 to 26 carbon atoms, by reacting vegetable or animal oils, neutral or otherwise, with monoalcohols containing 1 to 18 carbon atoms in the presence of a catalyst selected from: mixtures of titanium oxide and alumina having formula: (TiOx)y(Al2O3)1-y where x has the value 1.5 to 2.2 and y, representing the weight ratio of the two oxides, has a value of 0.005 to 0.995; mixtures of zirconium oxide and alumina having formula: (ZrOx)y(Al2O3)1-y where x has the value 1.5 to 2.2 and y has a value of 0.005 to 0.995; and mixtures of antimony oxide and alumina having formula: (SbOx)y(Al2O3)1-y where x has the value 1.2 to 2.6 and y has a value of 0.005 to 0.995, in order to directly produce, in one or more steps, an ester for use as a fuel and a pure glycerin.
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