摘要:
A process for the whitening of phosphogypsum comprising treating a phosphogypsum in aqueous suspension with an amount of ozone equal to at least 150 parts by weight per million parts by weight of phosphogypsum calculated as Ca SO.sub.4.2H.sub.2 O, the pH of the aqueous suspension being lower than or equal to 3, to yield a whiteness grade of phosphogypsum higher than 75, according to French Standard NF Q 03-038.
摘要:
A process for the manufacture of calcium sulphate alpha-hemihydrate which comprises the step of interacting an aqueous solution of calcium chloride and a source of sulphate or bisulphate ions in an aqueous system at a temperature above the calcium sulphate hemihydrate/gypsum transition temperature under the reaction conditions. The preferred reagents are the waste calcium chloride/sodium chloride effluent of the ammonia soda process and sulphuric acid (e.g. impure sulphuric acid effluent) to give hydrochloric acid as a co-product. The preferred reaction temperature is at least 20.degree. C. above the transition temperature (about 70.degree. C), e.g. at 95.degree.-100.degree. C at atmospheric pressure.
摘要:
Apparatus comprising means for dispersing comminuted limestone in a stream of hot gas and calcining it to form quicklime; a calcining chamber into which comminuted gypsum and the stream of hot gas containing the quicklime are introduced wherein the gypsum is calcined and thoroughly mixed with the quicklime; a gas-solids separator for separating the calcined gypsum and quicklime from the gas stream; and hydration means for hydrating the quicklime and gypsum whereby any phosphoric acid in the gypsum reacts with the hydrated quicklime to form insoluble calcium phosphate.
摘要:
A process is described for the formation of fibrous calcium sulfate hemihydrate, the fibers thereof having specified dimensions, wherein a dilute aqueous suspension of gypsum and, if desired, a crystal habit modifier is first formed. The gypsum in the suspension is then converted into fibrous hemihydrate by reaction in the presence of saturated steam at 120.degree. to 155.degree.C for 0.5 to 2.5 hours.
摘要:
FOR OBTAINING A BUILDING MATERIAL CONTAINING HYDRATED LIME AND PLASTER, QUICKLIME IS REACTED WITH SYNTHETIC GYPSUM, SUCH AS PHOSPHOGYPSUM WHICH IS A BYPRODUCT OF THE MANUFACTURE OF PHOSPHORIC ACID, THE REACTION TAKING PLACE WITHOUT EXTERNAL HEATING IN A REACTION ZONE IN WHICH A WATER SATURATED ATMOSPHERE IS MAINTAINED.
摘要:
BY-PRODUCT GYPSUM ARISING IN THE EXTRACTION OF PHOSPHORUS-CONTAINING MINERALS AND CONTAMINATED WITH PHOSPHORIC ACID AND ITS WATER-SOLUBLE SALTS IS CALCINED, THE CALCINE IS TREATED WITH WATER AND A NEUTRALISING AGENT TO FORM CALCIUM SULFATE DIHYDRATE AND WATER-INSOLUBLE COMPOUNDS OF THE CONTAMINANTS AND THE DIHYDRATE IS SUBJECTED TO A SECOND CALCINATION TO PRODUCE A SYNTHETIC CALCIUM SULFATE HEMIHYDRATE WHICH HAS PROPERTIES COMPARABLE TO OR BETTER THAN THOSE OF PLASTER OF PARIS DERIVED FROM NATURAL GYPSUM.
摘要:
A method of recovering desalinated activated alumina (AA) beads from a composition including salt laden (high salt absorbed) activated alumna (AA) beads and free anions and free cations, comprising the step of electrodialysis of the composition to reduce salt content of the activated alumina (AA) beads to produce a stream comprising the desalinated activated alumina (AA) beads.