A steel sheet for hot stamping includes: a steel sheet having a predetermined chemical composition; and a plating layer provided on a surface of the steel sheet, the plating layer having an adhesion amount of 10 g/m2 to 90 g/m2 and a Ni content of 10 mass % to 25 mass %, and containing a remainder consisting of Zn and impurities. The steel sheet for hot stamping includes, in a surface layer region of the steel sheet, 80% or more by area % of grains having an average crystal orientation difference of 0.4° to 3.0° inside grains surrounded by grain boundaries having an average crystal orientation difference of 5° or more.