公开(公告)号：US20150072863A1

公开(公告)日：2015-03-12

申请号：US14386534

申请日：2013-03-20

Applicant: BASF SE

Inventor： Thomas Freudenberg ,  Bernhard Holzapfel ,  Oliver Brunkahl ,  Michael Baecker

IPC: H01L39/12 ,  C01G27/02 ,  C01F17/00

CPC classification number: H01L39/126 ,  B82Y30/00 ,  C01B13/328 ,  C01F17/0043 ,  C01G1/02 ,  C01G3/006 ,  C01G25/02 ,  C01G27/02 ,  C01P2004/52 ,  C01P2004/64 ,  C01P2006/40 ,  C01P2006/82 ,  C04B35/4508 ,  C04B35/6264 ,  C04B35/632 ,  C04B2235/3215 ,  C04B2235/3225 ,  C04B2235/3229 ,  C04B2235/443 ,  C04B2235/444 ,  C04B2235/445 ,  C04B2235/449 ,  C04B2235/5454 ,  H01L39/2425

Abstract: Known processes for the production of nanoparticles of compounds of the transition metals Zr, Ti, Ta, rare earths (RE), Mn, and Fe via microemulsions lead to products that contain impurities from the reactants, particularly water, which make the further use of said nanoparticles difficult, for instance in high-temperature super conductors (HTSC). It is proposed that the nanoparticles be produced via anhydrous microemulsions having an outer phase composed of a nonpolar solvent and inner phase composed of a polar anhydrous solvent. The nanoparticles thus obtained exhibit good monodispersity and can be used in the production of REBa2Cu3O7 super conductors by incorporation into the precursor coating solution.

Abstract translation: 通过微乳液生产过渡金属Zr，Ti，Ta，稀土（RE），Mn和Fe的化合物的纳米颗粒的已知方法导致含有来自反应物，特别是水的杂质的产物，这使得进一步使用 所述纳米颗粒难以存在，例如在高温超导体（HTSC）中。 提出通过具有由非极性溶剂构成的外相和由极性无水溶剂组成的内相的无水微乳液来制造纳米粒子。 由此获得的纳米颗粒显示出良好的单分散性，并且可以通过掺入前体涂布溶液中而用于生​​产REBa2Cu3O7超导体。

公开(公告)号：US09257628B2

公开(公告)日：2016-02-09

申请号：US14386534

申请日：2013-03-20

Applicant: BASF SE

Inventor： Thomas Freudenberg ,  Bernhard Holzapfel ,  Oliver Brunkahl ,  Michael Baecker

IPC: H01L39/12 ,  C01B13/32 ,  C04B35/45 ,  C04B35/626 ,  C04B35/632 ,  C01G25/02 ,  C01G27/02 ,  C01F17/00 ,  C01G1/02 ,  C01G3/00 ,  H01L39/24 ,  B82Y30/00

CPC classification number: H01L39/126 ,  B82Y30/00 ,  C01B13/328 ,  C01F17/0043 ,  C01G1/02 ,  C01G3/006 ,  C01G25/02 ,  C01G27/02 ,  C01P2004/52 ,  C01P2004/64 ,  C01P2006/40 ,  C01P2006/82 ,  C04B35/4508 ,  C04B35/6264 ,  C04B35/632 ,  C04B2235/3215 ,  C04B2235/3225 ,  C04B2235/3229 ,  C04B2235/443 ,  C04B2235/444 ,  C04B2235/445 ,  C04B2235/449 ,  C04B2235/5454 ,  H01L39/2425

Abstract: Known processes for the production of nanoparticles of compounds of the transition metals Zr, Ti, Ta, rare earths (RE), Mn, and Fe via microemulsions lead to products that contain impurities from the reactants, particularly water, which make the further use of said nanoparticles difficult, for instance in high-temperature super conductors (HTSC). It is proposed that the nanoparticles be produced via anhydrous microemulsions having an outer phase composed of a nonpolar solvent and inner phase composed of a polar anhydrous solvent. The nanoparticles thus obtained exhibit good monodispersity and can be used in the production of REBa2Cu3O7 super conductors by incorporation into the precursor coating solution.

Abstract translation: 通过微乳液生产过渡金属Zr，Ti，Ta，稀土（RE），Mn和Fe的化合物的纳米颗粒的已知方法导致含有来自反应物，特别是水的杂质的产物，这使得进一步使用 所述纳米颗粒难以存在，例如在高温超导体（HTSC）中。 提出通过具有由非极性溶剂构成的外相和由极性无水溶剂组成的内相的无水微乳液来制造纳米粒子。 由此获得的纳米颗粒显示出良好的单分散性，并且可以通过掺入前体涂布溶液中而用于生​​产REBa2Cu3O7超导体。