Invention Grant
US06908975B2 Method for preparing high 1,4-cis polybutadiene having controlled cold flow
有权
制备具有受控冷流的高1,4-顺式聚丁二烯的方法
- Patent Title: Method for preparing high 1,4-cis polybutadiene having controlled cold flow
- Patent Title (中): 制备具有受控冷流的高1,4-顺式聚丁二烯的方法
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Application No.: US10653542Application Date: 2003-09-02
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Publication No.: US06908975B2Publication Date: 2005-06-21
- Inventor: Young Chan Jang , Pil Sung Kim , Shin Han , Gwang Hoon Kwag , Seung Hwon Lee
- Applicant: Young Chan Jang , Pil Sung Kim , Shin Han , Gwang Hoon Kwag , Seung Hwon Lee
- Applicant Address: KR
- Assignee: KoreaKumho Petrochemical Co., Ltd.
- Current Assignee: KoreaKumho Petrochemical Co., Ltd.
- Current Assignee Address: KR
- Agency: Dilworth & Barrese LLP
- Priority: KR10-2002-0072934 20021122
- Main IPC: C08F36/06
- IPC: C08F36/06 ; C08F136/06

Abstract:
The present invention relates to a method for preparing a high 1,4-cis polybutadiene having a controlled cold flow and, more particularly, to a novel method for preparing a high 1,4-cis polybutadiene having a controlled cold flow that involves initiating polymerization of a 1,3-butadiene in the presence of a non-polar solvent using, as a polymerization catalyst, a complex prepared by mixing a neodymium compound with or without a conjugated diene compound, a halogenated organoaluminum compound or a halogenated organic compound, and an organoaluminum compound irrespective of the addition order of the catalyst; and adding an organoborane compound as a cold flow controller of 1,4-cis polybutadiene after a predetermined time of the polymerization. Accordingly, a high 1,4-cis polybutadiene having an efficiently controlled cold flow can be prepared without causing a significant increase in the Mooney viscosity (molecular weight), an odor (bad smell), and a reduction in 1,4-cis content and polymerization yield.
Public/Granted literature
- US20040102589A1 Method for preparing high 1, 4-CIS polybutadiene having controlled cold flow Public/Granted day:2004-05-27
Information query
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