New aluminum alloys having iron, vanadium, silicon and copper are disclosed. The new alloys may include from 3 to 12 wt. % Fe, from 0.1 to 3 wt. % V, from 0.1 to 3 wt. % Si, and from 1.0 to 6 wt. % Cu, the balance being aluminum and impurities. The new aluminum alloys may be produced via additive manufacturing techniques, which may facilitate rapid solidification of a molten pool of the aluminum alloy.