The invention discloses an analysis method for identifying vitex chinensis mill honey and syrup adulterated vitex chinensis mill honey, and particularly relates to a method combining the ultra-high performance liquid chromatography-quadrupole-orbitrap high-resolution mass spectrum technology with metabonomics. The method comprises the steps that pretreatment is conducted on a true vitex chinensis mill honey sample and a syrup adulterated vitex chinensis mill honey sample through organic solvents respectively, and the ultra-high performance liquid chromatography-quadrupole-orbitrap high-resolution mass spectrum technology is used for achieving separation and determination of chemical components in the pretreated samples; then obtained UHPLC-MS original data of the true vitex chinensis mill honey sample and the syrup adulterated vitex chinensis mill honey sample is preprocessed; finally, the multivariate statistical analysis method is used for analyzing and distinguishing the true vitex chinensis mill honey from the syrup adulterated vitex chinensis mill honey. According to the method, metabolite information of the true vitex chinensis mill honey and the syrup adulterated vitex chinensis mill honey is comprehensively obtained, multivariate statistical analysis is used, the vitex chinensis mill honey and the syrup adulterated vitex chinensis mill honey are comprehensively analyzed, and detection of the syrup adulterated vitex chinensis mill honey is completed.