-
公开(公告)号：US20100069664A1
公开(公告)日：2010-03-18
申请号：US12620981
申请日：2009-11-18
Applicant: Miyoshi Yamashita , Takehiko Fukumoto
Inventor： Miyoshi Yamashita , Takehiko Fukumoto
CPC classification number: C07C41/48 , C07C29/10 , C07C41/50 , C07C67/08 , C07C69/007 , C07C69/145 , C07C33/02 , C07C43/30
Abstract: Provided is a method for preparing (E3,Z5)-3,5-alkadienyl acetate and (E3,Z5)-3,5-dodecadienyl acetate which is a sex pheromone of Brazilian apple leafminer. Specifically, provided is a method for preparing (E3,Z5)-3,5-alkadienyl acetate, comprising steps of hydrolyzing 5,5-diethoxy-(Z3)-3-pentenyl methoxymethyl ether in the presence of an acid to obtain 4-formyl-(E3)-butenyl methoxymethyl ether; reacting the 4-formyl-(E3)-butenyl methoxymethyl ether with alkylidene triphenylphosphorane in accordance with the Wittig reaction to obtain (E3,Z5)-3,5-alkadienyl methoxymethyl ether; and obtaining (E3,Z5)-3,5-alkadienyl acetate using the (E3,Z5)-3,5-alkadienyl methoxymethyl ether as a starting substance.
Abstract translation: 提供一种制备（E3，Z5）-3,5-链二烯酸乙酸酯和（E3，Z5）-3,5-十二烷基乙酸酯的方法，其是巴西苹果叶片的性信息素。 具体地说，提供了制备（E3，Z5）-3,5-链二烯基乙酸酯的方法，包括在酸存在下水解5,5-二乙氧基 - （Z 3）-3-戊烯基甲基甲基醚的步骤，得到4- 甲酰基 - （E3） - 丁烯基甲氧基甲基醚; 根据Wittig反应使4-甲酰基 - （E3） - 丁烯基甲氧基甲基醚与亚烷基三苯基正膦反应，得到（E3，Z5）-3,5-二甲氧基甲基醚; 并使用（E3，Z5）-3,5-链二烯基甲氧基甲基醚作为起始物质获得（E3，Z5）-3,5-链二烯酸乙酯。
-
2.发明授权5,5-Diethoxy-(Z3)-3-Pentenyl Methoxymethyl Ether and Preparation Method Thereof 有权5,5-二乙氧基 - （Z 3）-3-戊烯基甲氧基甲基醚及其制备方法
公开(公告)号：US07834220B2
公开(公告)日：2010-11-16
申请号：US12620981
申请日：2009-11-18
Applicant: Miyoshi Yamashita , Takehiko Fukumoto
Inventor： Miyoshi Yamashita , Takehiko Fukumoto
IPC: C07C43/30
CPC classification number: C07C41/48 , C07C29/10 , C07C41/50 , C07C67/08 , C07C69/007 , C07C69/145 , C07C33/02 , C07C43/30
Abstract: Provided is a method for preparing (E3,Z5)-3,5-alkadienyl acetate and (E3,Z5)-3,5-dodecadienyl acetate which is a sex pheromone of Brazilian apple leafminer. Specifically, provided is a method for preparing (E3,Z5)-3,5-alkadienyl acetate, comprising steps of hydrolyzing 5,5-diethoxy-(Z3)-3-pentenyl methoxymethyl ether in the presence of an acid to obtain 4-formyl-(E3)-butenyl methoxymethyl ether; reacting the 4-formyl-(E3)-butenyl methoxymethyl ether with alkylidene triphenylphosphorane in accordance with the Wittig reaction to obtain (E3,Z5)-3,5-alkadienyl methoxymethyl ether; and obtaining (E3,Z5)-3,5-alkadienyl acetate using the (E3,Z5)-3,5-alkadienyl methoxymethyl ether as a starting substance.
Abstract translation: 提供一种制备（E3，Z5）-3,5-链二烯酸乙酸酯和（E3，Z5）-3,5-十二烷基乙酸酯的方法，其是巴西苹果叶片的性信息素。 具体地说，提供了制备（E3，Z5）-3,5-链二烯基乙酸酯的方法，包括在酸存在下水解5,5-二乙氧基 - （Z 3）-3-戊烯基甲基甲基醚的步骤，得到4- 甲酰基 - （E3） - 丁烯基甲氧基甲基醚; 根据Wittig反应使4-甲酰基 - （E3） - 丁烯基甲氧基甲基醚与亚烷基三苯基正膦反应，得到（E3，Z5）-3,5-二甲氧基甲基醚; 并使用（E3，Z5）-3,5-链二烯基甲氧基甲基醚作为起始物质获得（E3，Z5）-3,5-链二烯酸乙酯。
-
公开(公告)号：US07638647B2
公开(公告)日：2009-12-29
申请号：US12323823
申请日：2008-11-26
Applicant: Miyoshi Yamashita , Takehiko Fukumoto
Inventor： Miyoshi Yamashita , Takehiko Fukumoto
IPC: C07C67/02
CPC classification number: C07C41/48 , C07C29/10 , C07C41/50 , C07C67/08 , C07C69/007 , C07C69/145 , C07C33/02 , C07C43/30
Abstract: Provided is a method for preparing (E3,Z5)-3,5-alkadienyl acetate and (E3,Z5)-3,5-dodecadienyl acetate which is a sex pheromone of Brazilian apple leafminer. Specifically, provided is a method for preparing (E3,Z5)-3,5-alkadienyl acetate, comprising steps of hydrolyzing 5,5-diethoxy-(Z3)-3-pentenyl methoxymethyl ether in the presence of an acid to obtain 4-formyl-(E3)-butenyl methoxymethyl ether; reacting the 4-formyl-(E3)-butenyl methoxymethyl ether with alkylidene triphenylphosphorane in accordance with the Wittig reaction to obtain (E3,Z5)-3,5-alkadienyl methoxymethyl ether; and obtaining (E3,Z5)-3,5-alkadienyl acetate using the (E3,Z5)-3,5-alkadienyl methoxymethyl ether as a starting substance.
Abstract translation: 提供一种制备（E3，Z5）-3,5-链二烯酸乙酸酯和（E3，Z5）-3,5-十二烷基乙酸酯的方法，其是巴西苹果叶片的性信息素。 具体地说，提供了制备（E3，Z5）-3,5-链二烯基乙酸酯的方法，包括在酸存在下水解5,5-二乙氧基 - （Z 3）-3-戊烯基甲基甲基醚的步骤，得到4- 甲酰基 - （E3） - 丁烯基甲氧基甲基醚; 根据Wittig反应使4-甲酰基 - （E3） - 丁烯基甲氧基甲基醚与亚烷基三苯基正膦反应，得到（E3，Z5）-3,5-二甲氧基甲基醚; 并使用（E3，Z5）-3,5-链二烯基甲氧基甲基醚作为起始物质获得（E3，Z5）-3,5-链二烯酸乙酯。
-
公开(公告)号：US20090143617A1
公开(公告)日：2009-06-04
申请号：US12323823
申请日：2008-11-26
Applicant: MIYOSHI YAMASHITA , Takehiko Fukumoto
Inventor： MIYOSHI YAMASHITA , Takehiko Fukumoto
IPC: C07C57/18
CPC classification number: C07C41/48 , C07C29/10 , C07C41/50 , C07C67/08 , C07C69/007 , C07C69/145 , C07C33/02 , C07C43/30
Abstract: Provided is a method for preparing (E3,Z5)-3,5-alkadienyl acetate and (E3,Z5)-3,5-dodecadienyl acetate which is a sex pheromone of Brazilian apple leafminer. Specifically, provided is a method for preparing (E3,Z5)-3,5-alkadienyl acetate, comprising steps of hydrolyzing 5,5-diethoxy-(Z3)-3-pentenyl methoxymethyl ether in the presence of an acid to obtain 4-formyl-(E3)-butenyl methoxymethyl ether; reacting the 4-formyl-(E3)-butenyl methoxymethyl ether with alkylidene triphenylphosphorane in accordance with the Wittig reaction to obtain (E3,Z5)-3,5-alkadienyl methoxymethyl ether; and obtaining (E3,Z5)-3,5-alkadienyl acetate using the (E3,Z5)-3,5-alkadienyl methoxymethyl ether as a starting substance.
Abstract translation: 提供一种制备（E3，Z5）-3,5-链二烯酸乙酸酯和（E3，Z5）-3,5-十二烷基乙酸酯的方法，其是巴西苹果叶片的性信息素。 具体地说，提供了制备（E3，Z5）-3,5-链二烯基乙酸酯的方法，包括在酸存在下水解5,5-二乙氧基 - （Z 3）-3-戊烯基甲基甲基醚的步骤，得到4- 甲酰基 - （E3） - 丁烯基甲氧基甲基醚; 根据Wittig反应使4-甲酰基 - （E3） - 丁烯基甲氧基甲基醚与亚烷基三苯基正膦反应，得到（E3，Z5）-3,5-二甲氧基甲基醚; 并使用（E3，Z5）-3,5-链二烯基甲氧基甲基醚作为起始物质获得（E3，Z5）-3,5-链二烯酸乙酯。
-
5.发明授权Sustained release pheromone preparation targeting insect pest having carboxylic acid as pheromone substance 有权以具有羧酸为信息素物质的昆虫害虫的缓释信息素制剂
公开(公告)号：US09545102B2
公开(公告)日：2017-01-17
申请号：US13325838
申请日：2011-12-14
Applicant: Tatsuya Fujii , Tatsuya Hojo , Naoki Ishibashi , Ryuichi Saguchi , Takehiko Fukumoto
Inventor： Tatsuya Fujii , Tatsuya Hojo , Naoki Ishibashi , Ryuichi Saguchi , Takehiko Fukumoto
Abstract: Targeting an insect pest having a carboxylic acid compound as a pheromone substance, provided is a sustained release pheromone preparation enabling a high amount of pheromone to be released during the control period. More specifically, provided is a sustained release pheromone preparation, comprising: a carboxylic acid compound to be released, and an ethylene-vinyl acetate copolymer membrane through which the carboxylic acid compound can permeate, wherein the preparation is targeted for an insect pest having the carboxylic acid compound as a pheromone substance.
Abstract translation: 提供了具有羧酸化合物作为信息素物质的害虫，其是提供在控制期间能够释放大量信息素的缓释信息素制剂。 更具体地，提供了一种缓释信息素制剂，其包含：待释放的羧酸化合物和羧酸化合物可以渗透的乙烯 - 乙酸乙烯酯共聚物膜，其中所述制剂靶向具有羧酸的害虫 酸化合物作为信息素物质。
-
6.发明申请
公开(公告)号：US20050209344A1
公开(公告)日：2005-09-22
申请号：US11063900
申请日：2005-02-23
Applicant: Sadahiro Tatsuki , Mamoru Terayama , Yasutoshi Tanaka , Takehiko Fukumoto
Inventor： Sadahiro Tatsuki , Mamoru Terayama , Yasutoshi Tanaka , Takehiko Fukumoto
CPC classification number: A01N35/02
Abstract: Provided are a behavior-disrupting agent of Argentine ants for controlling them or suppressing their reproduction is a safer and more effective manner, and the behavior-disrupting method of them. More specifically, a behavior-disrupting agent of Argentine ants comprising Z-9-hexadecenal, and a behavior-disrupting method of Argentine ants comprising a step of using the behavior-disrupting agent are provided based on the finding that the behavior of Argentine ants is disrupted by emission of Z-9-hexadecenal, which is a trail pheromone, into the atmosphere.
Abstract translation: 阿根廷蚂蚁的行为破坏剂是控制它们或抑制其繁殖是一种更安全和更有效的方式，以及它们的行为破坏方法。 更具体地，基于以下发现提供了包含Z-9-十六烯醛的阿根廷蚂蚁的行为破坏剂和包含使用行为破坏剂的步骤的阿根廷蚂蚁的行为破坏性方法，其发现：阿根廷蚂蚁的行为为 通过尾气信息素的Z-9-十六烯醛的排放而破坏了大气。
-
公开(公告)号：US06562331B1
公开(公告)日：2003-05-13
申请号：US09635905
申请日：2000-08-10
Applicant: Tatsuya Ito , Takehiko Fukumoto , Kinya Ogawa , Fumiaki Mochizuki
Inventor： Tatsuya Ito , Takehiko Fukumoto , Kinya Ogawa , Fumiaki Mochizuki
IPC: A01N2500
Abstract: A mating disruption method for the control of insect pests comprises releasing a sex pheromone in a field wherein an adsorption of the sex pheromone to a soil in the field is decreased.
Abstract translation: 用于控制害虫的交配破坏方法包括在场中的性信息素吸附到土壤中的场中释放性信息素。
-
8.发明授权1-halo-cis-3-tetradecenes and processes for the preparation of cis-olefin compounds by using same 失效1-卤代 - 顺式-3-十四碳烯和通过使用它们制备顺式烯烃化合物的方法
公开(公告)号：US5463149A
公开(公告)日：1995-10-31
申请号：US274139
申请日：1994-07-12
Applicant: Takehiko Fukumoto , Daisuke Iwai , Shigeo Okano , Hiroshi Suzuki , Mitsuyoshi Oshima
Inventor： Takehiko Fukumoto , Daisuke Iwai , Shigeo Okano , Hiroshi Suzuki , Mitsuyoshi Oshima
IPC: A01N27/00 , C07C1/32 , C07C11/02 , C07C17/16 , C07C21/04 , C07C21/14 , C07C21/17 , C07F1/02 , C07F3/02 , C07C19/08
Abstract: Disclosed are compounds suitable for use as raw materials which enable cis-olefin compounds useful as physiologically active substances such as the sex pheromones of various insects, or as intermediates for the synthesis thereof to be prepared on an industrial scale at a reasonable cost, and processes for the preparation of cis-olefin compounds by using the same. For this purpose, novel compounds (i.e., 1-halo-cis-3-tetradecenes) of the general formula (I)CH.sub.3 (CH.sub.2).sub.9 CH.dbd.CH(CH.sub.2).sub.2 X (I)wherein X is a halogen atom, are used as raw materials for the preparation of cis-olefin compounds.
Abstract translation: 公开了适合用作原料的化合物，其使得可用作诸如各种昆虫的性信息素的生理活性物质的顺式烯烃化合物或其合成成本的工业规模的合成中间体，以及方法 用于通过使用它们制备顺式烯烃化合物。 为此，将通式（I）CH（CH 2）9 CH = CH（CH 2）2 X（I）的新化合物（即1-卤代 - 顺式-3-十四碳烯）其中X为卤素原子用作 用于制备顺式烯烃化合物的原料。
-
公开(公告)号：US08900611B2
公开(公告)日：2014-12-02
申请号：US11226588
申请日：2005-09-14
Applicant: Tatsuya Hojo , Kinya Ogawa , Noboru Aiba , Takehiko Fukumoto
Inventor： Tatsuya Hojo , Kinya Ogawa , Noboru Aiba , Takehiko Fukumoto
CPC classification number: A01N25/18 , A01N37/02 , A01N35/02 , A01N31/02 , A01N2300/00
Abstract: Provided are a sustained releaser of sex pheromone substances and a method for controlling insect pest by using the releaser, each enabling to control the simultaneous release of a mixture of sex pheromone substances having different chemical structures of one insect pest or a mixture of sex pheromone substances of insect pests, and each enabling to release the sex pheromone substances at a fixed rate or greater during the infestation period or periods of the respective insect pest or pests. More specifically, provided is a sustained releaser of sex pheromone substances comprising one or more first sex pheromone substances selected from linear aliphatic aldehyde having 10 to 18 carbon atoms, one or more second sex pheromone substances selected from aldehyde-free aliphatic derivatives having 7 to 20 carbon atoms, and first and second chambers each made of polymer material, wherein all of the first sex pheromone substances or all of the first sex pheromone substances and some of the second sex pheromone substances are enclosed in the first chamber and the remainder of the sex pheromone substances is enclosed in the second chamber.
Abstract translation: 提供性信息素物质的持续释放者和通过使用释放剂来控制害虫的方法，每种能够控制同时释放具有不同化学结构的一种害虫或性信息素物质混合物的性信息素物质的混合物 的虫害，并且每个能够在相应的害虫或害虫的感染期或期间以固定的速率或更高的速率释放性信息素物质。 更具体地，提供了包含一种或多种选自具有10至18个碳原子的直链脂族醛的一种或多种第一性信息素物质的性信息素物质的持续释放剂，一种或多种选自不含醛的脂族衍生物的第二性别信息素物质，其具有7至20 碳原子，以及由聚合物材料制成的第一和第二室，其中所有第一性别信息素物质或所有第一性信息素物质和一些第二性信息素物质被封闭在第一室中，其余的性别 信息素物质被封闭在第二个室中。
-
10.发明授权Sustained release dispenser comprising two or more sex pheromone substances 有权包含两种或多种性信息素物质的持续释放分配器
公开(公告)号：US08834910B2
公开(公告)日：2014-09-16
申请号：US10801229
申请日：2004-03-16
Applicant: Tatsuya Hojo , Kinya Ogawa , Noboru Aiba , Takehiko Fukumoto
Inventor： Tatsuya Hojo , Kinya Ogawa , Noboru Aiba , Takehiko Fukumoto
CPC classification number: A01N31/02 , A01M1/2044 , A01N25/18 , A01N35/02 , A01N37/02 , A01N2300/00
Abstract: Provided are a sustained release dispenser which can control the release of sex pheromone simultaneously toward two or more species of insect pests and can also release the sex pheromone in response to the generation period of insect pest and the pest control method toward two or more insect pests. Provided specifically is a sex pheromone sustained release dispenser comprising two or more sex pheromone substances, each substance being aliphatic derivative having 10 to 20 carbons, and first and second chambers wherein some or all of the sex pheromone substance having a smallest carbon number excluding a carbon number in a functional group is contained in a first polymer chamber and the remainder is contained in a second polymer chamber. Provided also is a pest control method for using the sex pheromone sustained release dispenser.
Abstract translation: 提供一种持续释放分配器，其可以同时控制性信息素向两种或更多种害虫的释放，并且还可以响应于害虫的产生期和对两种或更多种害虫的害虫控制方法释放性信息素 。 特别提供一种包含两种或多种性信息素物质的性信息素持续释放分配器，每种物质是具有10至20个碳的脂族衍生物，以及第一和第二腔室，其中部分或全部具有最小碳数的性别信息素物质不包括碳 官能团中的数目包含在第一聚合物室中，其余部分包含在第二聚合物室中。 还提供了使用性信息素持续释放分配器的害虫控制方法。
