Aspects of the present disclosure describe systems, methods, and structures that provide organic light-emitting diodes having high luminous efficiency and low electrical dissipation. Embodiments in accordance with the present disclosure include a top electrode normally comprising a single film that includes a pair of metals and one metal compound, where the metals include a precious metal in combination with an alkaline earth metal or rare-earth metal and the metal compound is an alkali metal compound. As a result, such a top electrode has a work function that is better matched for efficient electron injection than magnesium-silver alloy-based transparent electrodes known in the prior art.