发明授权
- 专利标题: Dehydrocyclization with an acidic multimetallic catalytic composite
- 专利标题(中): 用酸性多金属催化复合材料脱氢环化
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申请号: US721137申请日: 1976-09-07
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公开(公告)号: US4036903A公开(公告)日: 1977-07-19
- 发明人: George J. Antos
- 申请人: George J. Antos
- 申请人地址: IL Des Plaines
- 专利权人: UOP Inc.
- 当前专利权人: UOP Inc.
- 当前专利权人地址: IL Des Plaines
- 主分类号: B01J23/89
- IPC分类号: B01J23/89 ; C07C5/41 ; C10G35/09 ; C10G49/06 ; C07C3/04 ; B01J23/82 ; C10G27/08
摘要:
Dehydrocyclizable hydrocarbons are converted to aromatics by contacting them at dehydrocyclization conditions with an acidic multimetallic catalytic composite comprising a combination of catalytically effective amounts of a platinum group component, a bismuth component, a cobalt component, and a halogen component with a porous carrier material. The platinum group, bismuth, cobalt and halogen components are present in the multimetallic catalyst in amounts respectively, calculated on an elemental basis, corresponding to about 0.01 to about 2 wt. % platinum group metal, about 0.05 to about 5 wt. % cobalt, about 0.01 to about 5 wt. % bismuth, and about 0.1 to about 3.5 wt. % halogen. Moreover, the catalytically active sites induced by these metallic components are uniformly dispersed throughout the porous carrier material and these metallic components are present in the catalyst in carefully controlled oxidation states such that substantially all of the platinum group component is in the elemental metallic state, substantially all of the bismuth component is preferably in an oxidation state above that of the elemental metal, and substantially all of the catalytically available cobalt component is present in the elemental metallic state or in a state which is reducible to the elemental metallic state under dehydrocyclization conditions, or in a mixture of these states. A specific example of dehydrocyclization method disclosed herein is a method for converting a feed mixture of n-hexane and n-heptane to a product mixture of benzene and toluene which involves contacting the feed mixture and a hydrogen stream with the acidic multimetallic catalyst disclosed herein at dehydrocyclization conditions.
公开/授权文献
- US4797383A Catalyst 公开/授权日:1989-01-10
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