Invention Grant
US07578987B2 Synthesis of SAPO-34 with essentially pure CHA framework 有权
用基本纯CHA框架合成SAPO-34

  • Patent Title: Synthesis of SAPO-34 with essentially pure CHA framework
  • Patent Title (中): 用基本纯CHA框架合成SAPO-34
  • Application No.: US11157102
    Application Date: 2005-06-20
  • Publication No.: US07578987B2
    Publication Date: 2009-08-25
  • Inventor: Stephen T. Wilson
  • Applicant: Stephen T. Wilson
  • Applicant Address: US IL Des Plaines
  • Assignee: UOP LLC
  • Current Assignee: UOP LLC
  • Current Assignee Address: US IL Des Plaines
  • Agent Arthur E Gooding
  • Main IPC: C01B39/54
  • IPC: C01B39/54 C01B37/06 C01B37/08
Synthesis of SAPO-34 with essentially pure CHA framework
Abstract:
A process for producing an ElAPO molecular sieve with essentially pure CHA framework having an average crystal size less than about 5 micrometers is disclosed. When El is silicon, the process allows for a broad range of silicon content, and produces a catalyst with a high selectivity for the conversion of methanol to olefins. The process includes making a crystalline metallo-aluminophosphate molecular sieve of the formula (ElxAlyPz)O2from a mixture comprising an aluminum source, a phosphorous source, water, an El source, a fluorine source and an organic template source wherein the molar ratio of the organic template source to phosphorous is less than about 0.5; crystallizing the molecular sieve at a temperature between 100 C and 250 C and calcining in air.
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