The invention provides an ecological fertilizer special for rice and an application process of the fertilizer, and belongs to the technical field of fertilizers. The ecological fertilizer special for rice comprises a basal-tillering fertilizer and a panicle-spikelet fertilizer. The application process comprises the following steps of: applying 45-55kg of basal-tillering fertilizer to each Mu of paddy field in three times from the seeding time to the tillering stage; and applying 15-25kg of panicle-spikelet fertilizer to each Mu of paddy field in the panicle differentiation stage. The ecological fertilizer provided by the invention is designed according to the growth characteristic and the fertilizing need characteristic of rice through adjusting the ratio of major elements N (nitrogen), P (phosphorus) and K (potassium) and adding chemicals such as rice growth specific microelements and an anti-nitrification inhibitor, the demands of major nutrient elements and microelements of rice in whole growth stage are met, and meanwhile, the purpose of increasing both yield and income is fulfilled by increasing the fertilizer efficiency and the fertilizer use ratio. The application process provided by the invention is designed according to two fertilizer-needing peak periods in the growth of rice; the application process is scientific and reasonable; and by using the application process, the fertilizer can be conveniently absorbed by rice, and meanwhile, the application cost is reduced.