公开(公告)号：US07510777B2

公开(公告)日：2009-03-31

申请号：US11306125

申请日：2005-12-16

申请人： Ramgopal Darolia ,  Brian Thomas Hazel

发明人： Ramgopal Darolia ,  Brian Thomas Hazel

IPC分类号： B32B9/00

CPC分类号： C23C28/321 ,  C23C28/3215 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  C23C30/00 ,  Y10T428/12951

摘要： A thermal barrier coating (TBC) for a component intended for use in a hostile environment, such as a component of a gas turbine engine. The TBC exhibits improved impact and erosion resistance as a result of being a composite material consisting essentially of particles of a ceramic reinforcement material dispersed in a ceramic matrix material. The ceramic reinforcement material has a yield strength greater than the ceramic matrix material at about 1100° C., and the particles of the ceramic reinforcement material have an average maximum dimension of greater than five micrometers.

摘要翻译： 用于在敌对环境中使用的组件的热障涂层（TBC），例如燃气涡轮发动机的部件。 作为基本上由分散在陶瓷基体材料中的陶瓷增强材料的颗粒组成的复合材料，TBC显示出改善的耐冲击性和耐腐蚀性。 陶瓷增强材料在约1100℃下的屈服强度大于陶瓷基体材料，并且陶瓷增强材料的颗粒的平均最大尺寸大于5微米。

公开(公告)号：US20080292803A1

公开(公告)日：2008-11-27

申请号：US11903096

申请日：2007-09-20

申请人： Bangalore A. Nagaraj ,  Irene Spitsberg ,  Christine Govern ,  Brian Thomas Hazel

发明人： Bangalore A. Nagaraj ,  Irene Spitsberg ,  Christine Govern ,  Brian Thomas Hazel

IPC分类号： B05D1/36

CPC分类号： C04B41/89 ,  C04B41/009 ,  C04B41/52 ,  C23C28/042 ,  C23C28/322 ,  C23C28/345 ,  C23C28/3455 ,  C04B41/5096 ,  C04B41/5035 ,  C04B41/522 ,  C04B41/4527 ,  C04B41/5024 ,  C04B41/5037 ,  C04B41/5042 ,  C04B2111/00405 ,  C04B41/5044 ,  C04B35/565 ,  C04B35/806

摘要： In accordance with an embodiment of the invention, a thermal barrier coating for inclusion in a thermal barrier coating/environmental barrier coating system (TBC/EBC system) for use on a silicon based substrate is disclosed. The thermal barrier coating comprising up to about 9 mol percent of a stabilizer and up to 91 mol percent of primary oxide selected from the group consisting of zirconia, hafnia and mixtures thereof. The stabilizer comprises: a first metal oxide selected from the group consisting of yttria, calcia, ceria, scandia, magnesia, india and mixtures thereof, a second metal oxide of a trivalent metal atom selected from the group consisting of lanthana, gadolinia, neodymia, samaria, dysprosia, ytterbia, erbia, and mixtures thereof. The first metal oxide is in an amount of from about 3 to about 5 mol %, the second metal oxide is in an amount of from about 0.25 to about 6 mol %.

摘要翻译： 根据本发明的一个实施例，公开了一种用于包含在用于硅基衬底的隔热涂层/环境阻挡涂层系统（TBC / EBC系统）中的热障涂层。 所述热障涂层包括高达约9mol％的稳定剂和至多91mol％的选自氧化锆，铪的主要氧化物及其混合物。 稳定剂包括：选自氧化钇，氧化钙，二氧化铈，钪，氧化镁，印度及其混合物的第一金属氧化物，选自氧化镧，氧化钆，氧化钕， samaria，dysprosia，ytterbia，erbia及其混合物。 第一金属氧化物的量为约3至约5mol％，第二金属氧化物的量为约0.25至约6mol％。

公开(公告)号：US20080124479A1

公开(公告)日：2008-05-29

申请号：US12026097

申请日：2008-02-05

申请人： Brian Thomas Hazel ,  Irene Spitsberg ,  Brett Allen Boutwell

发明人： Brian Thomas Hazel ,  Irene Spitsberg ,  Brett Allen Boutwell

IPC分类号： C23C4/12 ,  B05D3/02 ,  C23C16/06

CPC分类号： C23C4/02 ,  C04B41/009 ,  C04B41/52 ,  C04B41/89 ,  C23C28/321 ,  C23C28/325 ,  C23C28/345 ,  C23C28/3455 ,  Y10T428/12611 ,  Y10T428/12674 ,  Y10T428/24967 ,  Y10T428/263 ,  C04B41/5071 ,  C04B41/0072 ,  C04B41/4558 ,  C04B41/5035 ,  C04B41/5024 ,  C04B41/4529 ,  C04B41/5031 ,  C04B41/4527 ,  C04B41/5042 ,  C04B41/522 ,  C04B35/565 ,  C04B35/584 ,  C04B35/806

摘要： Process includes providing a silicide-containing bond coat layer overlying a silicon-containing substrate, optionally forming a silica scale layer adjacent to and overlying the bond coat layer by preoxidizing the bond coat layer, and providing an environmental barrier coating overlying the bond coat layer. The environmental barrier coating includes a corrosion resistant outer layer formed by reacting a metal source with the silica scale layer, if present, or with the silicide-containing substrate in the absence of the silica scale layer. The process may include providing a thermal barrier coating overlying the corrosion resistant outer layer. The silicon-containing substrate may include at least a portion of a gas turbine engine component selected from a turbine blade, vane, and blisk.

摘要翻译： 方法包括提供覆盖含硅基材的含硅化物的粘合涂层，任选地通过预氧化粘结涂层形成邻近并覆盖粘合涂层的二氧化硅垢层，以及提供覆盖在粘结涂层上的环境阻挡涂层。 环境保护涂层包括通过金属源与二氧化硅垢层（如果存在）反应形成的耐腐蚀外层，或者在没有二氧化硅垢层的情况下与含硅化物的衬底反应。 该方法可以包括提供覆盖耐腐蚀外层的热障涂层。 含硅衬底可以包括选自涡轮叶片，叶片和叶片的燃气涡轮发动机部件的至少一部分。

公开(公告)号：US07314674B2

公开(公告)日：2008-01-01

申请号：US11011695

申请日：2004-12-15

申请人： Brian Thomas Hazel ,  Michael James Weimer

发明人： Brian Thomas Hazel ,  Michael James Weimer

IPC分类号： B32B15/04 ,  F03B3/12

CPC分类号： C23C30/00 ,  C23C22/74 ,  C23C24/08 ,  C23C26/00 ,  F01D5/288 ,  F01D25/007 ,  F05D2230/90 ,  F05D2300/611 ,  Y10T428/12028 ,  Y10T428/12611 ,  Y10T428/1275

摘要： A composition comprising a particulate corrosion resistant component, and a glass-forming binder component. The particulate corrosion resistant component comprises from 0 to about 95% alumina particulates, and from about 5 to 100% corrosion resistant non-alumina particulates having a CTE greater than that of the alumina particulates. Also disclosed is an article comprising a turbine component comprising a metal substrate and a corrosion resistant coating having thickness up to about 10 mils (254 microns) overlaying the metal substrate. At least the layer of this coating adjacent to the metal substrate comprises a glass-forming binder component and the particulate corrosion resistant component adhered to the glass-forming binder component. Further disclosed is a method comprising the following steps: (a) providing a turbine component comprising the metal substrate; (b) depositing on the metal substrate a corrosion resistant coating composition; and (c) curing the deposited corrosion resistant coating composition to form at least one layer of a corrosion resistant coating having a thickness up to about 10 mils (254 microns).

摘要翻译： 一种组合物，其包含颗粒耐腐蚀组分和形成玻璃的粘合剂组分。 颗粒腐蚀性组分包含0至约95％的氧化铝颗粒，以及约5至100％的耐腐蚀的非氧化铝颗粒，其CTE大于氧化铝颗粒的CTE。 还公开了一种包括涡轮机部件的制品，该涡轮机部件包括覆盖金属基底的厚度高达约10密耳（254微米）的金属基底和耐腐蚀涂层。 至少与金属基材相邻的该涂层的层包含玻璃形成粘合剂组分，并且颗粒腐蚀性部件粘附到玻璃形成粘合剂组分。 进一步公开的方法包括以下步骤：（a）提供包括金属基底的涡轮机部件; （b）在金属基材上沉积耐腐蚀涂料组合物; 和（c）固化沉积的耐腐蚀涂料组合物以形成至少一层具有至多约10密耳（254微米）厚度的耐腐蚀涂层。

公开(公告)号：US07250225B2

公开(公告)日：2007-07-31

申请号：US11162838

申请日：2005-09-26

申请人： Brian Thomas Hazel ,  Ramgopal Darolia ,  Brett Allen Rohrer Boutwell ,  David John Wortman

发明人： Brian Thomas Hazel ,  Ramgopal Darolia ,  Brett Allen Rohrer Boutwell ,  David John Wortman

IPC分类号： B32B15/01 ,  B32B15/04 ,  B32B15/20 ,  F01D5/28

CPC分类号： C23C30/00 ,  Y10T428/12458 ,  Y10T428/12736 ,  Y10T428/1275 ,  Y10T428/12875 ,  Y10T428/12937 ,  Y10T428/12944

摘要： An intermetallic composition suitable for use as an environmentally-protective coating on surfaces of components used in hostile thermal environments, including the turbine, combustor and augmentor sections of a gas turbine engine. The coating contains the gamma-prime (Ni3Al) nickel aluminide intermetallic phase and either the beta (NiAl) nickel aluminide intermetallic phase or the gamma solid solution phase. The coating has an average aluminum content of 14 to 30 atomic percent and an average platinum-group metal content of at least 1 to less than 10 atomic percent, the balance of the coating being nickel, incidental impurities, and optionally hafnium.

摘要翻译： 适用于在敌对热环境中使用的组件的表面上用作环境保护涂层的金属间组合物，包括燃气涡轮发动机的涡轮机，燃烧器和增压器部分。 该涂层含有γ-prime（Ni 3 Al 3）铝铝化物金属间相和β（NiAl）镍铝化物金属间相或γ固溶体相。 该涂层的平均铝含量为14〜30原子％，平均铂族金属含量为1〜10原子％以下，镀层为镍，附带杂质，可选地为铪。

公开(公告)号：US06921251B2

公开(公告)日：2005-07-26

申请号：US10655835

申请日：2003-09-05

申请人： John Frederick Ackerman ,  Michael James Weimer ,  Joseph Aloysius Heaney ,  Robert George Zimmerman, Jr. ,  Bangalore Aswatha Nagaraj ,  Brian Thomas Hazel ,  Nripendra Nath Das

发明人： John Frederick Ackerman ,  Michael James Weimer ,  Joseph Aloysius Heaney ,  Robert George Zimmerman, Jr. ,  Bangalore Aswatha Nagaraj ,  Brian Thomas Hazel ,  Nripendra Nath Das

IPC分类号： C23C10/02 ,  C23C16/16 ,  C23C16/20 ,  F01D5/28 ,  F01D5/14

CPC分类号： F01D5/288 ,  C23C10/02 ,  C23C16/16 ,  C23C16/20 ,  F05D2230/90 ,  F05D2300/611 ,  Y02T50/67

摘要： A turbine engine rotor component, such as a compressor or turbine disk or seal element, is protected from corrosion by depositing an aluminum or chromium coating on the component. The deposition can be performed by a vapor deposition process, such as metal organic chemical vapor deposition (MOCVD), to a coating thickness of from about 0.2 to about 50 microns, typically from about 0.5 to about 3 microns. In one embodiment, the method is conducted in a vapor coating container having a hollow interior coating chamber, and includes the steps of loading the coating chamber with the component to be coated; and flowing a tri-alkyl aluminum or chromium carbonyl coating gas into the loaded coating chamber at a specified temperature, pressure, and time to deposit an aluminum or chromium coating on the surface of the component. The coated component is then heated in a nonoxidizing atmosphere to a specified temperature to form an aluminide or chromide coating on the surface. The coated component is typically then heated or maintained at an elevated temperature in the presence of oxygen to form an oxide coating on the surface of the component.

摘要翻译： 诸如压缩机或涡轮盘或密封元件的涡轮发动机转子部件通过在组件上沉积铝或铬涂层来防止腐蚀。 沉积可以通过气相沉积工艺（例如金属有机化学气相沉积（MOCVD））进行，涂层厚度为约0.2至约50微米，通常为约0.5至约3微米。 在一个实施方案中，该方法在具有中空内部涂覆室的蒸气涂覆容器中进行，并且包括以下步骤：将涂覆室与要涂覆的组分装载; 并在规定的温度，压力和时间下将三烷基铝或铬羰基涂覆气体流入装载的涂覆室，以在组件的表面上沉积铝或铬涂层。 然后将涂覆的组分在非氧化气氛中加热至特定温度，以在表面上形成铝化物或铬酸盐涂层。 然后通常在氧存在下将涂覆的组分加热或保持在升高的温度，以在组分的表面上形成氧化物涂层。