A micro-electro-mechanical device includes an ion exchange polymer coated onto a surface or within pores of a micro-electro-mechanical portion. The micro-electro-mechanical device may be an electrode, a sensor or a cantilever. The ion exchange polymer may comprise an additive, such as an inorganic particle or powder or a metal-organic framework compound. Gases may react with the ionomer and create voltage and/or current which can be measured. The incorporation of ion exchange polymer with a MEM to produce electrode can provide interesting chemical, mechanical and electrical properties, which may have promise in sensor application and some other applications. The ion exchange polymer may be either cation exchange polymer or anion exchange polymer. The ion exchange polymer can be chemically cross-linked, or reinforced by support material or additive.