Techniques are provided for optimizing performance of a multi-link device (MLD). In one embodiment, a controller receives information about a filter response for a first multi-link device (MLD, determines, based on the information about the filter response, a filtering transitional region of the first MLD indicating a range of frequencies where there is energy leakage due to the first MLD device operating in a simultaneous transmission and reception (STR) mode, determines cost metrics for a plurality of channels by identifying a STR and non-STR (NSTR) ratio for each of the plurality of channels, and assigns, based on the filtering transitional region and the cost metrics, a first radio of an access point (AP) to one of the plurality of channels to enable the first MLD to operate in the STR mode when communicating with the first radio.