The invention relates to an alcohol adsorption material and application and a using method thereof. The material is prepared by performing free radical polymerization reaction on a polymeric monomer under the action of a polymerization initiator, wherein the polymeric monomer consists of 60 to 80 volume percent of butyl acrylate monomer or methyl methacrylate monomer or a mixture of the monomers and 20 to 40 volume percent of hydroxyethyl acrylate monomer; and the addition amount of the initiator is 0.1 to 0.8 percent based on the weight of the polymeric monomer. The alcohol adsorption material can selectively adsorb alcohol in an alcohol aqueous solution at room temperature, and can be applied to the low-temperature extraction of the alcohol; continuous fermentation can be realized, and the work period of yeast is prolonged; the degree of wine can be reduced in short time; and in addition, the alcohol adsorption material is easy to prepare and low in cost.