The invention relates to a manufacturing method and a structure of a radio frequency identification label with surface engaging elements. The manufacturing method comprises steps of providing a membrane foundation plate of which an upper surface is formed with an antenna, a first connection pad and a second connecting pad, wherein the first connection pad defines a first surface engaging element disposing area, a first exposed area and a first anti-diffusion layer disposing area disposed between the first surface engaging element disposing area and the first exposed area; forming a first anti-diffusion layer in the first anti-diffusion layer disposing area; forming a first solder in the first surface engaging element disposing area, wherein the first solder is limited in the first surfaceengaging element disposing area by the first anti-diffusion layer so as to prevent the first solder being diffused into the first exposed area; and disposing a surface engaging element on the membrane foundation plate, wherein a first electrode of the surface engaging element is disposed in the first surface engaging element disposing area and is electrically connected to the first connection padby means of the first solder.