发明申请
US20070287845A1 Hydroxymethylfurfural Reduction Methods and Methods of Producing Furandimethanol
有权
羟甲基糠醛还原方法和生产呋喃二甲醇的方法
- 专利标题: Hydroxymethylfurfural Reduction Methods and Methods of Producing Furandimethanol
- 专利标题(中): 羟甲基糠醛还原方法和生产呋喃二甲醇的方法
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申请号: US11760634申请日: 2007-06-08
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公开(公告)号: US20070287845A1公开(公告)日: 2007-12-13
- 发明人: Michael Lilga , Richard Hallen , Todd Werpy , James White , Johnathan Holladay , John Frye , Alan Zacher
- 申请人: Michael Lilga , Richard Hallen , Todd Werpy , James White , Johnathan Holladay , John Frye , Alan Zacher
- 申请人地址: US WA Richland 99352
- 专利权人: BATTELLE MEMORIAL INSTITUTE
- 当前专利权人: BATTELLE MEMORIAL INSTITUTE
- 当前专利权人地址: US WA Richland 99352
- 主分类号: C07D307/02
- IPC分类号: C07D307/02
摘要:
A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250° C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30° C. A method of producing tetrahydrofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.
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