- 专利标题: Method for preparing aromatic hydrocarbons
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申请号: US16344375申请日: 2017-08-22
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公开(公告)号: US10927051B2公开(公告)日: 2021-02-23
- 发明人: Youming Ni , Wenliang Zhu , Zhongmin Liu , Zhiyang Chen , Yong Liu , Hongchao Liu , Xiangang Ma , Shiping Liu
- 申请人: Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- 申请人地址: CN Dalian
- 专利权人: Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- 当前专利权人: Dalian Institute of Chemical Physics, Chinese Academy of Sciences
- 当前专利权人地址: CN Dalian
- 代理机构: Edwin A. Sisson, Attorney at Law, LLC
- 代理商 Jeffrey J. Banyas
- 优先权: CN201610985085.2 20161024
- 国际申请: PCT/CN2017/098510 WO 20170822
- 国际公布: WO2018/076910 WO 20180503
- 主分类号: C07C1/22
- IPC分类号: C07C1/22 ; B01J29/40 ; C07C1/20
摘要:
Disclosed is a method for preparing aromatic hydrocarbons, particularly relates to the preparation of the aromatic hydrocarbons by passing methanol and carbon monoxide through a reactor loaded with an acidic ZSM-5 molecular sieve catalyst containing no metal additive under reaction conditions. Compared with the prior art, the method provided by the present invention can improve and stabilize the selectivity to aromatic hydrocarbons, particularly BTX, by adding carbon monoxide in methanol aromatization, and also prolongs the single-pass life of the catalyst. The performance of an inactivated catalyst is not significantly degraded after repeated regenerations. Furthermore, the catalyst preparation process omits the step of adding a metal additive, so that not only the process is simplified, but also costs are greatly reduced, and environmental protection is facilitated.
公开/授权文献
- US20190256440A1 METHOD FOR PREPARING AROMATIC HYDROCARBONS 公开/授权日:2019-08-22
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