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    Developer compositions
    52.
    发明授权
    Developer compositions 失效
    显影剂组合物

    公开(公告)号：US4634649A

    公开(公告)日：1987-01-06

    申请号：US713975

    申请日：1985-03-20

    申请人： John F. Knapp ,  Robert J. Gruber

    发明人： John F. Knapp ,  Robert J. Gruber

    IPC分类号： G03G9/087 ,  G03G9/10

    CPC分类号： G03G9/08755

    摘要： Disclosed is a two-component developer composition enabling smudge resistant images which is comprised of improved two-component contamination free developer composition comprised of (1) magnetite; (2) a polyester resin comprised of the polymeric esterification product of a dicarboxylic acid and a diol comprising a diphenol of the following formula ##STR1## wherein R is selected from substituted and unsubstituted alkylene radicals of from about 2 to about 12 carbon atoms, alkylidene radicals of from 1 to 12 carbon atoms and cycloalkylidene radicals of from 3 to 12 carbon atoms; R' and R" are selected from substituted and unsubstituted alkylene radicals of from 2 to 12 carbon atoms, alkylene arylene radicals of from 8 to 12 carbon atoms and arylene radicals; X and X' are selected from hydrogen or any alkyl radical having from 1 to 4 carbon atoms; and each n is a number of from 0 (zero) to 4; and (3) carrier particles.

    摘要翻译： 公开了一种双组分显影剂组合物，其具有防污图像，其包括由（1）磁铁矿组成的改进的双组分无污染显影剂组合物; （2）由二羧酸和二醇的聚合酯化产物组成的聚酯树脂，其包含下式的二酚：其中R选自取代和未取代的约2至约12个碳原子的亚烷基，亚烷基 1至12个碳原子的基团和3至12个碳原子的亚环烷基; R'和R“选自取代和未取代的2至12个碳原子的亚烷基，8至12个碳原子的亚烷基亚芳基和亚芳基; X和X'选自氢或任何具有1至4个碳原子的烷基; 并且每个n是从0（零）到4的数量; 和（3）载体颗粒。

    Development process with toner composition containing low molecular weight waxes
    53.
    发明授权
    Development process with toner composition containing low molecular weight waxes 失效
    含有低分子量蜡的调色剂组合物的显影方法

    公开(公告)号：US4578338A

    公开(公告)日：1986-03-25

    申请号：US645892

    申请日：1984-08-31

    申请人： Robert J. Gruber ,  Ronald J. Koch ,  John F. Knapp

    发明人： Robert J. Gruber ,  Ronald J. Koch ,  John F. Knapp

    IPC分类号： G03G9/087 ,  G03G9/08 ,  G03G9/09 ,  G03G9/097 ,  G03G13/08 ,  G03G13/20 ,  G03G15/20 ,  G03G13/14

    CPC分类号： G03G13/20 ,  G03G13/08 ,  G03G9/0975 ,  G03G9/09758

    摘要： An improved process for the development and fixing of electrostatic latent images which comprises (1) generating an electrostatic latent image on a photoconductive imaging member, (2) developing this image with a toner composition comprised of toner resin particles, pigment particles, and a wax component of a molecular weight of from about 500 to about 20,000, (3) transferring the developed image to a suitable substrate, and subsequently (4) fusing the transferred image with a compliant oil fuser roll, wherein the amount of fuser oil consumed is from about one microliter to about three microliters per page of developed image.

    摘要翻译： 一种用于显影和固定静电潜像的改进方法，其包括（1）在光导成像构件上产生静电潜像，（2）用调色剂树脂颗粒，颜料颗粒和蜡组成的调色剂组合物显影该图像 分子量为约500至约20,000的组分，（3）将显影图像转印到合适的基底上，随后（4）用柔性油定影辊对转印的图像进行定影，其中消融的定影油的量来自 每页大约1微升到大约3微升的图像。

    Developer compositions with infrared absorbing additives
    55.
    发明授权
    Developer compositions with infrared absorbing additives 失效
    具有红外吸收添加剂的显影剂组合物

    公开(公告)号：US4539284A

    公开(公告)日：1985-09-03

    申请号：US600854

    申请日：1984-04-16

    申请人： Angello J. Barbetta ,  Robert J. Gruber ,  Louis V. Isganitis ,  Kock-Yee Law ,  John W. Lin ,  Ronald J. Koch ,  Steven T. Dunn

    发明人： Angello J. Barbetta ,  Robert J. Gruber ,  Louis V. Isganitis ,  Kock-Yee Law ,  John W. Lin ,  Ronald J. Koch ,  Steven T. Dunn

    IPC分类号： G03G9/08 ,  G03G9/09 ,  G03G9/097 ,  G03G9/10

    CPC分类号： G03G9/09741 ,  G03G9/0918 ,  G03G9/09775 ,  Y10S430/145

    摘要： An improved infrared sensitive flash fusible colored toner composition comprised of (1) resin particles, (2) pigment particles selected from the group consisting of cyan, magenta, yellow, blue, red and green, and (3) additives selected from the group consisting of vanadyl phthalocyanines, naphthalocyanines, and the quaternary ammonium salts selected from the group consisting of 1,1',3,3,3',3 hexylmethyl-4,4',5,5'-dibenzo-2,2'-indotricarbocyanine perchlorate, 5,5'-dichloro-11-diphenylamine-3,3'-diethyl-10,12-ethylenethiatricarbocyanine perchlorate, 1,1',3,3,3',3'-hexamethylindotricarbocyanine perchlorate, and 3,3'-di(3-acetoxypropyl)-11-diphenylamine-10,12-ethylene-5,6,5',6'-dibenzothiatricarbocyanine perchlorate.

    摘要翻译： 由（1）树脂颗粒，（2）选自青色，品红色，黄色，蓝色，红色和绿色的颜料颗粒组成的改进的红外敏感闪光熔融着色调色剂组合物和（3）选自以下的添加剂： 的氧钒基酞菁，萘酞菁和选自1,1'，3,3,3'，3己基甲基-4,4'，5,5'-二苯并-2,2'-吲哚甲酸花青的季铵盐 高氯酸盐，5,5'-二氯-11-二苯胺-3,3'-二乙基-10,12-亚乙基二硫代高碘酸花青，1,1'，3,3,3'，3'-六甲基三异氰尿酸高氯酸盐和3,3 ' - 二（3-乙酰氧基丙基）-11-二苯胺-10,12-乙烯-5,6,5'，6'-二十二碳基硫代花青高氯酸盐。

    Nitrogen containing polymers as charge enhancing additive for electrophotographic toner
    56.
    发明授权
    Nitrogen containing polymers as charge enhancing additive for electrophotographic toner 失效
    含氮聚合物作为电子照相调色剂的电荷增强添加剂

    公开(公告)号：US4415646A

    公开(公告)日：1983-11-15

    申请号：US354472

    申请日：1982-03-03

    申请人： Robert J. Gruber ,  Steven B. Bolte ,  Doretta Agostine

    发明人： Robert J. Gruber ,  Steven B. Bolte ,  Doretta Agostine

    IPC分类号： G03G9/08 ,  C08K9/00 ,  C08K9/04 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L33/00 ,  C08L33/02 ,  C08L33/24 ,  C08L67/00 ,  C08L77/00 ,  C08L101/00 ,  G03G9/087 ,  G03G9/097 ,  G03G9/00

    CPC分类号： G03G9/0874 ,  G03G9/08726 ,  G03G9/08791

    摘要： This invention is directed to positively charged developer compositions and toner compositions, the toner composition being comprised of resin particles, pigment particles, and from about 0.1 to about 10 percent by weight of the toner particles of a polymeric charge enhancing additive selected from the group consisting of those additives of the following formulas: ##STR1## wherein a and b are percentage numbers equaling 100, a being from about 20 weight percent to about 99 weight percent, and b being from about 80 weight percent to about 1 weight percent, n is a repeating number ranging from about 3 to about 300, Z is an oxygen atom, c is the number zero or 1, Y is an alkyl or aromatic radical, Z' is selected from the group consisting of aliphatic, aromatic, and heterocyclic radicals, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently selected from alkyl radicals containing from about 1 to about 22 carbon atoms, X is an anion, a' is a number of from about 50 to about 500, R.sub.1 ' is hydrogen or an alkyl radical containing from 1 to about 22 carbon atoms; as well as methods of developing electrostatographic images utilizing such compositions.

    摘要翻译： 本发明涉及带正电荷的显影剂组合物和调色剂组合物，该调色剂组合物由树脂颗粒，颜料颗粒组成，和约0.1至约10重量％的聚合物电荷增强添加剂的调色剂颗粒，其选自 的下式的添加剂：其中a和b的百分数等于100，a为约20重量％至约99重量％，b为约80重量％至约1重量％ n为重复数，范围为约3至约300，Z为氧原子，c为数字0或1，Y为烷基或芳基，Z'选自脂族，芳族， 和杂环基，R 1，R 2，R 3和R 4独立地选自含有约1至约22个碳原子的烷基，X为阴离子，“为约50至约500的数，R 1'为氢 r为含有1至约22个碳原子的烷基; 以及利用这种组合物开发静电图像的方法。

    Process for charging toner compositions
    57.
    发明授权
    Process for charging toner compositions 失效
    调色剂组合物的加工方法

    公开(公告)号：US4378420A

    公开(公告)日：1983-03-29

    申请号：US298983

    申请日：1981-09-03

    申请人： Robert J. Gruber ,  Steven B. Bolte ,  Richard F. Koehler, Jr. ,  Edward W. Connors

    发明人： Robert J. Gruber ,  Steven B. Bolte ,  Richard F. Koehler, Jr. ,  Edward W. Connors

    IPC分类号： G03G9/10 ,  G03G9/087 ,  G03G9/09 ,  G03G9/097 ,  G03G9/113 ,  G03G13/08 ,  G03G15/09 ,  G03G21/00

    CPC分类号： G03G13/08 ,  G03G9/1138

    摘要： This invention is generally directed to an improved process for rapidly charging uncharged replenishment toner particles to a positive polarity, and the use of such particles for developing images in an electrostatographic imaging system, which process comprises (1) adding uncharged replenishment toner particles to a charged developer composition comprised of carrier particles and toner particles, the carrier particles consisting of a core containing a polymer coating thereon having incorporated therein an additive having a pKa of less than 5, said additive being selected from the group consisting of perfluorooctanoic acid, 2,4-dinitrophenol, 2,4,6-trinitrophenol, and naphthalene sulfonic acids, (2) contacting the charged developing composition containing said carrier particles with the uncharged toner particles, wherein positive charges are transferred to the uncharged toner particles within a mixing period of from about 5 seconds to about 5 minutes, thereby resulting in substantially the same level of positive charge intensity for said uncharged toner particles as the charge intensity of toner particles in the charged developer composition, said charge intensity ranging from about 0.1 femtocoulombs per micron, to about 3 femtocoulombs per micron of toner particles.

    摘要翻译： 本发明一般涉及用于将不带电补充调色剂颗粒快速装入正极性的改进方法，以及使用这种颗粒在静电图像成像系统中显影图像的方法，该方法包括（1）将不带电补充调色剂颗粒加入到带电 由载体颗粒和调色剂颗粒组成的显影剂组合物，载体颗粒由其上包含聚合物涂层的核心组成，其中掺入了其中pKa小于5的添加剂，所述添加剂选自全氟辛酸，2,4 二硝基苯酚，2,4,6-三硝基苯酚和萘磺酸，（2）使含有载体颗粒的带电显影组合物与不带电荷的调色剂颗粒接触，其中将正电荷转移到不带电调色剂颗粒的混合期间 约5秒至约5分钟，从而基本上得到 所述不带电荷的调色剂颗粒的正电荷强度水平与带电显影剂组合物中的调色剂颗粒的电荷强度相同，所述电荷强度范围为约0.1毫微微图/微米，至每微米调色剂颗粒约3毫微微图。

    Toner additives
    58.
    发明授权
    Toner additives 失效
    调色剂添加剂

    公开(公告)号：US4304830A

    公开(公告)日：1981-12-08

    申请号：US111620

    申请日：1980-01-14

    申请人： Steven B. Bolte ,  Robert J. Gruber ,  Richard F. Koehler, Jr. ,  Edward W. Connors

    发明人： Steven B. Bolte ,  Robert J. Gruber ,  Richard F. Koehler, Jr. ,  Edward W. Connors

    IPC分类号： G03G9/097 ,  G03G9/107 ,  G03G9/113 ,  G03G9/10

    CPC分类号： G03G9/09758 ,  G03G9/1075 ,  G03G9/1138

    摘要： This invention is directed to positively charged toners comprised of a resin, a colorant, and an additive possessing an anion, and more specifically, an alkyl pyridinium compound and its corresponding hydrate, of the formulas ##STR1## wherein A is an anion, which in a preferred embodiment is selected from halides such as fluoride, chloride, bromide, or iodide; sulfate, sulfonate, nitrate borate, and phosphate; R is a hydrocarbon radical containing from about 8 to about 22 carbon atoms and preferably from 12 to 18 carbon atoms. An important embodiment of the present invention is directed to a process for rapidly charging (or admixing) uncharged dry electrostatographic toner, containing the alkyl pyridinium compounds of the above formulas, subsequent to its addition to previously charged developer, whereby the uncharged toner particles acquire a charge within a period of from about 1 minute to about 5 minutes. The toners of this invention are useful for developing images of high quality in an electrostatographic imaging system.

    摘要翻译： 本发明涉及由具有阴离子的树脂，着色剂和添加剂组成的带正电荷的调色剂，更具体地，其中A是阴离子的式“IMAGE”的烷基吡啶鎓化合物及其相应的水合物，其中 优选的实施方案选自卤素如氟化物，氯化物，溴化物或碘化物; 硫酸盐，磺酸盐，硝酸硼酸盐和磷酸盐; R是含有约8至约22个碳原子，优选12至18个碳原子的烃基。 本发明的一个重要实施方案涉及一种用于在加入到预先装入的显影剂中之后快速装入（或混合）含有上述式的烷基吡啶鎓化合物的不带电的干燥静电色谱调色剂的方法，由此不带电荷的调色剂颗粒获得 在约1分钟至约5分钟的时间内充电。 本发明的调色剂可用于在静电图像成像系统中显影高质量图像。