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1.发明申请Process for coating a surface of a substrate made of nonmetallic material with a metal layer 有权用金属层涂覆由非金属材料制成的基材的表面的方法公开(公告)号：US20110256413A1
公开(公告)日：2011-10-20
申请号：US13089740
申请日：2011-04-19
申请人： Sebastien ROUSSEL , Frida GILBERT
发明人： Sebastien ROUSSEL , Frida GILBERT
CPC分类号： C23C18/1886 , C23C18/1639 , C23C18/1653 , C23C18/1658 , C23C18/1855 , C23C18/1896 , C23C18/2013 , C23C18/2073 , C23C18/22 , C23C18/38 , C23C18/40 , C23C28/023 , C25D5/56 , C25D9/02 , Y10T428/31678
摘要： A process for coating a surface of a substrate made of nonmetallic material with a metal layer consisting of providing a substrate made of nonmetallic material; subjecting a surface of said substrate to a treatment for increasing the specific surface area thereof; subjecting the resulting surface to an oxidizing treatment; contacting the resulting substrate with a solution containing an ion of a metal from groups IB and VIII of the Periodic Table; obtaining a substrate comprising ions of a metal that are chemically attached to the nonmetallic material constituting the substrate on at least one of its surfaces; subjecting the ions to a reducing treatment to obtain a substrate comprising atoms of a metal that are chemically attached to the nonmetallic material constituting the substrate on a part of at least one of its surfaces; and contacting the resulting surface with a solution containing ions of a metal.
摘要翻译： 一种用由非金属材料制成的基材的表面涂覆金属层的方法，所述金属层由提供由非金属材料制成的基材组成; 对所述基板的表面进行处理以增加其比表面积; 对所得表面进行氧化处理; 使所得底物与含有元素周期表IB和VIII族金属离子的溶液接触; 获得包含在其至少一个表面上化学连接到构成所述衬底的非金属材料的金属离子的衬底; 对所述离子进行还原处理以获得包含化学连接到构成所述基板的非金属材料的至少一个表面的一部分上的金属原子的基板; 并使所得表面与含有金属离子的溶液接触。
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2.发明授权Coating method by electrocatalyzed chemical grafting of a surface of a substrate with a polymeric layer 有权用聚合物层通过电催化化学接枝基材表面的涂布方法公开(公告)号：US09534309B2
公开(公告)日：2017-01-03
申请号：US13996614
申请日：2011-12-21
CPC分类号： C25D9/02 , C08J7/16 , C09D5/4411 , C25D13/04
摘要： The present invention relates to a coating method by electrocatalyzed chemical grafting of a surface of a substrate with a polymeric layer characterized in that it comprises the following steps: a. a substrate is provided, b. a bath containing at least one polymerizable monomer via a radical route, at least one cleavable aryl salt, at least one reducing agent and at least one solvent is provided, in which a potential difference is applied, c. said substrate is immersed in said bath, d. a grafted polymer is obtained on the surface of said substrate. The invention also relates to a substrate obtained according to the coating method by electrocatalyzed chemical grafting, the surface of which is coated with a polymeric layer.
摘要翻译： 本发明还涉及根据涂覆方法通过电催化化学接枝获得的基材，其表面涂覆有聚合物层。
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3.发明授权Process for coating a surface of a substrate made of nonmetallic material with a metal layer 有权用金属层涂覆由非金属材料制成的基材的表面的方法公开(公告)号：US09249512B2
公开(公告)日：2016-02-02
申请号：US14582228
申请日：2014-12-24
申请人： PEGASTECH
发明人： Sebastien Roussel , Frida Gilbert
IPC分类号： C23C18/18 , C23C18/16 , C23C18/20 , C23C18/22 , C23C18/38 , C25D5/56 , C23C18/40 , C23C28/02 , C25D9/02
CPC分类号： C23C18/1886 , C23C18/1639 , C23C18/1653 , C23C18/1658 , C23C18/1855 , C23C18/1896 , C23C18/2013 , C23C18/2073 , C23C18/22 , C23C18/38 , C23C18/40 , C23C28/023 , C25D5/56 , C25D9/02 , Y10T428/31678
摘要： The present invention relates to a process for coating a surface of a substrate made of nonmetallic material with a metal layer consisting of providing a substrate made of nonmetallic material; subjecting a surface of said substrate to a treatment for increasing the specific surface area thereof; subjecting the resulting surface to an oxidizing treatment; contacting the resulting substrate with a solution containing an ion of a metal from groups IB and VIII of the Periodic Table; obtaining a substrate comprising ions of a metal that are chemically attached to the nonmetallic material constituting the substrate on at least one of its surfaces; subjecting the ions to a reducing treatment to obtain a substrate comprising atoms of a metal that are chemically attached to the nonmetallic material constituting the substrate on a part of at least one of its surfaces; and contacting the resulting surface with a solution containing ions of a metal.
摘要翻译： 本发明涉及由非金属材料制成的基材的表面涂覆金属层的方法，所述金属层由提供由非金属材料制成的基材组成; 对所述基板的表面进行处理以增加其比表面积; 对所得表面进行氧化处理; 使所得底物与含有元素周期表IB和VIII族金属离子的溶液接触; 获得包含在其至少一个表面上化学连接到构成所述衬底的非金属材料的金属离子的衬底; 对所述离子进行还原处理以获得包含化学连接到构成所述基板的非金属材料的至少一个表面的一部分上的金属原子的基板; 并使所得表面与含有金属离子的溶液接触。
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4.发明授权Process for coating a surface of a substrate made of nonmetallic material with a metal layer 有权用金属层涂覆由非金属材料制成的基材的表面的方法公开(公告)号：US08962086B2
公开(公告)日：2015-02-24
申请号：US13089740
申请日：2011-04-19
申请人： Sebastien Roussel , Frida Gilbert
发明人： Sebastien Roussel , Frida Gilbert
CPC分类号： C23C18/1886 , C23C18/1639 , C23C18/1653 , C23C18/1658 , C23C18/1855 , C23C18/1896 , C23C18/2013 , C23C18/2073 , C23C18/22 , C23C18/38 , C23C18/40 , C23C28/023 , C25D5/56 , C25D9/02 , Y10T428/31678
摘要： A process for coating a surface of a substrate made of nonmetallic material with a metal layer consisting of providing a substrate made of nonmetallic material; subjecting a surface of said substrate to a treatment for increasing the specific surface area thereof; subjecting the resulting surface to an oxidizing treatment; contacting the resulting substrate with a solution containing an ion of a metal from groups IB and VIII of the Periodic Table; obtaining a substrate comprising ions of a metal that are chemically attached to the nonmetallic material constituting the substrate on at least one of its surfaces; subjecting the ions to a reducing treatment to obtain a substrate comprising atoms of a metal that are chemically attached to the nonmetallic material constituting the substrate on a part of at least one of its surfaces; and contacting the resulting surface with a solution containing ions of a metal.
摘要翻译： 一种用由非金属材料制成的基材的表面涂覆金属层的方法，所述金属层由提供由非金属材料制成的基材组成; 对所述基板的表面进行处理以增加其比表面积; 对所得表面进行氧化处理; 使所得底物与含有元素周期表IB和VIII族金属离子的溶液接触; 获得包含在其至少一个表面上化学连接到构成所述衬底的非金属材料的金属离子的衬底; 对所述离子进行还原处理以获得包含化学连接到构成所述基板的非金属材料的至少一个表面的一部分上的金属原子的基板; 并使所得表面与含有金属离子的溶液接触。
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5.发明申请COATING METHOD BY ELECTROCATALYZED CHEMICAL GRAFTING OF A SURFACE OF A SUBSTRATE WITH A POLYMERIC LAYER 有权通过电化学化学处理具有聚合物层的基材表面的涂覆方法公开(公告)号：US20140001048A1
公开(公告)日：2014-01-02
申请号：US13996614
申请日：2011-12-21
IPC分类号： C25D9/02
CPC分类号： C25D9/02 , C08J7/16 , C09D5/4411 , C25D13/04
摘要： The present invention relates to a coating method by electrocatalyzed chemical grafting of a surface of a substrate with a polymeric layer characterized in that it comprises the following steps: a. a substrate is provided, b. a bath containing at least one polymerizable monomer via a radical route, at least one cleavable aryl salt, at least one reducing agent and at least one solvent is provided, in which a potential difference is applied, c. said substrate is immersed in said bath, d. a grafted polymer is obtained on the surface of said substrate. The invention also relates to a substrate obtained according to the coating method by electrocatalyzed chemical grafting, the surface of which is coated with a polymeric layer.
摘要翻译： 本发明涉及一种通过电催化化学接枝具有聚合物层的基材的表面的涂布方法，其特征在于其包括以下步骤：a。 提供基板，b。 提供通过自由基途径含有至少一种可聚合单体的浴，至少一种可裂解的芳基盐，至少一种还原剂和至少一种溶剂，其中施加电位差。 所述衬底浸入所述浴中，d。 在所述基材的表面上获得接枝聚合物。 本发明还涉及根据涂覆方法通过电催化化学接枝获得的基材，其表面涂覆有聚合物层。
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