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1.发明授权Zeolitic catalyst with a controlled doping element content, and improved process for processing hydrocarbon feeds 有权具有受控掺杂元素含量的沸石催化剂，以及用于处理烃进料的改进方法公开(公告)号：US08002970B2
公开(公告)日：2011-08-23
申请号：US11722610
申请日：2005-12-13
Applicant: Patrick Euzen , Patrick Bourges , Christophe Gueret , Carole Bobin , Alexandra Chaumonnot , Hugues Dulot
Inventor： Patrick Euzen , Patrick Bourges , Christophe Gueret , Carole Bobin , Alexandra Chaumonnot , Hugues Dulot
IPC: C10G47/00
CPC classification number: B01J37/0009 , B01J21/12 , B01J29/146 , B01J29/166 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J2229/20 , B01J2229/42 , C10G47/14 , C10G47/20 , C10G65/12 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
Abstract: The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10−10 m to 24.15×10−10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
Abstract translation: 本发明涉及具有低大孔含量的混合沸石/铝硅酸盐载体上的掺杂催化剂，以及使用它们的加氢裂化/加氢转化和加氢处理方法。 该催化剂包含至少一种选自由元素周期表第ⅥB族和第Ⅷ族元素形成的基团和选自磷，硼和硅的受控量的掺杂元素和基于沸石Y的载体的脱氢元素， 在24.40×10-10 m至24.15×10-10m范围内的晶胞的晶格参数a和含有多于5重量％和95重量％以下的二氧化硅（SiO 2）的二氧化硅 - 氧化铝， 。
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2.发明申请
公开(公告)号：US20060070915A1
公开(公告)日：2006-04-06
申请号：US11221416
申请日：2005-09-08
Applicant: Patrick Euzen , Alexandra Chaumonnot , Carole Bobin , Patrick Bourges , Christophe Gueret , Hugues Dulot
Inventor： Patrick Euzen , Alexandra Chaumonnot , Carole Bobin , Patrick Bourges , Christophe Gueret , Hugues Dulot
IPC: B01J21/12 , B01J27/187 , B01J21/02 , B01J27/182 , C10G47/02
CPC classification number: B01J37/28 , B01J21/02 , B01J21/12 , B01J23/74 , B01J23/85 , B01J23/883 , B01J23/8877 , B01J23/888 , B01J23/8885 , B01J23/8993 , B01J27/188 , B01J35/0006 , B01J35/002 , B01J35/10 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J37/0201 , B01J37/03 , B01J37/10 , B01J37/20 , B01J37/30 , C10G49/04 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
Abstract: This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).
Abstract translation: 本发明涉及具有低含量大孔的铝硅酸盐底物上的掺杂催化剂和使用它们的加氢裂化/加氢转化和加氢处理方法。 催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和选自磷，硼和硅中的受控量的掺杂剂的氢脱氢元素 以及含有大于15重量％且小于或等于95重量％的二氧化硅（SiO 2）的量的二氧化硅 - 氧化铝基底的非沸石基材。
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3.发明授权Catalyst based on a material with a hierarchical porosity comprising silicon, and a process for hydrocracking/hydroconversion and hydrotreatment of hydrocarbon feeds 有权基于具有分层孔隙率的材料的催化剂，包括硅，以及用于烃进料的加氢裂化/加氢转化和加氢处理的方法
公开(公告)号：US08821714B2
公开(公告)日：2014-09-02
申请号：US12515862
申请日：2007-10-29
Applicant: Alexandra Chaumonnot , Patrick Bourges
Inventor： Alexandra Chaumonnot , Patrick Bourges
IPC: C10G47/02
CPC classification number: C10G65/12 , B01J29/005 , B01J29/0308 , B01J29/041 , B01J29/06 , B01J29/072 , B01J29/076 , B01J29/084 , B01J29/126 , B01J29/146 , B01J29/166 , B01J29/40 , B01J29/46 , B01J29/48 , B01J35/023 , B01J37/0045 , B01J2229/20 , B01J2229/62 , C10G47/20 , C10G49/08
Abstract: The invention describes a catalyst comprising at least one material with a hierarchical porosity comprising silicon and at least one hydrodehydrogenating element from group VIB and/or group VIII of the periodic table of the elements. Said material with a hierarchical porosity comprising silicon is constituted by at least two elementary spherical particles, each of said spherical particles comprising zeolitic nanocrystals having a pore size in the range 0.2 to 2 nm and a matrix based on silicon oxide, which is mesostructured, having a pore size in the range 1.5 to 30 nm and having amorphous walls with a thickness in the range 1 to 30 nm, said elementary spherical particles having a maximum diameter of 100 μm. The matrix based on silicon oxide may contain aluminum. The catalyst also optionally comprises at least one doping element in a controlled quantity selected from phosphorus, boron and silicon, optionally at least one element from group VB of the periodic table of the elements, and optionally an element from group VIIA. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.
Abstract translation: 本发明描述了一种催化剂，其包含至少一种具有分层孔隙率的材料，其包含硅和来自元素周期表的VIB族组和/或VIII族的至少一种脱氢元素。 具有包含硅的层状孔隙的所述材料由至少两个基本球形颗粒构成，每个所述球形颗粒包含孔径在0.2至2nm范围内的沸石纳米晶体和基于氧化硅的基体，其被介孔结构化，具有 孔径在1.5至30nm范围内，具有厚度在1至30nm范围内的非晶壁，所述基本球形颗粒的最大直径为100μm。 基于氧化硅的基体可以含有铝。 催化剂还任选地包含选自磷，硼和硅的受控量的至少一种掺杂元素，任选地，元素周期表的第VB族元素中的至少一种元素，以及任选的来自VIIA族的元素。 本发明还涉及使用所述催化剂的加氢裂化/加氢转化和加氢处理方法。
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4.发明授权Doped alumino-silicate catalyst and improved process for treatment of hydrocarbon feeds 有权掺杂铝硅酸盐催化剂和改进的烃类进料处理方法
公开(公告)号：US07879224B2
公开(公告)日：2011-02-01
申请号：US11663497
申请日：2005-09-20
Applicant: Patrick Euzen , Alexandra Chaumonnot , Magalie Roy-Auberger , Patrick Bourges , Tivadar Cseri , Maryline Delage , Nathalie Lett
Inventor： Patrick Euzen , Alexandra Chaumonnot , Magalie Roy-Auberger , Patrick Bourges , Tivadar Cseri , Maryline Delage , Nathalie Lett
IPC: C10G11/02 , B01J27/185
CPC classification number: B01J21/12 , B01J21/02 , B01J23/883 , B01J23/888 , B01J27/1853 , B01J27/188 , B01J35/0006 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/1066 , B01J35/108 , B01J37/0201 , B01J37/20 , B01J37/28 , C10G49/02 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
Abstract: The present invention concerns doped catalysts on an alumino-silicate support with an adapted macropore content and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table, a controlled quantity of phosphorus (optionally in combination with boron and/or silicon) as a doping element, and a non-zeolitic support based on alumina-silica containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
Abstract translation: 本发明涉及具有适用的大孔含量和加氢裂化/加氢转化和使用它们的加氢处理方法的铝硅酸盐载体上的掺杂催化剂。 该催化剂包含至少一种选自元素周期表第VIB族和第VIII族的元素形成的氢化脱氢元素，受控量的磷（任选与硼和/或硅组合）作为掺杂元素， - 基于含有大于5重量％和95重量％或更少的二氧化硅（SiO 2）的量的氧化铝 - 二氧化硅的硅铝石载体。
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5.发明申请CATALYST BASED ON A MATERIAL WITH A HIERARCHICAL POROSITY COMPRISING SILICON, AND A PROCESS FOR HYDROCRACKING/HYDROCONVERSION AND HYDROTREATMENT OF HYDROCARBON FEEDS 有权基于具有包含硅的分层孔隙的材料的催化剂，以及用于水力收割/烃转化和烃加氢处理的方法
公开(公告)号：US20100140138A1
公开(公告)日：2010-06-10
申请号：US12515862
申请日：2007-10-29
Applicant: Alexandra Chaumonnot , Patrick Bourges
Inventor： Alexandra Chaumonnot , Patrick Bourges
IPC: C10G11/05 , B01J29/064 , B01J29/068 , B01J29/072
CPC classification number: C10G65/12 , B01J29/005 , B01J29/0308 , B01J29/041 , B01J29/06 , B01J29/072 , B01J29/076 , B01J29/084 , B01J29/126 , B01J29/146 , B01J29/166 , B01J29/40 , B01J29/46 , B01J29/48 , B01J35/023 , B01J37/0045 , B01J2229/20 , B01J2229/62 , C10G47/20 , C10G49/08
Abstract: The invention describes a catalyst comprising at least one material with a hierarchical porosity comprising silicon and at least one hydrodehydrogenating element from group VIB and/or group VIII of the periodic table of the elements. Said material with a hierarchical porosity comprising silicon is constituted by at least two elementary spherical particles, each of said spherical particles comprising zeolitic nanocrystals having a pore size in the range 0.2 to 2 nm and a matrix based on silicon oxide, which is mesostructured, having a pore size in the range 1.5 to 30 nm and having amorphous walls with a thickness in the range 1 to 30 nm, said elementary spherical particles having a maximum diameter of 100 μm. The matrix based on silicon oxide may contain aluminium. The catalyst also optionally comprises at least one doping element in a controlled quantity selected from phosphorus, boron and silicon, optionally at least one element from group VB of the periodic table of the elements, and optionally an element from group VIIA. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.
Abstract translation: 本发明描述了一种催化剂，其包含至少一种具有分层孔隙率的材料，其包含硅和来自元素周期表的VIB族组和/或VIII族的至少一种脱氢元素。 具有包含硅的层状孔隙的所述材料由至少两个基本球形颗粒构成，每个所述球形颗粒包含孔径在0.2至2nm范围内的沸石纳米晶体和基于氧化硅的基体，其被介孔结构化，具有 孔径在1.5至30nm范围内，具有厚度在1至30nm范围内的非晶壁，所述基本球形颗粒的最大直径为100μm。 基于氧化硅的基体可以含有铝。 催化剂还任选地包含选自磷，硼和硅的受控量的至少一种掺杂元素，任选地，元素周期表的第VB族元素中的至少一种元素，以及任选的来自VIIA族的元素。 本发明还涉及使用所述催化剂的加氢裂化/加氢转化和加氢处理方法。
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6.发明授权
公开(公告)号：US07563743B2
公开(公告)日：2009-07-21
申请号：US11221416
申请日：2005-09-08
Applicant: Patrick Euzen , Alexandra Chaumonnot , Carole Bobin , Patrick Bourges , Christophe Gueret , Hugues Dulot
Inventor： Patrick Euzen , Alexandra Chaumonnot , Carole Bobin , Patrick Bourges , Christophe Gueret , Hugues Dulot
IPC: B01J27/00 , B01J21/00 , B01J23/00 , B01J23/10 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/56 , B01J20/00 , C07C4/02 , C10G11/00 , C10G11/02
CPC classification number: B01J37/28 , B01J21/02 , B01J21/12 , B01J23/74 , B01J23/85 , B01J23/883 , B01J23/8877 , B01J23/888 , B01J23/8885 , B01J23/8993 , B01J27/188 , B01J35/0006 , B01J35/002 , B01J35/10 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J37/0201 , B01J37/03 , B01J37/10 , B01J37/20 , B01J37/30 , C10G49/04 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
Abstract: This invention relates to doped catalysts on an aluminosilicate substrate with a low content of macropores and the hydrocracking/hydroconversion and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by the elements of group VIB and group VIII of the periodic table and a dopant in a controlled quantity that is selected from among phosphorus, boron, and silicon and a non-zeolitic substrate with a silica-alumina base that contains a quantity of more than 15% by weight and of less than or equal to 95% by weight of silica (SiO2).
Abstract translation: 本发明涉及具有低含量大孔的铝硅酸盐底物上的掺杂催化剂和使用它们的加氢裂化/加氢转化和加氢处理方法。 催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和选自磷，硼和硅中的受控量的掺杂剂的氢脱氢元素 和具有二氧化硅 - 氧化铝基底的非沸石基材，其含有大于15重量％且小于或等于95重量％的二氧化硅（SiO 2）的量。
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7.发明申请ZEOLITIC CATALYST WITH A CONTROLLED DOPING ELEMENT CONTENT, AND IMPROVED PROCESS FOR PROCESSING HYDROCARBON FEEDS 有权具有控制元素含量的新兴催化剂，以及加工油料进料的改进方法
公开(公告)号：US20090118556A1
公开(公告)日：2009-05-07
申请号：US11722610
申请日：2005-12-13
Applicant: Patrick Euzen , Patrick Bourges , Christophe Gueret , Carole Bobin , Alexandra Chaumonnot , Hugues Dulot
Inventor： Patrick Euzen , Patrick Bourges , Christophe Gueret , Carole Bobin , Alexandra Chaumonnot , Hugues Dulot
CPC classification number: B01J37/0009 , B01J21/12 , B01J29/146 , B01J29/166 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J2229/20 , B01J2229/42 , C10G47/14 , C10G47/20 , C10G65/12 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018
Abstract: The present invention concerns doped catalysts on a mixed zeolite/alumino-silicate support with a low macropore content, and hydrocracking/hydroconversion and hydrotreatment processes employing them. The catalyst comprises at least one hydrodehydrogenating element selected from the group formed by elements from group VIB and group VIII of the periodic table and a doping element in a controlled quantity selected from phosphorus, boron and silicon, and a support based on zeolite Y defined by a lattice parameter a of the unit cell in the range 24.40×10−10 m to 24.15×10−10 m and silica-alumina containing a quantity of more than 5% by weight and 95% by weight or less of silica (SiO2).
Abstract translation: 本发明涉及具有低大孔含量的混合沸石/铝硅酸盐载体上的掺杂催化剂，以及使用它们的加氢裂化/加氢转化和加氢处理方法。 该催化剂包含至少一种选自由元素周期表第ⅥB族和第Ⅷ族元素形成的基团和选自磷，硼和硅的受控量的掺杂元素和基于沸石Y的载体的脱氢元素， 在24.40×10 -10 m至24.15×10 -10 m范围内的晶胞的晶格参数a和含有多于5重量％和95重量％以下的二氧化硅（SiO 2）的二氧化硅 - 氧化铝。
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8.发明授权Process for hydrodesulphuration of gasoline cuts using a catalyst based on heteropolyanions trapped in a mesostructured silica support 有权使用基于捕获在介孔二氧化硅载体中的杂多阴离子的催化剂对汽油馏分进行加氢脱硫的方法
公开(公告)号：US09376636B2
公开(公告)日：2016-06-28
申请号：US13995800
申请日：2011-12-15
Applicant: Karin Marchand , Elodie Devers , Alexandra Chaumonnot , Audrey Bonduelle , Veronique Dufaud , Frederic Lefebvre , Manuela Bader , Susana Lopes Silva
Inventor： Karin Marchand , Elodie Devers , Alexandra Chaumonnot , Audrey Bonduelle , Veronique Dufaud , Frederic Lefebvre , Manuela Bader , Susana Lopes Silva
IPC: C10G45/04 , B01J27/186 , B01J27/188 , B01J27/19 , C10G45/10 , B01J29/03 , B01J35/00 , B01J35/10 , B01J37/03 , B01J37/10 , B01J37/20 , C10G45/06 , B01J27/195 , B01J27/198
CPC classification number: C10G45/10 , B01J27/186 , B01J27/188 , B01J27/19 , B01J29/0333 , B01J29/0341 , B01J35/002 , B01J35/1019 , B01J35/1042 , B01J35/1057 , B01J35/1061 , B01J37/033 , B01J37/10 , B01J37/20 , B01J2229/20 , C10G45/04 , C10G45/06 , C10G2300/104 , C10G2300/1044 , C10G2300/202 , C10G2300/4018 , C10G2400/02
Abstract: A process of hydrodesulphuration of at least one gasoline cut implementing a catalyst comprising, in its oxide form, at least one metal from group VIB and/or at least one metal from group VIII of the periodic table, present in the form of at least one polyoxometalate of the formula (HhXxMmOy)q−, wherein X is an element selected from phosphorus, silicon, boron, nickel and cobalt, M is one or more element(s) selected from molybdenum, tungsten, nickel and cobalt, h is an integer from 0-12, x is an integer from 0-4, m is an integer 5, 6, 7, 8, 9, 10, 11, 12 and/or 18, y is an integer of 17-72 and q is an integer of 1-20, the polyoxometalates being present within a mesostructured silicon oxide matrix having a pore size of 1.5-50 nm and having amorphous walls of thickness 1-30 nm, the catalyst being sulphured before use in the process.
Abstract translation: 至少一种汽油切割加氢脱硫的方法，其实施催化剂，其以其氧化物形式包含至少一种以至少一种形式存在的来自VIB族组分和/或至少一种来自元素周期表Ⅷ族的金属的金属 式（HhXxMmOy）q-的多金属氧酸盐，其中X是选自磷，硅，硼，镍和钴的元素，M是选自钼，钨，镍和钴的一种或多种元素，h是整数 从0-12，x是0-4的整数，m是整数5,6,7,8,9,10,11,12和/或18，y是17-72的整数，q是 整数为1-20，多金属氧酸盐存在于孔径为1.5-50nm的介孔结构的氧化硅基质中，并且具有厚度为1-30nm的无定形壁，催化剂在该方法使用前被硫化。
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9.发明授权Process for preparing materials by grafting halogenated phosphorus-containing groups onto an inorganic surface 失效通过将卤代含磷基团接枝到无机表面上制备材料的方法
公开(公告)号：US08247539B2
公开(公告)日：2012-08-21
申请号：US12375742
申请日：2007-07-06
Applicant: Renaud Revel , Florence Brodard-Severac , Gilles Guerrero , Hubert Mutin , Alain Forestiere , Alexandra Chaumonnot
Inventor： Renaud Revel , Florence Brodard-Severac , Gilles Guerrero , Hubert Mutin , Alain Forestiere , Alexandra Chaumonnot
CPC classification number: B01J20/3248 , B01J21/063 , B01J31/0269 , C04B41/009 , C04B41/4584 , C04B41/81 , C07F9/657181 , C04B41/4994 , C04B35/46
Abstract: The invention concerns a process for preparing a hybrid organic-inorganic material (HOIM) with phosphorus-containing bridges between the surface of an inorganic substrate containing an element M and one or more organic groups of the covalent M-O-P-R type, said process using, as a precursor for said organic group or groups, at least one organophosphorus acid halide with formula RxP(O)Xy in which x=1 or 2, y=3−x, X being a halogen and R designating at least one organic alkyl, aryl or aryl-alkyl group.Non-exhaustive applications for the hybrid organic-inorganic material obtained by the process of the invention are in the fields of anti-corrosion, lubrication, microelectronics, nanotechnologies, composite materials, heterogeneous catalysis, supported catalysis, depollution and biomedical applications.
Abstract translation: 本发明涉及一种在含有元素M的无机基质的表面与共价MOPR型的一种或多种有机基团的表面之间制备具有含磷桥的杂化有机 - 无机材料（HOIM）的方法，所述方法使用 所述有机基团的前体，至少一种式RxP（O）Xy的有机磷酰卤，其中x = 1或2，y = 3-x，X为卤素，R指定至少一个有机烷基，芳基或 芳基 - 烷基。 通过本发明方法获得的杂化有机 - 无机材料的非穷举应用在抗腐蚀，润滑，微电子学，纳米技术，复合材料，多相催化，负载催化，去污染和生物医学应用领域。
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10.发明授权Inorganic material that has metal nanoparticles that are trapped in a mesostructured matrix 有权具有被捕获在介孔结构基质中的金属纳米颗粒的无机材料
公开(公告)号：US08226740B2
公开(公告)日：2012-07-24
申请号：US11889890
申请日：2007-08-17
Applicant: Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Cedric Boissiere , David Grosso
Inventor： Alexandra Chaumonnot , Aurelie Coupe , Clement Sanchez , Cedric Boissiere , David Grosso
CPC classification number: C01B39/48 , B01J23/002 , B01J23/10 , B01J23/52 , B01J23/745 , B01J23/75 , B01J29/044 , B01J29/46 , B01J29/89 , B01J35/0013 , B01J35/10 , B01J35/1057 , B01J35/1061 , B01J35/1085 , B01J35/109 , B01J2229/18 , B01J2229/42 , B01J2523/00 , C01B37/02 , C01B39/04 , Y10S977/777 , Y10S977/779 , Y10T428/12042 , B01J2523/3706 , B01J2523/3712 , B01J2523/845 , B01J2523/41 , B01J2523/48 , B01J2523/31 , B01J2523/842
Abstract: An inorganic material that consists of at least two elementary spherical particles, each of said spherical particles comprising metal nanoparticles that are between 1 and 300 nm in size and a mesostructured matrix with an oxide base of at least one element X that is selected from the group that consists of aluminum, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium is described, whereby said matrix has a pore size of between 1.5 and 30 nm and has amorphous walls with a thickness of between 1 and 30 nm, said elementary spherical particles having a maximum diameter of 10 μm. Said material can also contain zeolitic nanocrystals that are trapped within said mesostructured matrix.
Abstract translation: 由至少两个基本球形颗粒组成的无机材料，每个所述球形颗粒包含尺寸在1至300nm之间的金属纳米颗粒和具有至少一种元素X的氧化物碱的介孔结构基质，所述元素选自基团 描述了由铝，钛，钨，锆，镓，锗，锡，锑，铅，钒，铁，锰，铪，铌，钽，钇，铈，钆，铕和钕组成的组合物， 孔径在1.5和30nm之间，并且具有1至30nm厚度的非晶壁，所述基本球形颗粒的最大直径为10μm。 所述材料还可以含有被捕获在所述介孔结构基质内的沸石纳米晶体。
