Invention Application
US20140349109A1 PRESSURE SENSITIVE ADHESIVES BASED ON CARBOXYLIC ACIDS AND EPOXIDES
审中-公开
基于羧酸和环氧化合物的压力敏感性粘合剂
- Patent Title: PRESSURE SENSITIVE ADHESIVES BASED ON CARBOXYLIC ACIDS AND EPOXIDES
- Patent Title (中): 基于羧酸和环氧化合物的压力敏感性粘合剂
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Application No.: US14363780Application Date: 2012-12-05
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Publication No.: US20140349109A1Publication Date: 2014-11-27
- Inventor: Kaichang Li , Anlong Li
- Applicant: State of Oregon acting by and through the State Board of Higher Education on behalf of Oregon , State University
- Applicant Address: US OR Corvallis
- Assignee: State of Oregon acting by and through the State Board of Higher Education of behalf of Oregon,State University
- Current Assignee: State of Oregon acting by and through the State Board of Higher Education of behalf of Oregon,State University
- Current Assignee Address: US OR Corvallis
- International Application: PCT/US2012/067961 WO 20121205
- Main IPC: C09J163/00
- IPC: C09J163/00 ; C09J7/02 ; B32B37/26 ; C09J163/08

Abstract:
A method for making a pressure sensitive adhesive comprising: (a) reacting (i) at least one dibasic acid or anhydride thereof with (ii) at least one epoxide having at least two epoxy groups, one diol or polyol, or one diamine at a stoichiometric molar excess of reactive carboxylic acid groups relative reactive epoxy groups, hydroxyl groups or amine groups to produce a thermoplastic prepolymer or oligomer capped with a carboxylic acid group at both prepolymer or oligomer chain ends, or a thermoplastic branched prepolymer or oligomer with at least two of the prepolymer or oligomer branches and chain ends capped with a carboxylic acid group; and (b) curing the resulting carboxylic acid-capped prepolymer or oligomer with at least one polyfunctional epoxy to produce a pressure sensitive adhesive, wherein the polyfunctional epoxy is not an epoxidized vegetable oil. A method for making a pressure sensitive adhesive comprising: (a) reacting at least one dibasic acid or anhydride thereof with at least one epoxide having at least two epoxy or oxirane groups at a stoichiometric molar excess of reactive epoxy or oxirane groups relative reactive carboxylic acid groups to produce a thermoplastic prepolymer or oligomer capped with an epoxy or an oxirane group at both prepolymer or oligomer chain ends, or a thermoplastic branched prepolymer or oligomer with at least two of the prepolymer or oligomer branches and chain ends capped with an epoxy or oxirane group; and (b) (i) curing the resulting epoxy-capped prepolymer or oligomer with at least one polybasic acid, or (ii) thermally curing the resulting epoxy-capped prepolymer or oligomer, to produce a pressure sensitive adhesive.
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