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发明公开
CN103172623A 含噻吩基吡唑啉酮衍生物及其聚合物薄膜的制备与应用 失效 - 权利终止

含噻吩基吡唑啉酮衍生物及其聚合物薄膜的制备与应用
摘要：
本发明属有机光致变色材料，涉及含噻吩基吡唑啉酮衍生物及其聚合物薄膜的制备与应用。含噻吩基吡唑啉酮衍生物为下述中任意一种：1-苯基-3-取代苯基/噻吩基/吡咯基/呋喃基/吡啶基/萘基-4-噻吩亚甲基-5-羟基吡唑啉酮缩苯基氨基脲/甲基氨基硫脲/乙基氨基硫脲/氨基硫脲或1-苯基-3-噻吩基-4-取代苯基亚甲基/噻吩亚甲基/吡咯亚甲基/呋喃亚甲基/吡啶亚甲基/萘亚甲基-5-羟基吡唑啉酮缩苯基氨基脲/甲基氨基硫脲/乙基氨基硫脲/氨基硫脲;聚合物为聚苯乙烯、聚甲基苯乙烯、聚乙烯、聚丙烯中任意一种。所述的含噻吩基吡唑啉酮衍生物及其聚合物薄膜可应用于信息存储、分子开关、防伪、光学镜片、智能窗户等领域。
摘要（英）：

The invention belongs to an organic photochromic material, and relates to preparations and applications of a thienyl group-containing pyrazolone derivative and its polymer film. The thienyl group-containing pyrazolone derivative is anyone of 1-phenyl-3-substituted-phenyl/thienyl/pyrryl/furyl/pyridyl/naphthyl-4-thienylmethylene-5-hydroxypyrazolone phenylsemicarbazone/methylthiosemicarbazide/ethylthiosemicarbazide/thiosemicarbazide or 1-phenyl-3-thienyl-4-subsituted-phenylmethylene/thienylmethylene/pyrrylmethyl/furylmethylene/pyridylmethylene/naphthylmethylene-5-hydroxypyrazolone phenylsemicarbazone/methylthiosemicarbazide/ethylthiosemicarbazide/thiosemicarbazide, and the polymer is anyone of polystyrene, polymethylstyrene, polyethylene and polypropylene. The thienyl group-containing pyrazolone derivative and its polymer film can be used in the information storage field, the molecular switch field, the false proof field, the optical eyeglass field, the intelligent window field and the like.

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